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thanks in advance ☺ (A). For the hypothetical reaction A+B → C the following rate data...
helpp 3. For the hypothetical reaction A+B → C the following rate data (with and without catalyst) were obtained: Rate, M/s Rate, M/s ALM B., Muncatalyzed) (catalyzed) 0.100 0.200 3.51 x 10 7.14 x 10 0.100 0.100 1.75 x 10 7.14 x 10 0.0500 0.200 1.76 x 10 3.57 x 10 0.0500 0.100 8.80 x 10 3.57 x 10 Based on these data: a. Determine the uncatalyzed and catalyzed rate laws for this reaction, and the corresponding rate constants. (16...
4. For the reaction: (CH3),CBr +1 → (CH3),CI + Br* the following data were collected: (CH3)3Br) (M) Time (s) 0.600 0 0.424 10.0 0.300 20.0 0.212 30.0 0.150 40.0 Determine the rate law for this reaction and calculate the rate constant. (20 points)
4. For the reaction: (CH3),CBr +1 → (CH3),CI + Br* the following data were collected: (CH3)3Br) (M) Time (s) 0.600 0 0.424 10.0 0.300 20.0 0.212 30.0 0.150 40.0 Determine the rate law for this reaction and calculate the rate constant. (20 points)
4. For the reaction: (CH3),CBr +1 → (CH3),CI + Br* the following data were collected: (CH3)3Br) (M) Time (s) 0.600 0 0.424 10.0 0.300 20.0 0.212 30.0 0.150 40.0 Determine the rate law for this reaction and calculate the rate constant. (20 points)
4. For the reaction: (CH3),CBr +1 → (CH3),CI + Br* the following data were collected: (CH3)3Br) (M) Time (s) 0.600 0 0.424 10.0 0.300 20.0 0.212 30.0 0.150 40.0 Determine the rate law for this reaction and calculate the rate constant. (20 points)
2. The rate of the reaction 2A+B → has been observed at 25°C. From the following data, determine the rate law for the reaction and calculate the rate constant. Experiment ) 2 3 4 5 Initial IAI(M) 0.100 0.200 0.400 0.100 0.100 Initial ( B M 0.100 0.100 0.100 0.300 0.600 Initial rate (M/s) 5.50 x 106 2.20 x 10 8.80 x 10 1.65 x 10 3.30 x 10
Thanks in advance please just Question A , b and c please this is chemistry based on kinetics there's no other subject please if you don't know the calculation based on that question, allow other experts to help out for the solutions Thanks in advance Helpful Hints: Arrhenius Equation: k = Ae–Ea/RT Gas Constant: R = 8.314 J/mol·K Integrated Rate Laws and Half-Lives: • Zero order: [A] = –kt + [A]0 t1/2 = [A]0/2k • First order: ln[A] = –kt...
Applicati 6. For a generic reaction A + B C, the following data are obtained Experiment Initial /AL. M Initial (e). M Initial rate (M/s 0.100 M 0.100 M 0.100 M 0.200 M 16.0 x 10 16.0 x 10 0200 M 0,100M 64.0 x10 64.0 x 10 0.100 M a. (5 pts) Based on the data, what is the rate law for the reaction? b. (5 pts) using experiment #2's data, solve for k. (5 pts) For experiment #2, after...
An uncatalyzed reaction has a rate of 4.4 x 10-7 s–1 at room temperature (25 °C). When an enzyme is added the rate is 3.1 x 104 s–1. If the height of the activation barrier for the uncatalyzed rate is 28.6 kcal/mol, what is the height of the activation barrier for the catalyzed rate? Report your answer in terms of kcal/mol to the nearest tenths. Also, assume the pre-exponential terms for the uncatalyzed and catalyzed reactions are the same.
1. Initial rate data at 25.0 °C are listed below for the reaction: 2 HgCl2 (aq) + C,042 (aq) → 2 (aq) + 2 CO2(g) + HgCl(s) Expt. [HgCl2]0 [C:02) Initial rate/Ms? 0.100 0.20 0.100 0.40 3.1 x 105 1.2 x 104 6.2 x 10-5 0.050 0.40 Use the data to determine the rate law for the reaction. 2. At 500 °C, cyclopropane (C3H.) rearranges to propene (CH:CH-CH2): CH. (g) → CH,CH=CH2 (8) The reaction is first order and the...