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1. The molecular weight of vanillin (a solid) is 152.15. The molecular weight of acetic anhydride (a liquid) is 102.04 and it

ACID CATALYZED ESTERIFICATION (Start this first) 1. Place 0.15 g vanillin and 1 ml acetic anhydride in a 3 mL conical vial. A

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Answer #1

\begin{aligned}&C_8H_8O_3\;\;\;\;\;+&C_4H_6O_3\;\;\rightleftharpoons \;\;&C_{10}H_{10}O_4\\&1.97\;mmol &8.45\;mmol\;\;\;\;\;&1.97\;mmol\end{aligned}

  1. No. of moles of vaniline  

          \begin{aligned}&= \mathrm{\frac{0.3\;g}{152.15\;g/mol}}\\&=1.97\;mmol \end{aligned}

   No. of moles of acetic anhydride

  \begin{aligned} &= \mathrm{\frac{density\times volume}{M_{wt}}}\\&= \frac{1.082\;g/mL\times0.8\;mL}{102.04}\\&=8.45\;mmol\end{aligned}

answer : option (a)

2. Limiting reagent = moles of vaniline

= 1.97 mmol

3. Theoretical yield = 1.97 mmol

\begin{aligned}&= \mathrm{\frac{1.97\;mmol}{194.15\;g/mol\;(M_{wt}=C_{10}H_{10}O_4)}}\\&=0.38\;g\end{aligned}

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