33. Which would be least likely to form after this series of reactions? Practice 32. Which...
33. What is the product for the following sequence of 1. Acetylchloride, AICI, 2. Zn(Hg), HCI reactions? Practice Which is the major isolated organic product after this series of steps? 1. LDA 2. EIB 3. M,0". Bry 3. NBS 4. PPhy 5. n-Buli 6. acetone 7. m-CPBA B. C. D. D. E. What is the reactant for the following sequence of reactions? 1. NOEI 2. HA OH 3. H,O heat 5. LDA & EB 7. NAH, OH & olyang 315...
a.) H H_Cro acetone b.) 1. XS KMnO,/KOH/HOIA 2.H30* c.) ni XS NaBH,, H,0 H OH d.) o 1. XS LAIH/THF/-78 °C 2. H20 H OH e.) NaNH / lig NH3 f.) Br 1. Mg/THE 2. CO2 3. H30 9.) Ph Ph cyclopropene HF CH h.) OH 1. PCCICH.CH 2. Pri 3. N,Cag) 1. LITHF 2.CO 3. NH.Ca) HNO, NH 1. HNO () 2. NaSCH CH.CH AICI, 3-chloro-2-methylpentane m.) 1.Pr.CI. AICI 2. NBS, CCH n.) OH XS H.COM acetone OH...
What are the products (with stereochemistry) of these
rxns?
(CH3) CHCCI AIC b) NaOCH,CH CH CH,OH c) Br2 CH,NH NO FeBry d) o O 1. NaOCH CHs 2. (CH) CHCH2Br 3. HCKaq). A CH,CH OCCH COCH CH e) CH2CH3 1. KMnO4(aq) 2. SO3. H2S04 NaOH triglceride CH,CH2NH2 (large xs) Br h)
Which of the following reaction sequences would accomplish the chemical transformation, shown below? (choose all correct) 1. CH CH2MgBr, then H20; 2. PCC CH3CH2MgBr, then H20 1. Cros. H2SO4: 2. SOCI:3. LICU(CH2CH3)2, the H2O 1. Cros. H2SO4; 2.CH,OH, H2SO4:3. CH3CHMgCl, then H2O
6. Which one of the following series of reactions does not produce a primary amine? 1) LIAIH, (excess) 1) Fe, HCI, H2O A) PHCN B) PhNO2 c) PhNHCCHE 2) H20 2) NaOH, HAO 1) LIAIH4 (excess) 2) H20 H, Raney-Ni NaOH, H2O, heat D) PhCHENH E) PHNHCCH,
Ph cyclopropene HF CH h) OH 1. POCICH.Ch 2. Pri 3 NH4Cl ag) 1.) 1. Li/THE 2.CO 3.NH.CH HNO k.) NH 1. HNO (aq) 2. NaSCH CH.CH AICI, 3-chloro-2-methylpentane m.) 1.Pr.CI. AICI 2. NBS, CCU. n) -OH XS H.CO acetone он 0.) OH XS Bobbit's SiO, CH.CH -OH 1. Ch. AICI 2 NaOH, 30 C 4,000 psi 3. HCI 9.) SCH 2Na, ETOH, NH, r.) 1. LIETO 2. oxirane 3. H,00 1.2 PY-MOBI OMe 2. NHCl(aq) t.) 1. Cl/ Feer...
5. Match the reagents to the corresponding reaction. I Cl NH2 OH II NH2 G. H20 A. SOCI2, pyridine B. Ethanol, pyridine H. xs CH3CH2NH2 I. 1) LIAI(OR)sH 2) H2O C. 1) xs LAH 2) H20 J. (CH3CH2)2CuLi D. 1) xs CH3CH2MgBr 2) H2O K. xs NH3 E. 1) NaOH 2) H30 L. 1) NaOH 2) CH3CH2CH2COCI F. 1) DIBAH 2) H20 M.Butanol, H
5. Match the reagents to the corresponding reaction. OH NH2 II NH2 G. H2O A. SOCI2, pyridine H. xs CH3CH2N H2 B. Ethanol, pyridine I. 1) LIAI(OR)sH 2) H20 C. 1) xs LAH 2) H20 J. (CH2CH2)2CuLi D. 1) xs CH3CH2M9 Br 2) H2O K. xs NH3 E. 1) NAOH 2) H,O F. 1) DIBAH 2) H2O L. 1) NaOH 2) CH3CH2CH2COCI M. Butanol, H
1. Which of the followi ch of the following reactions is not readily explained by the Arrhenius concept of acids and bases? a. A. HCl(aq) + NaOH(aq) - NaCl(aq) + H20() b. H30(aq) + OH-(aq) + 2H20(1) c. HCI(g) + NH3(g) - NH4Cl(s) d. HC2H302(aq) + H2O(l) H30*(aq) + C2H302-(ag) e. H30 (aq) + OH-(aq) + 2H2O(aq) 2. Classify each of the following species as Brønsted acid or base or both: a) H20, b) OH", c) H30, d) NH3, e)...
1. Which of the followi ch of the following reactions is not readily explained by the Arrhenius concept of acids and bases? a. A. HCl(aq) + NaOH(aq) - NaCl(aq) + H20() b. H30(aq) + OH-(aq) + 2H20(1) c. HCI(g) + NH3(g) - NH4Cl(s) d. HC2H302(aq) + H2O(l) H30*(aq) + C2H302-(ag) e. H30 (aq) + OH-(aq) + 2H2O(aq) 2. Classify each of the following species as Brønsted acid or base or both: a) H20, b) OH", c) H30, d) NH3, e)...