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Predict the major products with stereochemistry 원 H2N-OH heating (otho) Н -Ph Php. CHPh. THE BPCACHOCHES...
Predict the major product expected with correct stereochemistry (if any) in each of the following reactions (8 points). H2N-OH heating (-20) 88 Ph PhyP-CHP THF Ph3P-CHCH2CH3 THF m-CPBA CH,C12 to TSOH (cat) HO OH
Name the following compounds? (2 points) HON CHO Predict the wgir product expected with correct stereochemistry (if any) in each of the following reactions (8 points). HAN-OH heating (0) PhP-CHPA THF Ph,P.CHCH.CH THF m-CPBA CH.CH TSOH(cat) но OH
1) Reactions. Provide the major products for each reaction sequence, account for stereochemistry 1) KMnO4, A 2) SOCI, CH2Cl2 3) 2 equiv. 1) ethylene oxide, THF 2) H3O+ workup Culi 3) DIBAL-H, THF 4) H3O+ workup 5) cat. TsOH, THF H3CCHE (c) HN COH 1) excess LAH, THE 2) H30+ workup 3) 1 equiv. EtN, DMF 4) pyridine i ( " culi , THF (d) PC Ph 2) H3O+/H2O workup 3) KMnO4, A 4) CH,OH, cat. H2SO4 5) cat. TsOH,...
predict the products and indicate the relative stereochemistry for the following transformations. When necessary indicate the major product. Me 1. light 2. xylenes, heat Et (d) (4 points) CN xylenes, heat Me 2. H30+, heat 3. Me OH Me Me cat p-TsOH, PhH reflux (d) (4 points) Meo OMe 1. AczO, pyridine Meo 2. HO HO OH Me 1. light 2. xylenes, heat Et (d) (4 points) CN xylenes, heat Me 2. H30+, heat 3. Me OH Me Me cat...
PROBLEMS 1. Reagents. Give the structures of the major products (A-G) expected from the following reactions. Assume standard aqueous workup conditions are used for product isolation. a. OH 1. TBSCI imidazole, CH2Cl2 ► DMF, -18°C tot HO OH2. NalO4, CH2Cl2 large excoss A 80% b. олон 1. TSCI. py B "CH, 2. LiEt3BH. THE c. MeOC O H OH 1. TICI (1 cq) py, cat. DMAP - 2. TBSOT 2,6-lutidine, CH2Cl2 C1 79% 3. LIBHA, THE 4. Php. 12 imidazole...
help please! 1) Reactions. Provide the major product for each reaction sequence, account for stereochemistry. 1) PCC, CH2Cl2 2) Brz, acetic acid OH 3) KotBu, A 4) NaOEt, EtOH P CO 8 5) H2O+ workup 6) THF, H.CaPPha HCB , cat. PdOAC) cat. PPh3, DMF, EN | CHA 0 нс. CH32) LDA, THF, -78 °C CHICH,then H3O+ workup 4) NaBH4, EtOH, then H3O+ workup 5) cat. TSOH, benzaldehyde 1) cat. H2SO4, A 2) O3. CH2Cl2, then (CH3)2S CH; 3) NaOE,...
Predict the major products of the following reactions, and give the structures of any intermediates. Include stereochemistry where appropriate . s-46 Predict the major predueowing reactions, and give the structures of any intermediates. Include stereochemistry where appropriate (l BH, THF (2) H,O, OH CCl, () 0, (-78 C) (2) (CH31,5 へ HCI ROOR KMno OH CH,CO,H H. H,0 KMnO, OH (warm, coned.) ) (l)03 (-78 °C) (2) (CH,S ·H20 MI- CHR Pt (0) Cl2 H,0 (2) NaBH 7 Limonene is...
4. Predict the major product in the following reactions. relationship between: Lindlar cat. A and C i. m-CPBA H2 CH3 ii. H30* H2O Ph A B and D H2SO4 i. m-CPBA Ph CH3 heat ii. H30* H2O OH 4. Predict the major product in the following reactions. relationship between: Lindlar cat. A and C i. m-CPBA H2 CH3 ii. H30* H2O Ph A B and D H2SO4 i. m-CPBA Ph CH3 heat ii. H30* H2O OH
3. (28 pts) Draw the starting material, reagents, or major products of the following reactions. Indicate stereochemistry where relevant. - 5 mino cat. NaOCH CH, OH bo He° °CH °CH, Z HOA L ambe also THF, CO, : HO. HO H. CH, OH en generall HD, HD
Predict the product(s), both major and minor, of the following reactions. Indicate stereochemistry where appropriate. КОНЕТОН OTs Ph н н а. Ph b. THF OMs NaOCH(CH3)2 с. Н НОСHCH)2