What are the products (with stereochemistry) of these rxns?
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What are the products (with stereochemistry) of these
rxns?
(CH3) CHCCI AIC b) NaOCH,CH CH CH,OH...
Ph cyclopropene HF CH h) OH 1. POCICH.Ch 2. Pri 3 NH4Cl ag) 1.) 1. Li/THE...
Ph cyclopropene HF CH h) OH 1. POCICH.Ch 2. Pri 3 NH4Cl ag) 1.) 1. Li/THE 2.CO 3.NH.CH HNO k.) NH 1. HNO (aq) 2. NaSCH CH.CH AICI, 3-chloro-2-methylpentane m.) 1.Pr.CI. AICI 2. NBS, CCU. n) -OH XS H.CO acetone он 0.) OH XS Bobbit's SiO, CH.CH -OH 1. Ch. AICI 2 NaOH, 30 C 4,000 psi 3. HCI 9.) SCH 2Na, ETOH, NH, r.) 1. LIETO 2. oxirane 3. H,00 1.2 PY-MOBI OMe 2. NHCl(aq) t.) 1. Cl/ Feer...
1. Provide products for the following reactions. Show appropriate stereochemistry where appropriate. HI H2SO4 CH,OH 1....
1. Provide products for the following reactions. Show appropriate stereochemistry where appropriate. HI H2SO4 CH,OH 1. Hg(OAc),/H,0 2. NaBH4 1. BH; 2. H,Oz/NaOH H/Pd H2SO4/H2O 4. Provide the missing reagents or starting materials in the following reactions. OH Br HO 1. Br2 2, NaNH (excess) 3. H2O
a.) H H_Cro acetone b.) 1. XS KMnO,/KOH/HOIA 2.H30* c.) ni XS NaBH,, H,0 H OH...
a.) H H_Cro acetone b.) 1. XS KMnO,/KOH/HOIA 2.H30* c.) ni XS NaBH,, H,0 H OH d.) o 1. XS LAIH/THF/-78 °C 2. H20 H OH e.) NaNH / lig NH3 f.) Br 1. Mg/THE 2. CO2 3. H30 9.) Ph Ph cyclopropene HF CH h.) OH 1. PCCICH.CH 2. Pri 3. N,Cag) 1. LITHF 2.CO 3. NH.Ca) HNO, NH 1. HNO () 2. NaSCH CH.CH AICI, 3-chloro-2-methylpentane m.) 1.Pr.CI. AICI 2. NBS, CCH n.) OH XS H.COM acetone OH...
Consider the following molecules: b. а. CHS CH3 O NH— CH—CH2—ОН NH2-CH-C-OH CHз d. C. CHз...
Consider the following molecules: b. а. CHS CH3 O NH— CH—CH2—ОН NH2-CH-C-OH CHз d. C. CHз о Но-СН—С—ОН НО—С—С—С—ОН CH3 [Select ] i. Which of the molecules above is a secondary amine? ii. Which of the molecules above will be a zwitterion under physiological conditions (pH 7)? (Select) [Select ] ii. Which of the molecules above has two acidic protons?
2 problems REVIEW Topics [References) CH HC OCH Br2 CH3 B H3C CH,OH H₂C CH₂ Electrophilic...
2 problems
REVIEW Topics [References) CH HC OCH Br2 CH3 B H3C CH,OH H₂C CH₂ Electrophilic addition of hypohalous acids to alkenes yields a 1,2-haloalcohol called a halohydrin. Halohydrin formation, however, does not result from the addition of HOBr, for example. Instead the addition is done indirectly by reaction of the alkene with Br, in the presence of water. The reaction also works with Cl2 to give chlorohydrins instead of bromohydrins. The reaction proceeds through a cyclic intermediate known as...
practice questions ③ show the product on products Expected for the reactions below a) + CH₃OH...
practice questions
③ show the product on products Expected for the reactions below a) + CH₃OH alcohol c-c-c aldehyde c-c-c acid C b) 014 + CH3 CH alcohol ÖH c) -10 kmnog LOH heat (Excess) cox - Bonus! 0: CEN: d) -10- H₂ Pd/c. (Excess H2) (Red) H -Bones! e) ÖH ć. + -10 alcohol он acid croch Grid x + CH₃ CH₂ 0 4 (drohol) -10 NH₂ 3 continued - show prodoct (s) رخ دن 2) 15 PH:10 NaOH...
18. Draw the structures of Compound 18a. and 18b. (18 pts), clearly indicate your assignments of...
18. Draw the structures of Compound 18a. and 18b. (18 pts), clearly indicate your assignments of all proton resonances (8 pts). Calculate the Unsaturation Index of each compound (4 pts) (30 points total) 30 Unsat. Index = (2C+2-H-X+NY2 = 200 25 e = 2.00 ppm, 4.90 f = 1.27 ppm, 20 720 Compound 18a: C,H,O, singlet, 2H triplet, 3H 127 15 d = 2.66 ppm, a = 7.21 ppm, b = 7.18 ppm, doublet, 2H doublet, 2H C = 4.90...
I hope the answer is clear and correct thanks Question 1 (1 point) What is the...
I hope the answer is clear and correct thanks
Question 1 (1 point) What is the change in enthalpy (in kJ mol'?) for the following reaction F2(g) + Cabr,(s) CaF() + Brz(1) O 1) -112 kJmo12 O2) 504 kJmo11 03) -504 kJmol 1 04) 537 kJmo11 O 5) -537 kJmol'i Question 2 (1 point) What is true about the following reaction at 25°C? F,(g) + 2HCl(g) 2 2017(g) + H (9) Ahrº=76 kJ mol'i Asr°=-10.13 J mol'i Ki Agrº=79 kJ...
Ph cyclopropene HF CH h) OH 1. POCICH.Ch 2. Pri 3 NH4Cl ag) 1.) 1. Li/THE 2.CO 3.NH.CH HNO k.) NH 1. HNO (aq) 2. NaSCH CH.CH AICI, 3-chloro-2-methylpentane m.) 1.Pr.CI. AICI 2. NBS, CCU. n) -OH XS H.CO acetone он 0.) OH XS Bobbit's SiO, CH.CH -OH 1. Ch. AICI 2 NaOH, 30 C 4,000 psi 3. HCI 9.) SCH 2Na, ETOH, NH, r.) 1. LIETO 2. oxirane 3. H,00 1.2 PY-MOBI OMe 2. NHCl(aq) t.) 1. Cl/ Feer...
1. Provide products for the following reactions. Show appropriate stereochemistry where appropriate. HI H2SO4 CH,OH 1. Hg(OAc),/H,0 2. NaBH4 1. BH; 2. H,Oz/NaOH H/Pd H2SO4/H2O 4. Provide the missing reagents or starting materials in the following reactions. OH Br HO 1. Br2 2, NaNH (excess) 3. H2O
a.) H H_Cro acetone b.) 1. XS KMnO,/KOH/HOIA 2.H30* c.) ni XS NaBH,, H,0 H OH d.) o 1. XS LAIH/THF/-78 °C 2. H20 H OH e.) NaNH / lig NH3 f.) Br 1. Mg/THE 2. CO2 3. H30 9.) Ph Ph cyclopropene HF CH h.) OH 1. PCCICH.CH 2. Pri 3. N,Cag) 1. LITHF 2.CO 3. NH.Ca) HNO, NH 1. HNO () 2. NaSCH CH.CH AICI, 3-chloro-2-methylpentane m.) 1.Pr.CI. AICI 2. NBS, CCH n.) OH XS H.COM acetone OH...
Consider the following molecules: b. а. CHS CH3 O NH— CH—CH2—ОН NH2-CH-C-OH CHз d. C. CHз о Но-СН—С—ОН НО—С—С—С—ОН CH3 [Select ] i. Which of the molecules above is a secondary amine? ii. Which of the molecules above will be a zwitterion under physiological conditions (pH 7)? (Select) [Select ] ii. Which of the molecules above has two acidic protons?
2 problems
REVIEW Topics [References) CH HC OCH Br2 CH3 B H3C CH,OH H₂C CH₂ Electrophilic addition of hypohalous acids to alkenes yields a 1,2-haloalcohol called a halohydrin. Halohydrin formation, however, does not result from the addition of HOBr, for example. Instead the addition is done indirectly by reaction of the alkene with Br, in the presence of water. The reaction also works with Cl2 to give chlorohydrins instead of bromohydrins. The reaction proceeds through a cyclic intermediate known as...
practice questions
③ show the product on products Expected for the reactions below a) + CH₃OH alcohol c-c-c aldehyde c-c-c acid C b) 014 + CH3 CH alcohol ÖH c) -10 kmnog LOH heat (Excess) cox - Bonus! 0: CEN: d) -10- H₂ Pd/c. (Excess H2) (Red) H -Bones! e) ÖH ć. + -10 alcohol он acid croch Grid x + CH₃ CH₂ 0 4 (drohol) -10 NH₂ 3 continued - show prodoct (s) رخ دن 2) 15 PH:10 NaOH...
18. Draw the structures of Compound 18a. and 18b. (18 pts), clearly indicate your assignments of all proton resonances (8 pts). Calculate the Unsaturation Index of each compound (4 pts) (30 points total) 30 Unsat. Index = (2C+2-H-X+NY2 = 200 25 e = 2.00 ppm, 4.90 f = 1.27 ppm, 20 720 Compound 18a: C,H,O, singlet, 2H triplet, 3H 127 15 d = 2.66 ppm, a = 7.21 ppm, b = 7.18 ppm, doublet, 2H doublet, 2H C = 4.90...
I hope the answer is clear and correct thanks
Question 1 (1 point) What is the change in enthalpy (in kJ mol'?) for the following reaction F2(g) + Cabr,(s) CaF() + Brz(1) O 1) -112 kJmo12 O2) 504 kJmo11 03) -504 kJmol 1 04) 537 kJmo11 O 5) -537 kJmol'i Question 2 (1 point) What is true about the following reaction at 25°C? F,(g) + 2HCl(g) 2 2017(g) + H (9) Ahrº=76 kJ mol'i Asr°=-10.13 J mol'i Ki Agrº=79 kJ...
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