Provide the products and mechanisms of the reactions of 1-methylcyclohexene with the following reagents: A.) CHBr3,...
Provide the products and mechanisms of the reactions of 1-methylcyclohexene with the following reagents:
A.) CHBr3, OH-
B.) Simmons-Smith Reagent
C.) H+, H2O
D.) 1. BH3 * THF, then 2. OH-, H2O2
E.) 1. Hg (OAc)2, H2O; then 2. NaBH4
F.) H2, Ni
G.) Br2
H.) Br2, H2O
Homework Answers
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Provide the products and mechanisms of the reactions of
1-methylcyclohexene with the following reagents:
A.) CHBr3,...
Provide the major product(s) for the following reactions: Show Stereochemistry when necessary HBr Br2 CH2Cl2 HBr...
Provide the major product(s) for the following reactions: Show
Stereochemistry when necessary
HBr Br2 CH2Cl2 HBr Br2 ROOR H20 H2O СН,ОН H30* 1) BH3, THE 2) H2O2, NaOH, H2O 1) Hg(O2CCF3)2 CH3OH 2) NaBH4, NaOH 1) Hg(OAc)2, H20, THF 2) NaBH4, NaOH H2 Pd/C
Predict the major organic product or products of each of the following reactions: Identify the mechanism...
Predict the major organic product
or products of each of the following reactions:
Identify the mechanism
taking place in each of the reactions and please provide
explanation.
H2SO4 a) (CHỊ) CH CH=CH, HO Hg(OAc)2 NaBH4 b) (CH3)2CH CH=CH2 H2O BH3: THE H2O2, NaOH c) (CH3),CH CH=CH2 H2SO4, H2O d) CHCECH HgSO4 HZ/Ni f) + Cl2 + H2O g) Cold KMnO4 dilute h) 1. CH CO-OH 2. Hz0 Br2 i) CC14
1. Provide products for the following reactions. Show appropriate stereochemistry where appropriate. HI H2SO4 CH,OH 1....
1. Provide products for the following reactions. Show appropriate stereochemistry where appropriate. HI H2SO4 CH,OH 1. Hg(OAc),/H,0 2. NaBH4 1. BH; 2. H,Oz/NaOH H/Pd H2SO4/H2O 4. Provide the missing reagents or starting materials in the following reactions. OH Br HO 1. Br2 2, NaNH (excess) 3. H2O
Starting from 3-methylhex-1-ene as the substrate at the center of your page, draw a reaction map showing the regiochemical and stereochemical outcome or outcomes for each of the following series of reagents. Name each of your products, including stereoche
Starting from 3-methylhex-1-ene as the substrate at the center of your page, draw a reaction map showing the regiochemical and stereochemical outcome or outcomes for each of the following series of reagents. Name each of your products, including stereochemical designations for any chirality centers that are generated.**Pay attention to the possibility of rearrangement when your mechanism produces a carbocation. A. H2SO4, H2OB. 1. Hg(OAc)2, H2O; 2. NaBH4C. 1. BH3•THF; 2. H2O2, NaOHD. Br2, CCl4E. Br2, H2OF. HBrG. HBr, ROORH. 1. O3; 2. DMSI. H2, Pt
What are the best reagents to complete this synthesis? O 1. BH3 – THF; 2. H2O2,...
What are the best reagents to complete this synthesis? O 1. BH3 – THF; 2. H2O2, NaOH; 3. PCC O 1. BHz – THF; 2. H2O2, NaOH; 3. H, CrO4 01. 03; 2. DMS 01. Hg(OAC)2, H2O; 2. NaBH4; 3. PCC Predict the product of the following reaction scheme: 2LIATH H2O OH OH Predict the product for the following reaction | | Identify the reaction sequence of reactions that can achieve the following transformation a- O (1) Br2, CCl4: (2)...
14. Provide all of the organic products for the following transformations: A. Å Br2, CH2CL2 B....
14. Provide all of the organic products for the following transformations: A. Å Br2, CH2CL2 B. 1. Hg(OAC)2, H2O 2.NaBH4 OH C. SOCI2 CH3 Me D 1. BH3 2. NaOH, H2O2
3. Complete the following reactions of the compound shown by drawing the correct products with CORRECT...
3. Complete the following reactions of the compound shown by drawing the correct products with CORRECT stereochemistry if important (10 pts). + Br2 Brain H20 1. 03 2. Mezs Hipo H/Pd 1. Hg(OAC) in THF/water 2. NaBH4, NaOH 1. BH3-THF 2. H2O2, NaOH peroxyacid HBO HBr/peroxide 1. Os04 2. NaHSO3
1. PREDICT THE PRODUCT: Provide the structure of the major product expected from the following reactions...
1. PREDICT THE PRODUCT: Provide the structure of the major product expected from the following reactions or reaction sequences. Make sure you account for any regio- and/or stereochemistry! (24 pts.) H2O 1. Hg(OAC), CH, OH 2. NaBH H2SO4 H20 1) BH-THF 2) H202, KOH HBr Bry, H2O HBr ROOR 1. BH3-THF 2. H2O2, NaOH H20, H2SO4 1. NaNH2 H2 H-CEC-CH2 CH2 CH3 2. CH CH Br Lindlar cat 1. Sia BH-THF 2. H2O2, H2O
please do 1-6 the reagents are listed to the right. and each regeant needs to be...
please do 1-6
the
reagents are listed to the right. and each regeant needs to be
reacted with each alkene substrates on the left.
React each of the alkene substrates on the left with each of the reagents on the right If you see fit. provide kinetic and theromdinamic products as well as all possible diastereomere 10}} 8 1) HBr 2) Br2 3) H2O, H+ 4) Br2, H2O 5) O3, PPh 6) HBr, Peroxides 7) Hg(OAc)2, H2O, NaBH4 8) BH3,...
5.27 Give the principal organic products expected when 1-butene reacts with each of the following reagents...
5.27 Give the principal organic products expected when 1-butene reacts with each of the following reagents (a) Br2 in CH2Cl2 solvent (b) O3, -78 oc (c) product of (b) with (CH3)2S (d) product of (b) with H202 (e) O2, flame (f) HBr (g) I2, H20 (h) H2, Pt/C (i) HBr, peroxides (j) BH3 in tetrahydrofuran (THF) (k) product of G) with NaOH, H,02 (1) Hg(OAc), H2O (m) product of (I) with NaBH4/NaOH (n) HI (o) HI, AIBN
Provide the major product(s) for the following reactions: Show
Stereochemistry when necessary
HBr Br2 CH2Cl2 HBr Br2 ROOR H20 H2O СН,ОН H30* 1) BH3, THE 2) H2O2, NaOH, H2O 1) Hg(O2CCF3)2 CH3OH 2) NaBH4, NaOH 1) Hg(OAc)2, H20, THF 2) NaBH4, NaOH H2 Pd/C
Predict the major organic product
or products of each of the following reactions:
Identify the mechanism
taking place in each of the reactions and please provide
explanation.
H2SO4 a) (CHỊ) CH CH=CH, HO Hg(OAc)2 NaBH4 b) (CH3)2CH CH=CH2 H2O BH3: THE H2O2, NaOH c) (CH3),CH CH=CH2 H2SO4, H2O d) CHCECH HgSO4 HZ/Ni f) + Cl2 + H2O g) Cold KMnO4 dilute h) 1. CH CO-OH 2. Hz0 Br2 i) CC14
1. Provide products for the following reactions. Show appropriate stereochemistry where appropriate. HI H2SO4 CH,OH 1. Hg(OAc),/H,0 2. NaBH4 1. BH; 2. H,Oz/NaOH H/Pd H2SO4/H2O 4. Provide the missing reagents or starting materials in the following reactions. OH Br HO 1. Br2 2, NaNH (excess) 3. H2O
What are the best reagents to complete this synthesis? O 1. BH3 – THF; 2. H2O2, NaOH; 3. PCC O 1. BHz – THF; 2. H2O2, NaOH; 3. H, CrO4 01. 03; 2. DMS 01. Hg(OAC)2, H2O; 2. NaBH4; 3. PCC Predict the product of the following reaction scheme: 2LIATH H2O OH OH Predict the product for the following reaction | | Identify the reaction sequence of reactions that can achieve the following transformation a- O (1) Br2, CCl4: (2)...
14. Provide all of the organic products for the following transformations: A. Å Br2, CH2CL2 B. 1. Hg(OAC)2, H2O 2.NaBH4 OH C. SOCI2 CH3 Me D 1. BH3 2. NaOH, H2O2
3. Complete the following reactions of the compound shown by drawing the correct products with CORRECT stereochemistry if important (10 pts). + Br2 Brain H20 1. 03 2. Mezs Hipo H/Pd 1. Hg(OAC) in THF/water 2. NaBH4, NaOH 1. BH3-THF 2. H2O2, NaOH peroxyacid HBO HBr/peroxide 1. Os04 2. NaHSO3
1. PREDICT THE PRODUCT: Provide the structure of the major product expected from the following reactions or reaction sequences. Make sure you account for any regio- and/or stereochemistry! (24 pts.) H2O 1. Hg(OAC), CH, OH 2. NaBH H2SO4 H20 1) BH-THF 2) H202, KOH HBr Bry, H2O HBr ROOR 1. BH3-THF 2. H2O2, NaOH H20, H2SO4 1. NaNH2 H2 H-CEC-CH2 CH2 CH3 2. CH CH Br Lindlar cat 1. Sia BH-THF 2. H2O2, H2O
please do 1-6
the
reagents are listed to the right. and each regeant needs to be
reacted with each alkene substrates on the left.
React each of the alkene substrates on the left with each of the reagents on the right If you see fit. provide kinetic and theromdinamic products as well as all possible diastereomere 10}} 8 1) HBr 2) Br2 3) H2O, H+ 4) Br2, H2O 5) O3, PPh 6) HBr, Peroxides 7) Hg(OAc)2, H2O, NaBH4 8) BH3,...
5.27 Give the principal organic products expected when 1-butene reacts with each of the following reagents (a) Br2 in CH2Cl2 solvent (b) O3, -78 oc (c) product of (b) with (CH3)2S (d) product of (b) with H202 (e) O2, flame (f) HBr (g) I2, H20 (h) H2, Pt/C (i) HBr, peroxides (j) BH3 in tetrahydrofuran (THF) (k) product of G) with NaOH, H,02 (1) Hg(OAc), H2O (m) product of (I) with NaBH4/NaOH (n) HI (o) HI, AIBN
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