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110060581-E1 (1).pdf 3. Write the equation for the reaction by which 2-bromobutane can be prepared from...
1.1 In which of the following solvents would the reaction of 1-bromobutane with sodium azide,NaN3, proceed...
1.1 In which of the following solvents would the reaction of
1-bromobutane with sodium azide,NaN3, proceed the fastest?
a.aceticacid
b.ethanol
c.water
d.acetonitrile
1.2 Which of the following solvents is the best choice for the
reaction of 1-chlorohexane with sodium bromide?
a.dimethylsulfoxide
b.water
c.hexane
d.toluene,PhCH3
1.3 Which of the following is most likely to undergo
rearrangement during reaction with methanol?
1.4 Name which energy diagrams represents the course of an
exothermic SN1, SN2,E1, or E2 reaction?
1.5 Which of the following...
1. Write the overall balanced reaction equation for the following reactions: 1-bromobutane + CH3CH,OH + AgNO3...
1. Write the overall balanced reaction equation for the following reactions: 1-bromobutane + CH3CH,OH + AgNO3 2-bromobutane + CH,CH,OH + AgNO3 2-bromo2-methylpropane + CH CH OH + AgNO3 — 2. For the solvolysis reaction of 2-bromo-2-methylpropane with ethanol in presence of silver nitrate: a. Write the balanced equation for the reaction b. Identify the substrate, nucleophile, leaving group and the solvent c. What is the role of silver nitrate d. Write the mechanism of the reaction(with arrows showing the movement...
Predict the major product(s) that should form from reaction between 2-bromobutane and each of the following...
Predict the major product(s) that should form from reaction between 2-bromobutane and each of the following substances. By which reaction mechanism is each formed - SN1, SN2 E1 or E2? a. KI in DMF b. NH3 in ethanol c. NaOEt in ethanol d. Ethanol e. (CH3)3COK in (CH3)3COH
help on the problems 4. Write the complete equation for the hydration reaction of the following...
help on the problems
4. Write the complete equation for the hydration reaction of the following alkenes. If more than one product can be formed, indicate which one is the major product. For example, the hydration of ethene is written as follows: H н H он Но + Н-С C-H ethene H H CH2CH3 CH3 CH3 b) CH,CH2 a) CH2CH2CH2CH2CH CH3CH2CH Name the following molecules: 5. CH2CH сH-CH,CнсH,сн, снсH,сн, HF OH H H HH I! ! I a) Cl-c-C-C-c-H II...
_1. An alkyl halide which might be expected to undergo rearrangement under Snl or E1 conditions...
_1. An alkyl halide which might be expected to undergo rearrangement under Snl or E1 conditions is: HZC Br CH3 A. 1 B. | F—CH,BH C. CH3-C-CH-CH, CHz CH3 D. CH3 CH3-C-CH2CH2-Br CH3 E. A Br 2. Your task is to convert 2-chloropentane into 1-pentene. Which reagents would you choose? a) NaOH/H20 b) KOH/CH3OH c) CH3ONa/CH3OH d) CH3CH2ONa/CH3CH2OH e) (CH3)3COK/(CH3)3COH 3. Circle the reaction below which is faster in polar protic solvents. OH,H,O A. CH,CH,CH,Br- CH,CH,CH,OH + Br or SH.RSH...
14) When (R)-2-bromobutane reacts with Cl2/hw, which of the following is true CH3 CH3 H--C1 CH3...
14) When (R)-2-bromobutane reacts with Cl2/hw, which of the following is true CH3 CH3 H--C1 CH3 CH3 A) Only I is formed. B) Only II is formed. C) I and II are formed in equal amounts. D) I and II are formed in unequal amounts. E) I and II could never form under these conditions. 15) Which of the following compounds is more stable? Explain. -CHb. 16) Give the best product for the reaction. CH CH:CH Br, ight 17) Complete...
1.1 What is the equation for the rate of formation of tert-butyl alcohol from the reaction...
1.1 What is the equation for the rate of formation of tert-butyl
alcohol from the reaction of tert-butyl bromide (t-BuBr) with water
by an SN1 mechanism?
A. Rate= k[t-BuBr]
B Rate=k[ t-BuBr][H2O]
C. Rate=k[ H2O]
D. Rate=k[t-BuBr]^2
1.2 What is the equation for the rate of formation of
1-iodobutane from the reaction of 1-chlorobutane (BuCl) with NaI by
an SN2 mechanism?
A. Rate=k[BuCl]
B. Rate=k[BuCl][NaI]
C. Rate=k[NaI]
D. Rate=k[BuCl]^2
1.3 What is the equation for the rate of formation of...
2. (3)For the following reaction: Mg(s) + Ni(NO3)2 (aq) → Mg(NO3)2(aq) + Ni(s) a. Write the...
2. (3)For the following reaction: Mg(s) + Ni(NO3)2 (aq) → Mg(NO3)2(aq) + Ni(s) a. Write the reduction half-reaction: b. Write the oxidation half-reaction: c. What is the reducing agent: d. What is the oxidizing agent? 3. (2) For each of the following 'half-reactions' indicate whether the carbon compound is a) reduced b) oxidized or c) neither oxidized nor reduced and state your reasoning: (a,b or c) ОН CH, CH2-CH=CH2 CH, CH2-CH-CH3 Your reasoning: CH, CH2CH=CH2 howro bob518) abon 2 219160...
Question 20 7.33 pts Identify the major product resulting from the following reaction. 1) BH3-THE 2)...
Question 20 7.33 pts Identify the major product resulting from the following reaction. 1) BH3-THE 2) CH,CO,D CH3 c) D D сн. CH CH3 CH3 ОА OB oc OD Question 21 7.33 pts Which of the following compounds would you expect to be the MAJOR product under the reaction conditions shown? (adapted from Droblem 21 Question 21 7.33 pts Which of the following compounds would you expect to be the MAJOR product under the reaction conditions shown? (adapted from Problem...
3. a) Write the equilibrium equation for the following reaction N2(g) + 3 H2(g) <-> 2...
3. a) Write the equilibrium equation for the following reaction N2(g) + 3 H2(g) <-> 2 NH3(g) b) An equilibrium mixture at 500 K has the following concentrations: [N2] = 3.0 x 10-2 M [H2] = 3.7 x 10-2 M [NH3] = 1.6 x 10-2 M, calculate the equilibrium constant, Kc c) Calculate the Kp for this reaction d) Is the equilibrium mixture mostly reactants or products? e) Does this reaction go to nearly 100% completion? Explain f) If Qc...
1.1 In which of the following solvents would the reaction of
1-bromobutane with sodium azide,NaN3, proceed the fastest?
a.aceticacid
b.ethanol
c.water
d.acetonitrile
1.2 Which of the following solvents is the best choice for the
reaction of 1-chlorohexane with sodium bromide?
a.dimethylsulfoxide
b.water
c.hexane
d.toluene,PhCH3
1.3 Which of the following is most likely to undergo
rearrangement during reaction with methanol?
1.4 Name which energy diagrams represents the course of an
exothermic SN1, SN2,E1, or E2 reaction?
1.5 Which of the following...
1. Write the overall balanced reaction equation for the following reactions: 1-bromobutane + CH3CH,OH + AgNO3 2-bromobutane + CH,CH,OH + AgNO3 2-bromo2-methylpropane + CH CH OH + AgNO3 — 2. For the solvolysis reaction of 2-bromo-2-methylpropane with ethanol in presence of silver nitrate: a. Write the balanced equation for the reaction b. Identify the substrate, nucleophile, leaving group and the solvent c. What is the role of silver nitrate d. Write the mechanism of the reaction(with arrows showing the movement...
help on the problems
4. Write the complete equation for the hydration reaction of the following alkenes. If more than one product can be formed, indicate which one is the major product. For example, the hydration of ethene is written as follows: H н H он Но + Н-С C-H ethene H H CH2CH3 CH3 CH3 b) CH,CH2 a) CH2CH2CH2CH2CH CH3CH2CH Name the following molecules: 5. CH2CH сH-CH,CнсH,сн, снсH,сн, HF OH H H HH I! ! I a) Cl-c-C-C-c-H II...
_1. An alkyl halide which might be expected to undergo rearrangement under Snl or E1 conditions is: HZC Br CH3 A. 1 B. | F—CH,BH C. CH3-C-CH-CH, CHz CH3 D. CH3 CH3-C-CH2CH2-Br CH3 E. A Br 2. Your task is to convert 2-chloropentane into 1-pentene. Which reagents would you choose? a) NaOH/H20 b) KOH/CH3OH c) CH3ONa/CH3OH d) CH3CH2ONa/CH3CH2OH e) (CH3)3COK/(CH3)3COH 3. Circle the reaction below which is faster in polar protic solvents. OH,H,O A. CH,CH,CH,Br- CH,CH,CH,OH + Br or SH.RSH...
14) When (R)-2-bromobutane reacts with Cl2/hw, which of the following is true CH3 CH3 H--C1 CH3 CH3 A) Only I is formed. B) Only II is formed. C) I and II are formed in equal amounts. D) I and II are formed in unequal amounts. E) I and II could never form under these conditions. 15) Which of the following compounds is more stable? Explain. -CHb. 16) Give the best product for the reaction. CH CH:CH Br, ight 17) Complete...
1.1 What is the equation for the rate of formation of tert-butyl
alcohol from the reaction of tert-butyl bromide (t-BuBr) with water
by an SN1 mechanism?
A. Rate= k[t-BuBr]
B Rate=k[ t-BuBr][H2O]
C. Rate=k[ H2O]
D. Rate=k[t-BuBr]^2
1.2 What is the equation for the rate of formation of
1-iodobutane from the reaction of 1-chlorobutane (BuCl) with NaI by
an SN2 mechanism?
A. Rate=k[BuCl]
B. Rate=k[BuCl][NaI]
C. Rate=k[NaI]
D. Rate=k[BuCl]^2
1.3 What is the equation for the rate of formation of...
2. (3)For the following reaction: Mg(s) + Ni(NO3)2 (aq) → Mg(NO3)2(aq) + Ni(s) a. Write the reduction half-reaction: b. Write the oxidation half-reaction: c. What is the reducing agent: d. What is the oxidizing agent? 3. (2) For each of the following 'half-reactions' indicate whether the carbon compound is a) reduced b) oxidized or c) neither oxidized nor reduced and state your reasoning: (a,b or c) ОН CH, CH2-CH=CH2 CH, CH2-CH-CH3 Your reasoning: CH, CH2CH=CH2 howro bob518) abon 2 219160...
Question 20 7.33 pts Identify the major product resulting from the following reaction. 1) BH3-THE 2) CH,CO,D CH3 c) D D сн. CH CH3 CH3 ОА OB oc OD Question 21 7.33 pts Which of the following compounds would you expect to be the MAJOR product under the reaction conditions shown? (adapted from Droblem 21 Question 21 7.33 pts Which of the following compounds would you expect to be the MAJOR product under the reaction conditions shown? (adapted from Problem...
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