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Question 15 (2 points) Which of the following substituents will not direct the incoming group to...
Question 27 (2 points) Which of the following substituents will not direct the incoming group to the ortho/para position during electrophilic aromatic substitution? Oa) -OCOCH3 ob) -COOCH3 OC) -CH2CH3 od) -N(CH3)2 Question 28 (2 points) Provide the reagents necessary to carry out the following conversion. OH OH B Br Br oa) Br2, hn ob) HBr (3 moles) oc) Br2, FeBr3 od) Br2
Question 27 (2 points) Saved Which of the following substituents will not direct the incoming group to the ortho/para position during electrophilic aromatic substitution? Oa) -OCOCH3 Ob) -COOCH3 Oc) -CH2CH3 Od) -N(CH3)2 Question 28 (2 points) Saved Provide the reagents necessary to carry out the following conversion. OH OH Br Br Br Oa) Br2, hn Ob) HBr (3 moles) O c) Br2, FeBr3 o d) Br2
Substituents on an aromatic ring can have several effects on electrophilic aromatic substitution reactions. Substituents can activate or deactivate the ring to substitution, donate or withdraw electrons inductively, donate or withdraw electrons through resonance, and direct substitution either to the ortho/para or to the meta positions. From the following lists, select the substituents that have the indicated property. The substituents are written as XY, where X is the atom directly bound to the aromatic ring. Activation of the ring towards...
Question 19 (2 points) Which of the following compounds will undergo the fastest SN 1 reaction? Br BI Br Br 1 I! II! IV oa) III ob) IV OC) 11 od) 1 Question 20 (2 points) In the molecule shown below, determine which of the highlighted C-H bonds a to d is expected to have the lowest bond dissociation energy? HU Hd Oa) C-Hb ob) C-HC Oc) C-Hd od) C-Ha
Which of the following sets of substituents are all ortho/para directing in electrophilic aromatic substitution reactions? O CN, NO2, COCH3 O CI, OH, CH3 OBr, OH, COCH3 OCI, CH3. CN
Which of the following is most likely to be the first slop in the general mechanism for electrophilie substitution reactions? Arrange the following compounds in order of decreasing reactivity towards electrophilie aromatic substitution (most reactive first). V>II>I>III>IV II>V>III>I>IV IV>I>III>V>II III>II>I>IV>V IV>V>II>I>III Which one of the following substituents will not direct an incoming group to the ortho/para positions during electrophilic aromatic substitution? -CH_2CH_3 -CF_3 -OCH_3 -NHCH_3 -Br Which one of the following is not a resonance form of the cyclohexadienyl cation...
Question 45 (2 points) For which of the following compounds will the M+2 peak intensity be equal to the intensity of the molecular ion peak M? oa) CH3CH2CH2NH2 ob) CH3CH2CH2Br OC) CH3CH2CH2C1 od) CH3CH2CH2OH Question 46 (2 points) Predict the major product(s) of the following reaction. Br2 light Ar o Br CHB CH-Br CHUB Br III IV Br Oa) IV Ob) III OC) 11 od) 1
please help in all sections asap!! Which of the following reactions would produce isopropylbenzene as the major product? ОН AICI: H2SO4 H2SO4 AICI3 IV I all of these Predict the product for the following reaction fuming H2SO4 SO3H Predict the structure of the major product for the following reaction Which of the following compounds will not undergo nucleophilic aromatic substitution? 1-chloro-2,4-dinitrobenzene 1-bromo-4-nitrobenzene O-chloronitrobenzene m-chloronitrobenzene p-chloronitrobenzene Choose the correct sequence of reagents for the following transformation. 2) 3 . NH2 2)...
Question 15 (2 points) Which of the following are possible products of the reaction shown? hv NBS Br Br IV Oa) I, II and III ob) I and II Oc) I, II, III and IV od) 1, III and IV Question 16 (2 points) Guess the structure of the compound using your understanding of chemical shifts. 2H PP انه IV oa) III ob) 1 oc) IV od) 11
Question 41 (2 points) Which of the following carbocations is (are) likely to undergo rearrangement through a methyl shift? H2C CH3 H3C CH3 H3C CH3 III a) both II and III Ob) both I and II Oc) Od) Question 42 (2 points) For the reaction shown, select the expected major organic product. 1. 1 eq HCI 2. 1 eq HBr Br. CI -Br -CI Ha CI Br + enantiomer + enantiomer + enantiomer CI Br + enantiomer IV 11 III...