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1. Provide products for the following reactions. Show appropriate stereochemistry where appropriate. HI H2SO4 CH,OH 1....
Provide the major product(s) for the following reactions: Show Stereochemistry when necessary HBr Br2 CH2Cl2 HBr Br2 ROOR H20 H2O СН,ОН H30* 1) BH3, THE 2) H2O2, NaOH, H2O 1) Hg(O2CCF3)2 CH3OH 2) NaBH4, NaOH 1) Hg(OAc)2, H20, THF 2) NaBH4, NaOH H2 Pd/C
Draw the products for the following reactions. Clearly indicate stereochemistry where important. 6. Draw the products for the following reactions. Clearly indicate the stereochemistry where important. 12 pts Br- 1.0, 2. Zn, HO CH,OH KMnO4 1. BH3 2 NaOH, H,0 1. Os0 2. NaHSO3 CHCl,. NaOH Br2 H2. Pd 1. Hg(OAc, HO 2. NaBH
Provide the major product(s) for the following reactions: Show Stereochemistry when necessary (9 points total) HBr (1 equivalent) HBr (2 equivalents) Br2 Brz (1 equivalent) CH,CI, (2 equivalents) CH,CI, HO 1) disyamylborane HgSo., H2SO4 2) H0, NaOH, H2O Bonus: Provide the major product(s) for the following reactions: Show Stereochemistry when necessary (4 points total) 1) NaNH, (1) NaNH, 2) (CH),CHCH,Br 2) (CH),CHCH,Br 3) H, 3) L, NH, Lindlar's catalyst 1) NaNH, 2) EtBr 3) Hz, Pd/C 1) NaNH, 2) EtBr...
2. Provide the MAJOR product(s) and/or missing starting materials for the reactions below. (5.5 pts) Hint: please apply Mark's rule wherever it is necessary + H-Br A. +HO-CI B. C. D. Br Br2- F. Br 1) Hg(OAc)a, H2O 2) NaBH4, NaOH G. Hint: th them, ls next to
3. Identify (draw the structure showing stereochemistry where required) ALL of the missing reactant, reagents, or major product to complete the following transformations. CH2l2, Zn(Cu) Br Biz excess H20 Тон Hz. Pd/C ether o - - HCI H2O NaOH H₂O Excess 1. Hg(OAc), H20 2. NaBH4 HBT CH,C12 Excess 1. BH, THF 2. H2O2, H20
Provide the products and mechanisms of the reactions of 1-methylcyclohexene with the following reagents: A.) CHBr3, OH- B.) Simmons-Smith Reagent C.) H+, H2O D.) 1. BH3 * THF, then 2. OH-, H2O2 E.) 1. Hg (OAc)2, H2O; then 2. NaBH4 F.) H2, Ni G.) Br2 H.) Br2, H2O
Provide the major product(s) for the following reactions: Show Stereochemistry when necessary (10 points total) Br HBr CH2CI Br2 HBr Но ROOR CH,OH Н,о н* Н,о° 1) Hg(O,CCF3)2 CH,OH 1) BН, THF 2) H,О, NaOH, Нао 2) NaBH, NaOH 1) Hg(OAc) Н0, THF/ Hа Pd/C 2) NaBH, NaOH
Predict the major product(s) of the following reactions. Show stereochemistry where appropriate. 3 CO3H i) OsO4 H ii) NaHSO3, H2O CHC13, KOH any cha, kot i) BH3, THF CECH 11) H2O2, NaOH Li NH (liquid) cm X Ft, H/HO (vii) Two Markovnikov products Draw the structure of alkene for each of the following reactions. OH i) BH, THF 11) H202, NaOH 1) Hg(OAc)2, H20 ii) NaBH4 1) 03 ii) Zn/H Styrene undergoes propagation to give polystyrene. Showing electron-flow using half-headed...
Provide the major organic product (including stereochemistry if appropriate) for each of the following reactions: 3. 1) NaH а) (CH)-СHCH,ОН 2) (CH),СНОСH-CH,Br b) excess HI 1) Hg(OAc),/H,O 2) NaBHĄ/HO¯ 1) NaOH 2) PҺOH d) CH,CH,Br 1) BH3/THF 2) H-0,/Но" НCIZnClz он g) MCPBA h) 1) mCPBA 2) CH3O¯ 1) mCPBA 2) CH,ОН/Н"
1. PREDICT THE PRODUCT: Provide the structure of the major product expected from the following reactions or reaction sequences. Make sure you account for any regio- and/or stereochemistry! (24 pts.) H2O 1. Hg(OAC), CH, OH 2. NaBH H2SO4 H20 1) BH-THF 2) H202, KOH HBr Bry, H2O HBr ROOR 1. BH3-THF 2. H2O2, NaOH H20, H2SO4 1. NaNH2 H2 H-CEC-CH2 CH2 CH3 2. CH CH Br Lindlar cat 1. Sia BH-THF 2. H2O2, H2O