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7. Using the following reaction progress diagram, answer the questions below: wiring Energy A G Rxn....
5. How much faster would a reaction be if a catalyst is used that lowers the activation energy from 20.0 kJ/mol to 10.0 kJ/mol? Do the calculation at two temperatures: first at 25.0°C and then at 0.0°C. (20 points) (V) Helpful Stuff Thermodynamics: AG° = AH-TAS Nernst Equation: 6 = 6 - (RT/nF)InQ AG=RTIK At 25°C: 8 = 6 - (0.0591/n)logQ AGRT Ke=e AGⓇ =-nF8° Units/Constants: Volt: 1 V = 1 J/C Faraday: 1 F = 96,485 C/mole Arrhenius Equation:...
2. Using the decay chain for 238U, calculate the amount of time it takes 5.0 kg of 238U to decay to 2.5 kg. What mass of 206Pb is produced? (5 points) (V) Helpful Stuff Thermodynamics: AG° = AH-TAS Nernst Equation: 6 = 6 - (RT/nF)InQ AG=RTIK At 25°C: 8 = 6 - (0.0591/n)logQ ΔGIRT Ke=e AGⓇ = -nF8° Units/Constants: Volt: 1 V=1/C Faraday: 1 F -96,485 C/mol e Arrhenius Equation: k = Ae Ea/RT R= 8.314 J/mol K Integrated Rate...
help!! (CH3),CBr + 1 → (CH3),CI + Br the following data were collected: [(CH3)3Br] (M) Time (s) 0.600 0 0.424 10.0 0.300 20.0 0.212 30.0 0.150 40.0 Determine the rate law for this reaction and calculate the rate constant. (20 points) E (V) Thermodynamics: AGº - AH-TAS Nernst Equation: 8 = 8°-(RT/nF)InQ AGⓇ--RTINK At 25°C: 8-6° -0.0591/n)logQ AG RT K-e AG° = -nF8° Units/Constants: Volt: 1 V-1 JC Faraday: 1 F -96,485 C/mole Ea/RT Arrhenius Equation: k = Ae R-8.314...
helpp 3. For the hypothetical reaction A+B → C the following rate data (with and without catalyst) were obtained: Rate, M/s Rate, M/s ALM B., Muncatalyzed) (catalyzed) 0.100 0.200 3.51 x 10 7.14 x 10 0.100 0.100 1.75 x 10 7.14 x 10 0.0500 0.200 1.76 x 10 3.57 x 10 0.0500 0.100 8.80 x 10 3.57 x 10 Based on these data: a. Determine the uncatalyzed and catalyzed rate laws for this reaction, and the corresponding rate constants. (16...
Fill in the Blanks 0.34 Half Reaction E. (V) Half Reaction Erd® (V) F + 2e →2F 0+ 2H + 2e →H,02 0.68 Ag* + e → Ag Cu* + e → Cu 0.52 Co? + e Co? O2 + 2H,0 + 4e → 40H 0.40 H,O, + 2H + 2e → 2H,0 Cu2+ + 2e → Cu Cet+e → Ces Cu2+ + e → Cut 0.16 PbO, + 4H+ +50,2 +2e → PbSO, + 2H,0 2H* + 2e →...
Consider the following species. Cut Ce3+ Ag+ Zn2+ What is the standard potential for the reaction of Cut with Zn2+ to produce Cu2+ and Zn? E = 0.28 X v Will Cut be able to reduce Zn2+ to Zn? no (yes or no) What is the standard potential for the reaction of Ce3+ with Ag! to produce Ag? Ex= 0.90 x v Will Cell be able to reduce Ag! to Ag? yes (yer or no) Ered (V) 0.68 0.52 0.40...
1. How do I read the half reaction table? 2. If im asked for the best reducing agent from Cu+, Ag+, F2, and Fe3+, where do I look first in the table? before the arrow or after the arrow? 3. Sometimes a value that has originally a positive (V) from the table it will have the negative sign in a homework problem, and viceversa, so the question is, how do I use the positive and negative signs in respect to...
2.87 Ered® (V) 0.68 0.52 0.40 0.34 0.16 Half Reaction F,+ 2e →2F Ag* + e → Ag Co3 + e + CO2- H2O2 + 2H+ + 2e → 2H,0 Ce4+ + e → Ce+ PbO, + 4H+ + SO42- + 2e → PbSO, + 2H,0 Mno, + 4H+ + 3e → MnO2 + 2H,0 2e + 2H+ + 10, → 103 + H2O Mn0, +8H+ + 5e → Mn2+ + 4H,0 Aul+ + 3e → Au Cl2 + 2e...
the first picture is about some useful information, and the second picture is the question that bothers me. I wonder how we know the half-cell reaction of it. Please explain!!! TABLE 18.1 | Standard Reduction Potentials at 25°C (298 K) for Many Common Half-Reactions 8° (V) 0.40 0.34 0.27 0.22 0.20 0.16 0.00 Half-Reaction F2 + 2e →2F Ag2+ + e +Agt Co3- + e + CO2- H2O2 + 2H+ + 2e +2H20 Ce+ + e + Ce+ PbO2 +...
For all of the following experiments, under standard conditions, which species could be spontaneously produced? A lead wire is placed in a solution containing Cu2+ yes no Cu yes no PbO2 yes no No reaction Crystals of I2 are added to a solution of NaCl. yes no I- yes no No reaction yes no Cl2 A silver wire is placed in a solution containing Cu2+ no yes Cu no yes No reaction no yes Ag+ Half-Reaction 8° (V) Half-Reaction 8° (V) 2.87 1.99 1.82 1.78 1.70 1.69 1.68 1.60...