Question

Lead ions can be precipitated from aqueous solutions by the addition of aqueous iodide: Pb2+(aq) +...

Lead ions can be precipitated from aqueous solutions by the addition of aqueous iodide:

Pb2+(aq) + 2 I-(aq) → PbI2(s)

Lead iodide is virtually insoluble in water so that the reaction appears to go to completion. How many milliliters of 3.550 M HI(aq) must be added to a solution containing 0.100 mol of Pb(NO3)2 to completely precipitate the lead?

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Answer #1

Number of moles of Pb(NO3)2 is 0.100 moles

Number of moles of Pb2+=Number of moles of Pb(NO3)2

Number of moles of Pb2+=0.100 moles

Number of moles of I- required =2 x Number of moles of Pb2+

Number of moles of I- required = 2x 0.100= 0.200 moles

molarity = number of moles * volume in L

Volume of 3.550 M HI = Number of moles of I- / molarity

Volume of 3.550 M HI= 0.200/3.550 = 0.05634 L = 56.34 mL

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