Question

1. A solution is prepared containing 5 x 10 6 M selenous acid (H2Seo30) at pH 7.8 and 25°C. a) Write out stepwise mass action reactions for the first and second acid-dissociation reactions. The acid constants are 2.63 (pKa1) and 8.40 (pKa2). (2 marks) b) Write out the overall mass action reaction for complete dissociation of selenous acid and calculate the overall dissociation constant. (2 marks) c) Write out the mass balance equation for selenium, assuming only selenous acid and its conjugate bases are present in solution. (2 marks) d) Calculate [HSeo31 and [Seo3 in mg L under the given conditions. Assume concentration and activity are equivalent. (8 marks) e) How would LHSeo3 and [Seo32n change if the pH was increased to 8.80? (2 marks)

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(b) Overall Mass acfon eachon 2-ven thy -2-63 &千 - 4-63 2 oC 2 2 lonizahion 弋HSeO 48-8 -0 チ67-8 ka = 8.840.43

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