Question

Data Table 2: Titration Curve Values pH Value Trial 1 pH Value Trial 2 pH Value (Average) Drops NaOH Added Half- Equivalence
40 4.5 4.5 4.5 50 O7 5 5 60 5.5 5.5 5.5 70 6 6.5 6.25 80 12.5 13 12.75 90 13.5 13.5 13.5 100 13.5 13.5 13.5 110 14 14 14 120
Data Table 3 Graph 1 Data Table 3: Determination of Unknown ? ? pKa of Unknown Weak Acid: Ka of Unknown Weak Acid: Unknown We
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Answer #1

The half-equivalence point is halfway between the equivalence point and the origin. This is the point at which the pH of the solution is equal to the dissociation constant (pKa) of the acid.

titration curve value
Drops of NaOH added pH value (trial 1) pH value (trial 2) average pH
0 2.5 2.5 2.5
10 4.5 4.5 4.5
20 4.5 4.5 4.5
30 4.5 4.5 4.5
40 4.5 4.5 4.5
50 5 5 5
60 5.5 5.5 5.5
70 6 6.5 6.25
80 12.5 13 12.75
90 13.5 13.5 13.5
100 13.5 13.5 13.5
110 14 14 14
120 14 14 14

(trial 1) 16 14 12 10 pH value (trial 1) 8 pH value (trial 1) 6 4 2 0 0 20 40 60 80 100 120 140 Drops of NaOH added

(trial 2) pH value(trial 2) 16 14 O O O 12 10 PH VALUE (TRIAL 2) 8 o © O 0 O 4 O 2 0 0 20 40 60 80 100 120 140 DROPS OF NAOH

titration curve 16 14 12 10 pH value (average) 8 6 -titration curve value 2 0 0 20 40 60 80 100 120 140 Drops of NaOH added

The half-equivalence point pH = pKa = 4.6
pH at The half-equivalence point is in trial 1 pH at The half-equivalence point is in trial 2 average pH pKa
4.6 4.6 4.6 4.6
pH at equivalence point is in trial 1 pH at equivalence point is in trial 2 average pH
9.25 9.75 9.5
pKa Ka pKa Ka
4.6 2.51189E-05 4.6 2.51189E-05
percentage error of pKa
approx value exact value error % error
4.6 4.7 -0.021276596 2.127659574
percentage error of Ka
approx value exact value error % error
2.51189E-05 1.99526E-05 0.258925412 25.89254118

pKa value = 4.6

The pKa of acetic acid is 4.7...and our pKa value = 4.6 which is closes value

so the acid is acetic acid.

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