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Predict the following reaction # CH3 C = C / - HBr H H Show transcribed...
4. Predict the products for the following reaction sequences. OH H SOCI pyridine (CH3)2NH 1. LIAIHA 2. H20 CH,CH,Br NH2 base (-HBr) CH3Br base (-HBr) o cum, quod cas merea, moms outlet V i har hatteNaensen mCPBA (a) LIAIH4 (b) H20 NaBH,CN NH2 H2SO4
5. Predict the major product of the reaction shown below 0 H2NCH3, cat. H* CH3 (c) HNH H3C .сн он 0 CH3 .сн CH3 6. Predict the major product of the reaction shown below. H2NCH3, cat. H+ CH3 0 он CH3 CH3 CH3
QUESTION 9 Estimate the ΔΗ for forming the first product. H,C H + HBr CH QUESTION 8 Write a Mechanism for Making the Second Product the Following Reaction. HaC H C Cl CH CH, H,C hv HCI CH H,C H C Predict the product(s) of the reaction shown, including stereochemistry: 2 H2C NaCN acetone CH3
Predict the product for the following reaction sequence. O H,SO CH3 Edit
What is the AH° for the reaction in kcal/mole? CH3 H2C- C-OH + HBr – - H3C—¢-Br + H2O CH3 BDE in kcal/mole H-Br = 87.6 3° C-Br = 63 3° C-OH = 92 H-OH = 119
Predict the major products for each of the following reactions.
KOC(CHsh HOC(CH3)hs HBr H20, H2SO4, 100 C H PO4. conc -0109%0 60 100 C
Predict the major product of the follow reaction: -0 DI CHg rona CH3 H CH3 сн. -CH₃ H ~ THF, 70°C (higher temperature) . -CH3 H" CH3 HY Hz О А О В ОС O
Predict the major product of the follow reaction: -0 DI CHg rona CH3 H CH3 сн. -CH₃ H ~ THF, 70°C (higher temperature) . -CH3 H" CH3 HY Hz О А О В ОС O
Given the following reaction, CH HBr CH3 anae nism arrow and name the first step of the given reaction. Show the resulting intermediate(s). (a) Draw mecha points) (b) Predict the major organic product(s) formed indicating stereochemistry when necess (b1) concentration of HBr is concentrated (3 points) (b2) concentration of HBr is dilute (3 points)
Predict the major product(s) from the following
reactions:
CH3 CH₃ H₃C H₂ ? -CH₃ CH3 НАС 1. BH3-THF 2. H2O2, NaOH ? CH3 Brz CH3 CH2OH