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12) What reagent(s) are used to make the following transformation? ery A) Br2, H20 B) O3,...
Which is the best reagent(s) for the following transformation? ce Br Br2 Br2, CH3OOCH3 Br2, H20 HBr
Question 9 Which one of the following reaction steps work best to carry out the transformation shown below? ? ? H 1) BH3, THF PCC A) 2) H2O2, NaOH CH2Cl2 H20, H2SO4 (cat.) PCC B) CH2Cl2 1) BH3, THF HIO1 C) 2) HOh, NaOH D) OsO4 (CH3)3COOH, OH K2Cr207, H2SO4 H2O С в СА D
Give the missing reagent(s). Due 11/22/19 Give the missing reagent(s). CH3 Пон CH3 ОН CH3 он он CH3 пон lot Matching: ACH, инно он CH3 пон "HOH Matching: H2SO4, H20 1) BH3.THF 2) H2O2, OH-1 C2 1) Br2, H2O 2) NaH KMnO4 Cold, Dilute,Basic HCl 1) Hg(OAc)2, H2O 2) NaBH4, OH! H2O, H2SO4 mCPBA 1) mCPBA 2) H:07 H2 1) OsO4 2) NaHSO3 (1) O₃ 2) (CH3)2S Na, Liquid NH; | 1) mCPBA 2) H2O, OH"! Lindlar's Catalyst
Propose an efficient synthesis for the following transformation. The transformation above can be performed with some reagent or combination of the reagents listed below. Give the necessary reagent(s) in the correct order, as a string of letters (without spaces or punctuation, such as "EBF"). If there is more than one correct solution, provide just one answer. A B Br2 HBr, ROOR cat. Os04, NMO D E H2, Pd F H2SO4, H20, HgSO4 HBO G 1) O3; 2) DMS H 1)...
2. Provide the major products from the following reactions. Starting Material Reagent(s) Product? Br2 Place appropriate groups H, Br CH, on scaffold) HCI Place appropriate groups (H, Br, CH, on scaffold) CH Brz/H20 Place appropriate groups H, Br CHs on scaffold] 1) O3 2) Zn/HOÁC LICH H2, Pd/C CH₂ 1. BH3 2. H2O2, NaOH(aq) CH2 hot KMnO4 in H2O - CH₂ CH3CO3H Product from above H30+, H2O
25) What reagents can best be used to accomplish the following transformation? A) H+, H2O B)1. BH3-THF 2. Ho, H202 C)1. Hg(OAc)2, H2O/THF 2. NaBH4 D)1. Hg(O2CCF3)2 CH3OH 2. NaBH4 E) NaOH, H20
Practice Problem 11.18a Propose an efficient synthesis for the following transformation. OH The transformation above can be performed with some reagent or combination of the reagents listed below. Give the necessary reagent(s) in the correct order, as a string of letters (without spaces or punctuation, such as "EBF"). If there is more than one correct solution, provide just one answer. A B с H2, Lindlar's cat. HBr, ROOR 1) xs NaNH2, 2) H2O D E F HBr Br2 H2S04, H20,...
QUESTION 5 What reagents can best be used to accomplish the following transformation? 1. BH3-THF 2. HO- H202 NaOH, H20 H+ H20 1.03 2. (CH3)2
Provide the major product(s) for the following reactions: Show Stereochemistry when necessary HBr Br2 CH2Cl2 HBr Br2 ROOR H20 H2O СН,ОН H30* 1) BH3, THE 2) H2O2, NaOH, H2O 1) Hg(O2CCF3)2 CH3OH 2) NaBH4, NaOH 1) Hg(OAc)2, H20, THF 2) NaBH4, NaOH H2 Pd/C
5.27 Give the principal organic products expected when 1-butene reacts with each of the following reagents (a) Br2 in CH2Cl2 solvent (b) O3, -78 oc (c) product of (b) with (CH3)2S (d) product of (b) with H202 (e) O2, flame (f) HBr (g) I2, H20 (h) H2, Pt/C (i) HBr, peroxides (j) BH3 in tetrahydrofuran (THF) (k) product of G) with NaOH, H,02 (1) Hg(OAc), H2O (m) product of (I) with NaBH4/NaOH (n) HI (o) HI, AIBN