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9 just identify the type of reactiom a) 9) Complete the following: (Stereochemistry and regiochemistry may...
3. Give the major product of the following reactions with the appropriate stereochemistry and regiochemistry 2. Hoc МСРВА NO нас H3C 1.LiTMs ; 2. MeOH 1. KOMe/MeOH; 2. dil. HCI, O C d. 1. NaN 3, H2SO4 water heat; 2. dil. KOH H3C OH e. 1. LDA, THF, -78 C; 2. TMSCI; ; 4. water; 5. HCl/water, heat
help please! 1) Reactions. Provide the major product for each reaction sequence, account for stereochemistry. 1) PCC, CH2Cl2 2) Brz, acetic acid OH 3) KotBu, A 4) NaOEt, EtOH P CO 8 5) H2O+ workup 6) THF, H.CaPPha HCB , cat. PdOAC) cat. PPh3, DMF, EN | CHA 0 нс. CH32) LDA, THF, -78 °C CHICH,then H3O+ workup 4) NaBH4, EtOH, then H3O+ workup 5) cat. TSOH, benzaldehyde 1) cat. H2SO4, A 2) O3. CH2Cl2, then (CH3)2S CH; 3) NaOE,...
1) Reactions. Provide the major product for each reaction sequence, account for stereochemistry 1) PCC, CHCI 2) Bry, acetic acid 3) KOBU, A 4) NaOEI, ETOH, P CO- 5) H30 workup 6) THF, H.COPPA HC CH2 O e .cat. Pd(OAc) cat. PPh. DMF, EIN 2) LDA, THF. -78 °C 3) Chichen H3O* workup 4) NaBH, EtOH, then H3O+ workup 5) cat. TSOH, benzaldehyde (c) L AL SUO TESTE TO 1) cat. H2SO4. A лон 2) O3, CH, Cl, then (CH),...
(30 pt) Draw the structures of the MAJOR products for the following reactions. Be sure to clearly show the REGIO- and STEREOCHEMISTRY of each product. H2SO4 X - H2O BH3 H2O2 THF H20, OH Br2 CH2OH excess HBO d) CH3-C=C-CH3 1 eq Cl2 e) CH3 -C=C-CH3 CH2Cl2 Na CH3CO2H 9) CH.-C=C-H, under CH3COH f) CH3-CEC-CH3 liquid NH3 -78 °C H202 g) CH3CH2-CEC-H R2BH THE H2O, OH NaNH2 CH3CH2Br H2SO4 h) CH3CH2-CEC-H my Chcn=c20-n, Nanets, Cheka na H2O HgSO4 heat 1...
Identify the major product of this reaction но Identify the major product of this reaction. CH, H2SO4 (A) CH (B) .CH CH (D) CH REMOVED Identify a reagent or set of reagents to accomplish the following transformation. OH (A) OsO4 I-BUOOH (C) 1) THF-BH) 2) H30, OH H20 (B) 1) Hg(OAc), H,0 2) NaBHE (D) HOOH A 9 Identify an important intermediate in following reaction. -93 1) LATHA 2) 11,0 OCH, ဂုံ + HOCH CH, CHCI CHỊCH (A) (B) :OH...
Question 9 Which one of the following reaction steps work best to carry out the transformation shown below? ? ? H 1) BH3, THF PCC A) 2) H2O2, NaOH CH2Cl2 H20, H2SO4 (cat.) PCC B) CH2Cl2 1) BH3, THF HIO1 C) 2) HOh, NaOH D) OsO4 (CH3)3COOH, OH K2Cr207, H2SO4 H2O С в СА D
Identify the reagents to be used in the following synthetic schemes: (Specify the reagents you would use to carry out the conversion by using letters from the table. Write the letters in the order that they are used, e.g., abc.) Scheme1 CH3 CH3 CH3 CH3 OH Scheme 2 Br CH3 H3C CH3 CH3 a. BH3, THF then H202, OH h. NBS, CCl b. PBr3 c. Mg, ether then H3o* d. (CH3)2Culi e. Br2 f. NaNH2, NH3 g. H2O, H2SO4, HgSO4...
Ph cyclopropene HF CH h) OH 1. POCICH.Ch 2. Pri 3 NH4Cl ag) 1.) 1. Li/THE 2.CO 3.NH.CH HNO k.) NH 1. HNO (aq) 2. NaSCH CH.CH AICI, 3-chloro-2-methylpentane m.) 1.Pr.CI. AICI 2. NBS, CCU. n) -OH XS H.CO acetone он 0.) OH XS Bobbit's SiO, CH.CH -OH 1. Ch. AICI 2 NaOH, 30 C 4,000 psi 3. HCI 9.) SCH 2Na, ETOH, NH, r.) 1. LIETO 2. oxirane 3. H,00 1.2 PY-MOBI OMe 2. NHCl(aq) t.) 1. Cl/ Feer...
*Ignore the structures drawn in pencil. The purple lines indicate that they are incorrect. 23. As 5 points. Complete 10 of the 15 following reactions by providing the missing information: reactants products or reagents and conditions. When predicting products, you must include all products that will most likely form in an appreciable amount. When more than one product is likely, label the major and minor products. (Watch out for rearrangements). Where appropriate, indicate stereochemistry, as well as whether or not...
Question 9.27, 9.30 Choose one reagent from the Table to carry out the following conversions. Use letters from the table to specify reagents. Reagents КMnO,/ Н,о* O3 d 1. Br2 g a 2. KOH in ethanol H2/ Lindlar catalyst hr H20/ H2SO4/ HgSO4 е 1. NaNH2 in NH3 2. CH3Br Li in NH3 1 equiv Br2 f 1. BH3 in THF C 2. H202 in NaOH a) CHACH,сH,сH,CECH CHн-CH-CH-CH2CH-CH CHз b) сHa-CHa-CEс-сн, CH3CH2 The following synthesis requires more than one...