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3. (3 pts.) Shown below is the IR spectrum 2-acetylcyclohexanone (the structure is provided in the...
3. shown below is the IR spectrum 2-acetylcyclohexanone (the structure is provided in the spectrum). 2-acetylcyclohexanone Exists as an equilibrium mixture of diketone and two enol forms. Both the diketonr and enol forms can be seen in the provide IR spectrum although the two different enols cannot be distinguished. The IR spectra of both enols is essentially identical and so do not be concerned with distinguishing the enols, just assign peaks to a "generic" enol. On the spectrum identify the...
1. shown below are IR spectra of cyclohexanecarbaldehyde (I) and cyclohexene (II). which of the spectra A and B corresponds to which structure (I or II)? On each spectrum identify the peaks that are associated with a specific bond vibration bond by drawing the functional group for that bond, circling the specific vibrating bond and drying and arrow from the circled bond to the absorption peak. include all the C-H bonds. 2. provided below are IR spectra of 1,2,3,6-tetrahydrobenzaldehyde (I)...
2. (2 pts.) Provided below are IR spectra of 1,2,3,6-tetrahydrobenzaldehyde (I) and 3-methyl-2-cyclohexen-1-one (II). Decide which of the IR spectra A and B corresponds to which structure (I or II). On each spectrum, identify the peaks that are associated with a specific bond vibration bond by drawing the functional group for that bond, circling the specific vibrating bond and drawing an arrow from the circled bond to the absorption peak, as appropriate. Include all the C-H bonds. odo and II...
Use the following correlation chart to help answer the IR spectrum questions: small range range of values N-H -O-H-CEN usually broad peak C-o strong 1600-1660 EC-H 3250-3300 2200 1680 gco sco 2710- 2820 2 peaks 3000- 3100 CECH (N-H C-H 1730 2200 broad with spikes --3300 O-H 1600 2850- 2960 1710 broad-3300-3400 -CO-H broad-3000 1650 4000 3500 3000 2000 1500 2500 wavenumber, cm 1000 1. (2 pts.) Shown below are IR spectra of cyclohexanecarbaldehyde (I) and cyclohexene (II). Which of...
7. (3 pts.) Shown below is the 'HNMR spectrum of curcumin in solution. In solution, curcumin could exist in diketone form or enol form, or as a mixture of the two. We can determine if the spectrum corresponds to the keto form or the enol form or a mixture of the two forms. If the spectrum corresponds to both the keto and enol form we should see the peaks for Ha protons in the keto form and the Hb proton...