Provide names for the following molecules (don't forget stereochemistry when necessary) b. Ho OH C. d....
1. Provide acceptable IUPAC names for the following compounds. Don't forget stereochemistry if needed. OH L4 Be 041 9.012 3A 4A 5A 6A 7A 400 5 B6 C7 NR 09 F10 Ne 1081 1201 140 16.00 19:00 20:18 Na 12 Mg 299 2431 38 43 58 68 7B B 13 A 14 S 15 P 16 S 17 CI 18 Ar 28269828093097 32.07 35.45 19.95 K 2.09 20 Ca 21 Sc 22 Ti 23 V 40.08 449 47.88 50 94...
Provide the major product(s) for the following reactions: Show Stereochemistry when necessary (9 points total) HBr (1 equivalent) HBr (2 equivalents) Br2 Brz (1 equivalent) CH,CI, (2 equivalents) CH,CI, HO 1) disyamylborane HgSo., H2SO4 2) H0, NaOH, H2O Bonus: Provide the major product(s) for the following reactions: Show Stereochemistry when necessary (4 points total) 1) NaNH, (1) NaNH, 2) (CH),CHCH,Br 2) (CH),CHCH,Br 3) H, 3) L, NH, Lindlar's catalyst 1) NaNH, 2) EtBr 3) Hz, Pd/C 1) NaNH, 2) EtBr...
5. Please determine the double bond stereochemistry for the following molecules. (a) A: E; B: E (b) A: E; B: Z (c) A: Z; B: Z (d) A: Z; B: E 6. What would be the final major product (or products) of the following reaction sequence? Consider substitution pathways, only. (a) (b) (c) (d) (e) an equal mixture of (c) and (d) would be isolated 7. What would be the first step in the dehydration of an alcohol in sulfuric...
Provide the major product(s) for the following reactions: Show Stereochemistry when necessary (10 points total) Br HBr CH2CI Br2 HBr Но ROOR CH,OH Н,о н* Н,о° 1) Hg(O,CCF3)2 CH,OH 1) BН, THF 2) H,О, NaOH, Нао 2) NaBH, NaOH 1) Hg(OAc) Н0, THF/ Hа Pd/C 2) NaBH, NaOH
1.Give the IUPAC names for the following molecules OH Ho 2. Predict the products in the following reactions. You must draw these in the correct skeletal structure for credit. You only need to draw products that contain carbon atoms; however, you're welcome to draw side products if it helps you If there is no reaction, write an "X" or "no reaction in the products. to] OH loj он H SO4 excess (H
1. Provide products for the following reactions. Show appropriate stereochemistry where appropriate. HI H2SO4 CH,OH 1. Hg(OAc),/H,0 2. NaBH4 1. BH; 2. H,Oz/NaOH H/Pd H2SO4/H2O 4. Provide the missing reagents or starting materials in the following reactions. OH Br HO 1. Br2 2, NaNH (excess) 3. H2O
Question 5 Provide the reagents necessary to carry out the following conversion. HO 1. HOCH CH,OH/H2SO4 2. CH3CH2MB (2 e) 3. H,00 1. HOCH2CH2OH/H2SO4 2. LAIN 3. CH CH MgBr (2 ea) 1. H2SO4 2. CH3CH2OH 3. H2O Provide the reagents necessary for the following conversion. Br o 1. NaBH,/CH2OH, 2. CH3CH2MgBr CH3CH2MgBr/ether 1. H307 2. CH3CH2MgBr/ether 1. CH3CH2MgBr/ether, 2. Hz0+, A
3) Which of the following compounds is chiral? A) H Н-С-н н B) H HO C-OH Н C) CH3 HO-C-H Cl D) Br Н-С-ОН н E) C Br- C-C Br 4) In the L- isomer of a Fischer projection of a monosaccharide, the -OH group furthest from the carbonyl is written A) on the left of the top chiral carbon B) on the right of the top chiral carbon C) on the left of the middle chiral carbon D) on...
3) Provide a synthesis of the following molecules. Be sure to show all reagents and isolable products. No mechanisms required. Full credit to those syntheses that maximize yield and minimize side products. HO a) OEt b) and any alcohols Br HO Ho 요 c) OMe OH Br d) 0 OH e)
For each reaction, provide the starting material, product, or reagents. Indicate stereochemistry when present. HO(CH2)2OH, H+ (-H,0) Na2Cr2O7 H2SO4, H20 HNED, H, heat (-H20) OH, heat OH (H20) Ph Y Ph HS(CH2)2SH, H (-H,0) HOY OH