Question

(A). You study the following reaction in a series of experiments: (CH),COH(aq) + HCl(aq) → (CH3),CCl(aq) + H20(1) At 100 °C y


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Helpful Hints:   Arrhenius Equation: k = Ae–Ea/RT Gas Constant: R = 8.314 J/mol·K

Integrated Rate Laws and Half-Lives:

• Zero order: [A] = –kt + [A]0 t1/2 = [A]0/2k

• First order: ln[A] = –kt + ln[A]0 t1/2 = 0.693/k

• Second order: 1/[A] = kt + 1/[A]0 t1/2 = 1/k[A]0

• Pseudo first order: Use first order integrated rate law for the pseudo-first order reactant; other reactant concentrations remain constant, but are still present in overall rate law

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