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8. 80.0 mL of a 1.00 M HCl solution at 20.00 °C is mixed with 80.0 mL of a 1.00 M Ca(OH)2 solution at 20.00 °C. If the final
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Answer #1

Moles of acid =1mol × .08 L/ 1 L

= .08 mol

Moles of base ( as it is dibasic acid its moles will be double then molarity)

=2× 1 mol × .08 L/ 1L

= .16 mol

Moles of base involved in reaction= .08 mol

Total number of moles of acid+ base=

0.08+0.08= 0.16 mol

Volume of solution= 80+80= 160 ml

Mass of solution= 160 g

q= mc( T2-T1)

q= 160g× 4.184J/g°C×(35°C- 20°C)

q=10041.6 J

Enthalpy of neutralisation= q/n

∆H= 10041.6/ moles of acid+ base

= 62760 J /mol

= 62.760 kJ/ mol

This value is little high as heat capacity of calorimeter is included in it.

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