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14. Provide all of the organic products for the following transformations: A. Å Br2, CH2CL2 B....
Please answer all of them in detail 14. Provide all of the organic products for the following transformations: A. i Bra, CHCI B 1. Hg(OAC)2, H2O 2.NaBHA OH C. SOCI2 CH3 Me D. 1. BH3 2. NaOH, H2O2
Provide the major product(s) for the following reactions: Show Stereochemistry when necessary HBr Br2 CH2Cl2 HBr Br2 ROOR H20 H2O СН,ОН H30* 1) BH3, THE 2) H2O2, NaOH, H2O 1) Hg(O2CCF3)2 CH3OH 2) NaBH4, NaOH 1) Hg(OAc)2, H20, THF 2) NaBH4, NaOH H2 Pd/C
Predict the major organic product or products of each of the following reactions: Identify the mechanism taking place in each of the reactions and please provide explanation. H2SO4 a) (CHỊ) CH CH=CH, HO Hg(OAc)2 NaBH4 b) (CH3)2CH CH=CH2 H2O BH3: THE H2O2, NaOH c) (CH3),CH CH=CH2 H2SO4, H2O d) CHCECH HgSO4 HZ/Ni f) + Cl2 + H2O g) Cold KMnO4 dilute h) 1. CH CO-OH 2. Hz0 Br2 i) CC14
draw the major products for the following transformations and determine whether it is a Markovnikov or anti-Markovnikov(if applicable) Make sure products are stereochemically correct. (Write down each reaction and draw products) 1) BH3. THE 2) H2O2, NaOH, H20 1) Hg(OAC)2, EtOH 2) NaBH4, H30+ 1-Ethylcyclohexene Br2, H2O
Provide the products and mechanisms of the reactions of 1-methylcyclohexene with the following reagents: A.) CHBr3, OH- B.) Simmons-Smith Reagent C.) H+, H2O D.) 1. BH3 * THF, then 2. OH-, H2O2 E.) 1. Hg (OAc)2, H2O; then 2. NaBH4 F.) H2, Ni G.) Br2 H.) Br2, H2O
Predict the major organic product or products of each of the following reactions. H2SO4 a) (CH3),CHCH-CH2- 1. Hg(OAc), H,0 2. NaBH4 b) (CH3)2CHCH=CH, 1. BH3-THF 2. H2O2, NaOH c) (CH3)2CHCH=CH2
5.27 Give the principal organic products expected when 1-butene reacts with each of the following reagents (a) Br2 in CH2Cl2 solvent (b) O3, -78 oc (c) product of (b) with (CH3)2S (d) product of (b) with H202 (e) O2, flame (f) HBr (g) I2, H20 (h) H2, Pt/C (i) HBr, peroxides (j) BH3 in tetrahydrofuran (THF) (k) product of G) with NaOH, H,02 (1) Hg(OAc), H2O (m) product of (I) with NaBH4/NaOH (n) HI (o) HI, AIBN
2 3 tab 4 % 5 Q W E con lo R page 16 8 14. Provide all of the organic products for the following transformations: A Br, CHCI B 1. Ho(OAc), H20 2.NaBH OH SOCI2 CH3 C Me 1. BH 2, NaOH, HOA D
match the right reagent 3 OH + enantiomer + enantiomer 5 CO A.) PBrs B.) NBS, hv C.) D.) NaOH E.) NaNH2 F.) Br2 G.) HCI H.) Cl2, H2O 1.) HBO J.) H2 (1 eq), Pt K.) Na, NH3 L.) H2SO4, H20 M.)1. Hg(OAC)2 0.) N.) 1. mCPBA 2. H+, H2O 2. NaBH4 P.) 1. BH3 2. H2O2, NaOH 3 OH + enantiomer + enantiomer 6 CO A.) PBrs B.) NBS, hv C.) D.) NaOH E.) NaNH2 F.) Br2 G.)...
2. Predict the major organic product(s) of the reactions below. Assume 1 equivalent of reagent unless otherwise stated, it's a solvent, or an oxidizing/reducing agent. Do consider stereochemistry and regioselectivity. 2. Predict the major organic product(s) of the reactions below. Assume 1 equivalent of reagent unless otherwise stated, it's a solvent, or an oxidizing/reducing agent. Do consider stereochemistry and regioselectivity. (3 points each; 15 points total) A. Me 1. HNO3 2. O3 3. DMS 1. mCPBA, DCM (1 equiv) 2....