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A 50 mL sample of 0.20 M propionic acid buffer (pKa 4.87 according to Google) has...

A 50 mL sample of 0.20 M propionic acid buffer (pKa 4.87 according to Google) has an initial pH of 4.77. After an unknown amount of 0.25 M HCl is added to the buffer, its pH has been lowered to 4.47. Using the Henderson-Hasselbalch equation, determine what volume of HCl was added to the buffer to cause the pH change, as well as the mass of Pr- necessary to return the buffer to its original pH.

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