The reversible gas-phase decomposition of nitrogen tetra oxide, N2O4, to nitrogen dioxide, NO2, is to be carried out at constant temperature. The feed consists of pure N2O4 at 340 K and 202.6 kPa (2 atm). The rate constant of forward reaction is 0.5 min-1 and the equilibrium constant, Kc, at 340 K = 0.1 mol/dm3.
N2O4 
2NO2
Use POLYMATH, calculate the equilibrium conversion of N2O4 in a flow reactor.
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The reversible gas-phase decomposition of nitrogen tetra oxide,
N2O4, to nitrogen dioxide, NO2, is
to be...
Decomposition of nitrogen dioxide dimer N2O4 is described by the reaction: N2O4(g) = 2NO2(g) Concentration of...
Decomposition of nitrogen dioxide dimer N2O4 is described by the reaction: N2O4(g) = 2NO2(g) Concentration of N2O4 became 2 times less after 2,5⋅103 s. You have to calculate: a) the value of rate constant k of the reaction; b) the value of equilibrium constant Kp. You are given the value of standard Gibb’s energy of formation Goform: substance Goform, kJ/mol NO2(g) 51.6 N2O4(g) 98.4
Decomposition of nitrogen dioxide into nitrogen oxide gas is an equillibrium process described by the following...
Decomposition of nitrogen dioxide into nitrogen oxide gas is an equillibrium process described by the following equation: 2NO2(g)--2NO(g)+ O2(g), deltaH=-98.7kj. Predict whether the position of equilberium will shift to the right left or no change. -increase the concentration of NO -Decrease the concentration of NO2 -Increase the pressure by the addition of helium gas -Increase the pressure by decreasing the volume - Decrease the temp -Add a catalyst
15. Consider the reaction 2 NO2(g) N2O4(g) . (a) Using Gf N2O4(g) = 97.79 kJ/mol and...
15. Consider the reaction 2 NO2(g)
N2O4(g) .
(a) Using Gf
N2O4(g) = 97.79 kJ/mol and Gf NO2(g)
= 51.3 kJ/mol, calculate G° at 298 K.
kJ
(b) Calculate G at 298 K if the partial pressures of
NO2 and N2O4 are 0.35 atm and 1.60
atm, respectively.
kJ
16. Consider the reaction given below.
H2(g) + F2(g)
2 HF(g)
(a) Using thermodynamic data from the course website, calculate
G° at 298 K.
kJ
(b) Calculate G at 298 K...
Nitrogen dioxide dimerizes according to the following reaction: 2NO2(g)⇌N2O4(g) Kp=6.7at298K A 2.35-L container contains 0.057 mol...
Nitrogen dioxide dimerizes according to the following reaction: 2NO2(g)⇌N2O4(g) Kp=6.7at298K A 2.35-L container contains 0.057 mol of NO2 and 0.084 molof N2O4at298K. Calculate Kc for the reaction. Express the equilibrium constant with respect to concentration to three significant figures. Calculate Q for the reaction. Express the reaction quotient to three significant figures.
The oxidation of nitric oxide NO + 02 =NO2 takes place in an isothermal batch reactor....
The oxidation of nitric oxide NO + 02 =NO2 takes place in an isothermal batch reactor. The reactor is charged with a mixture containing 20.0 volume percent NO and the balance air at an initial pressure of 380 kPa (absolute). (a) Assuming ideal-gas behavior, determine the composition of the mixture (component mole fractions) and the final pressure (kPa) if the conversion of NO is 90%. (b) Suppose the pressure in the reactor eventually equilibrates (levels out) at 360 kPa. What...
Nitrogen dioxide gas undergoes decomposition producing nitrogen monoxide and oxygen gases: 2 NO2(g)........ 2 NO(g) + O2...
Nitrogen dioxide gas undergoes decomposition producing nitrogen monoxide and oxygen gases: 2 NO2(g)........ 2 NO(g) + O2(g) A sample consisting of 0.10 moles of NO2 is placed in a 10.0 L in a container that is then heated to 750 K. When equilibrium is reached, the pressure in the container is 0.827 bar. Calculate the equilibrium constant and the degree of dissociation at this temperature. (Hint: pressures are directly proportional to concentration, so they can be used in ICE tables).
When heated, colorless dinitrogen tetraoxide, N2O4(g), decomposes into red-brown nitrogen dioxide, NO2(g), according to the following...
When heated, colorless dinitrogen tetraoxide, N2O4(g), decomposes into red-brown nitrogen dioxide, NO2(g), according to the following reaction: N204 (g) + 2 NO2 (g) Suppose that 2.00 mol of N204(g) was placed into an empty 5.00-L flask and heated to 407 K. When equilibrium was attained, the concentration of red-brown NO2(g) was found to be 0.525 M. Calculate the equilibrium constant, K, for this reaction at 407 K. 3.80 2.00 0.500 0.263 0.525
In some aquatic ecosystems, nitrate (NO3–) is converted to nitrite (NO2–), which then decomposes to nitrogen and water....
In some aquatic ecosystems, nitrate (NO3–)
is converted to nitrite (NO2–), which then
decomposes to nitrogen and water. As an example of this second
reaction, consider the decomposition of ammonium nitrite:
$$NH4NO2(aq)N2(g)+2H2O(l)
3rd attempt
See Hint
See Periodic Table
What would be the change in pressure in a sealed 10.0 L vessel
due to the formation of N2gas when the ammonium nitrite
in 2.60 L of 0.800 M NH4NO2 decomposes at
25.0°C?
atm
We were unable to transcribe this imageWe...
Dinitrogen tetraoxide, a colorless gas, exists in equilibrium with nitrogen dioxide, a reddish brown gas. One...
Dinitrogen tetraoxide, a colorless gas, exists in equilibrium with nitrogen dioxide, a reddish brown gas. One way to represent this equilibrium is: N204(0) 2NO2(g) Indicate whether each of the following statements is true, T, or false, F. AT EQUILIBRIUM we can say that: _ 1. The concentration of NO2 is equal to the concentration of N204. _ 2. The rate of the dissociation of N2O4 is equal to the rate of formation of N204. 3. The rate constant for the...
QUESTION 2 Colorless gas nitric oxide gas, NO, can react with oxygen to form the brown gas nitrogen dioxide, NO2, a...
QUESTION 2 Colorless gas nitric oxide gas, NO, can react with oxygen to form the brown gas nitrogen dioxide, NO2, as shown below 2 NO(g)+ O2(g)-2 NO2(g) Suppose you wanted to carry out this reaction in the laboratory. You could filled one gas syringe with 100. mL of nitric oxide and another with 90. mL of oxygen gas. When you connected the syringes and mixed the gases, the reaction mixture changes to a brown color indicating the the reaction had...
15. Consider the reaction 2 NO2(g)
N2O4(g) .
(a) Using Gf
N2O4(g) = 97.79 kJ/mol and Gf NO2(g)
= 51.3 kJ/mol, calculate G° at 298 K.
kJ
(b) Calculate G at 298 K if the partial pressures of
NO2 and N2O4 are 0.35 atm and 1.60
atm, respectively.
kJ
16. Consider the reaction given below.
H2(g) + F2(g)
2 HF(g)
(a) Using thermodynamic data from the course website, calculate
G° at 298 K.
kJ
(b) Calculate G at 298 K...
The oxidation of nitric oxide NO + 02 =NO2 takes place in an isothermal batch reactor. The reactor is charged with a mixture containing 20.0 volume percent NO and the balance air at an initial pressure of 380 kPa (absolute). (a) Assuming ideal-gas behavior, determine the composition of the mixture (component mole fractions) and the final pressure (kPa) if the conversion of NO is 90%. (b) Suppose the pressure in the reactor eventually equilibrates (levels out) at 360 kPa. What...
When heated, colorless dinitrogen tetraoxide, N2O4(g), decomposes into red-brown nitrogen dioxide, NO2(g), according to the following reaction: N204 (g) + 2 NO2 (g) Suppose that 2.00 mol of N204(g) was placed into an empty 5.00-L flask and heated to 407 K. When equilibrium was attained, the concentration of red-brown NO2(g) was found to be 0.525 M. Calculate the equilibrium constant, K, for this reaction at 407 K. 3.80 2.00 0.500 0.263 0.525
In some aquatic ecosystems, nitrate (NO3–)
is converted to nitrite (NO2–), which then
decomposes to nitrogen and water. As an example of this second
reaction, consider the decomposition of ammonium nitrite:
$$NH4NO2(aq)N2(g)+2H2O(l)
3rd attempt
See Hint
See Periodic Table
What would be the change in pressure in a sealed 10.0 L vessel
due to the formation of N2gas when the ammonium nitrite
in 2.60 L of 0.800 M NH4NO2 decomposes at
25.0°C?
atm
We were unable to transcribe this imageWe...
Dinitrogen tetraoxide, a colorless gas, exists in equilibrium with nitrogen dioxide, a reddish brown gas. One way to represent this equilibrium is: N204(0) 2NO2(g) Indicate whether each of the following statements is true, T, or false, F. AT EQUILIBRIUM we can say that: _ 1. The concentration of NO2 is equal to the concentration of N204. _ 2. The rate of the dissociation of N2O4 is equal to the rate of formation of N204. 3. The rate constant for the...
QUESTION 2 Colorless gas nitric oxide gas, NO, can react with oxygen to form the brown gas nitrogen dioxide, NO2, as shown below 2 NO(g)+ O2(g)-2 NO2(g) Suppose you wanted to carry out this reaction in the laboratory. You could filled one gas syringe with 100. mL of nitric oxide and another with 90. mL of oxygen gas. When you connected the syringes and mixed the gases, the reaction mixture changes to a brown color indicating the the reaction had...
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