A 3rd order irreversible reaction takes place in a PFR reactor. The flow entering the PFR...
A 3rd order irreversible reaction takes place in a PFR reactor. The flow entering the PFR has a concentration of A of CA0. The volumetric flow rate is a constant, v0, and the reaction rate constant is kA. Please derive a relation between the concentration of A (CA) with respect to the volume of PFR, V. Draw a diagram of 1/CA2 vs. V. PLOT
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A 3rd order irreversible reaction takes place in a PFR reactor.
The flow entering the PFR...
The irreversible gas phase rxn, A=> B+C is performed in an adiabatic, 800‐liter PFR with a rate...
The irreversible gas phase rxn, A=> B+C is performed in
an adiabatic, 800‐liter PFR with a rate constant, k, as
below: k=60*exp(‐5000/T) s‐1 The feed is pure A at 15 bar and 450 K
with a volumetric flow rate of 1.956 L/s. The heat of
rxnis ‐12 kJ/mol(independent of temperature), heat
capacities are CPA= 40 J/mol/K, CPB= 15 J/mol/K, and CPC
= 25 J/mol/K. The reaction is operated at constant
pressure Plot (a) FAand FBversus reactor volume (b) Temperature
versus reactor volume (c) volumetric flow...
The reaction A ------> B (1) with rate constant, k1= 0.5 min-1 at 400 K is...
The reaction A ------> B (1) with rate constant, k1= 0.5 min-1 at 400 K is to be carried out in an isothermal PFR. However, a second reaction A ----> C (2) with rate constant, k2= 0.1 min-1at 400 K occurs concurrently with reaction (1). The concentration of Ain the feed is CA0= 2 mol dm-3 and the volumetric flow rate of the feed is v0= 4 dm3min-1. (a) Determine the mean residence time, t and the reactor volume, V...
QUESTION 5 The following gas-phase reaction takes place in a plug flow reactor (a tubular reactor)...
QUESTION 5 The following gas-phase reaction takes place in a plug flow reactor (a tubular reactor) that has a diameter of 6 inches and cross sectional area of 0.1 ft2. A C.The reaction rate depends only on the concentration of A, CA, and has the following form: rate of destruction of A-k * CA , where k= 0.124 s-1. The feed consists of pure A, and enters the reactor at a volumetric flowrate of 0.22 ft3/s. Determine the required length...
e unknown-order irreversible reaction takes place in a batch reactor. The initial concentrations A (CAD) is...
e unknown-order irreversible reaction takes place in a batch reactor. The initial concentrations A (CAD) is 10 mol dm-3, and the reaction constant, k1, is 0.5 (its unit is unknown). After multiple experiments, the concentraion change of A over the reaction is measured as below. Please, determine the order of reaction and explain your reasoning. AAR t = np.array([1, 2, 3, 4,5, 6, 7, 8, 9, 101) CA = np.array([0.499, 0.353, 0.289, 0.250.0.224.0.204.0.189, 0.177.0.167,0.158)
PROBLEM 2 The elementary liquid phase irreversible reaction (A+B -> C) takes place in a 1...
PROBLEM 2 The elementary liquid phase irreversible reaction (A+B -> C) takes place in a 1 m² Mixed Flow Reactor with the equimolar mixture of A and B at the volumetric feed flow rate of 0.5 m3/min, the feed concentration of A equal to 1 mol/L, and the feed temperature of 300K. When the reaction takes place under isothermal conditions at 300K the conversion of A is 30%. When the reaction takes place adiabatically the exit temperature is 350K and...
The following first-order gas-phase reaction occurs in an isothermal, isobaric PFR reactor: A->2B. There is 60%...
The following first-order gas-phase reaction occurs in an isothermal, isobaric PFR reactor: A->2B. There is 60% A and 40% inert in the initial feed. If the volumetric flow rate at the outlet of the reactor is 1.3 times of the one at entrance, calculate the conversion rate of the reactor. Assume ideal gas law (PQ = NRT)
Continuously operated stirred tank reactor has been design on the assumption of perfect mixing to achieve 90% conversion of the first order reaction. Subsequent flow patterns study (flow visualizatio...
Continuously operated stirred tank reactor has been design on the assumption of perfect mixing to achieve 90% conversion of the first order reaction. Subsequent flow patterns study (flow visualization and RTD measurements) indicate that: (i) 65% of the volume is well mixed, (ii) 20%, of the volume locally exhibits plug flow (ii) 15% volume is inactive and 25% of the feed bypass the reactor. The conversion to be expected from this reactor is to be estimated. Design: У, САЗ-0.1 САО...
Question 1: Design of isothermal reactors 30 Marks The irreversible, gas-phase reaction A+B D is to be carried out...
Question 1: Design of isothermal reactors 30 Marks The irreversible, gas-phase reaction A+B D is to be carried out in an isotherma °C) plug-flow reactor (PFR) at 5.0 atm. The mole fractions of the feed streams are A 0 B 0.50, and inerts 0.30. The activation energy for the above reaction is 80 000 cal/mol. the pressure drop due to fluid friction in the reactor is so small that it can be ignored, perform the following tasks: 2T a s...
Exercise 4.4: Catalyst deactivation in a batch reactor Consider the irreversible, liquid-phase isomerization reaction carried out...
Exercise 4.4: Catalyst deactivation in a batch reactor Consider the irreversible, liquid-phase isomerization reaction carried out in a solvent containing dissolved catalyst at 25°C in a batch reactor Aka B The apparent first-order reaction-rate constant, ka, decreases with time because of cat- alyst deterioration. A chemist colleague of yours has studied the catalyst deactivation process and has proposed that it can be modeled by ka= Tt kat in which k is the fresh catalyst rate constant and ka is the...
The second order gas phase irreversible reaction: 2.4-B is carried out in an isothermal batch reactor...
The second order gas phase irreversible reaction: 2.4-B is carried out in an isothermal batch reactor containing 40 kg of catalyst and with an initial volume of 60-liter. The reactor is initially filled with equal molar quantities of A and inert I at 300 K and 2.5 atm. Calculate the time needed for the concentration of product (B) to be 0.02 mole/liter if: a) the reaction takes in a constant pressure batch reactor (3 points) b) the reaction takes place...
The irreversible gas phase rxn, A=> B+C is performed in
an adiabatic, 800‐liter PFR with a rate constant, k, as
below: k=60*exp(‐5000/T) s‐1 The feed is pure A at 15 bar and 450 K
with a volumetric flow rate of 1.956 L/s. The heat of
rxnis ‐12 kJ/mol(independent of temperature), heat
capacities are CPA= 40 J/mol/K, CPB= 15 J/mol/K, and CPC
= 25 J/mol/K. The reaction is operated at constant
pressure Plot (a) FAand FBversus reactor volume (b) Temperature
versus reactor volume (c) volumetric flow...
QUESTION 5 The following gas-phase reaction takes place in a plug flow reactor (a tubular reactor) that has a diameter of 6 inches and cross sectional area of 0.1 ft2. A C.The reaction rate depends only on the concentration of A, CA, and has the following form: rate of destruction of A-k * CA , where k= 0.124 s-1. The feed consists of pure A, and enters the reactor at a volumetric flowrate of 0.22 ft3/s. Determine the required length...
e unknown-order irreversible reaction takes place in a batch reactor. The initial concentrations A (CAD) is 10 mol dm-3, and the reaction constant, k1, is 0.5 (its unit is unknown). After multiple experiments, the concentraion change of A over the reaction is measured as below. Please, determine the order of reaction and explain your reasoning. AAR t = np.array([1, 2, 3, 4,5, 6, 7, 8, 9, 101) CA = np.array([0.499, 0.353, 0.289, 0.250.0.224.0.204.0.189, 0.177.0.167,0.158)
PROBLEM 2 The elementary liquid phase irreversible reaction (A+B -> C) takes place in a 1 m² Mixed Flow Reactor with the equimolar mixture of A and B at the volumetric feed flow rate of 0.5 m3/min, the feed concentration of A equal to 1 mol/L, and the feed temperature of 300K. When the reaction takes place under isothermal conditions at 300K the conversion of A is 30%. When the reaction takes place adiabatically the exit temperature is 350K and...
Continuously operated stirred tank reactor has been design on the assumption of perfect mixing to achieve 90% conversion of the first order reaction. Subsequent flow patterns study (flow visualization and RTD measurements) indicate that: (i) 65% of the volume is well mixed, (ii) 20%, of the volume locally exhibits plug flow (ii) 15% volume is inactive and 25% of the feed bypass the reactor. The conversion to be expected from this reactor is to be estimated. Design: У, САЗ-0.1 САО...
Question 1: Design of isothermal reactors 30 Marks The irreversible, gas-phase reaction A+B D is to be carried out in an isotherma °C) plug-flow reactor (PFR) at 5.0 atm. The mole fractions of the feed streams are A 0 B 0.50, and inerts 0.30. The activation energy for the above reaction is 80 000 cal/mol. the pressure drop due to fluid friction in the reactor is so small that it can be ignored, perform the following tasks: 2T a s...
Exercise 4.4: Catalyst deactivation in a batch reactor Consider the irreversible, liquid-phase isomerization reaction carried out in a solvent containing dissolved catalyst at 25°C in a batch reactor Aka B The apparent first-order reaction-rate constant, ka, decreases with time because of cat- alyst deterioration. A chemist colleague of yours has studied the catalyst deactivation process and has proposed that it can be modeled by ka= Tt kat in which k is the fresh catalyst rate constant and ka is the...
The second order gas phase irreversible reaction: 2.4-B is carried out in an isothermal batch reactor containing 40 kg of catalyst and with an initial volume of 60-liter. The reactor is initially filled with equal molar quantities of A and inert I at 300 K and 2.5 atm. Calculate the time needed for the concentration of product (B) to be 0.02 mole/liter if: a) the reaction takes in a constant pressure batch reactor (3 points) b) the reaction takes place...
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