Answer:
Gievn buffer is formic acid and sodium formate.
pH=pKa+log[salt]/[acid]
Given pKa=3.745, [salt]=[NaHCOO]=0.111 M,
[Acid]=[HCOOH]=0.253 M.
Therefore pH=3.745 + log(0.111/0.253)
pH=3.745 - 0.357=3.387.
pH=3.387.
So option (A) is correct.
Please let me know if you have any doubt. Thanks and I hope you like it.
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