Homework Answers
The best way to synthesize the product is option C.
The raction of methyl benzene with Br2, FeBr3 is a Selective reaction and gives higher percentage of para bromo methyl benzene product which further reacts with NaN3 to form azide and reduces to NH2 by H2, Ni to form the desired product.
Option B also forms the desired product but selectivity of Nitration reaction is less so ortho and para product both are formed which decreases the yield for desired product.
Option A and D do not form the desired product.
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The best way to synthesize the following amine is: HN 1. NBS, hy 2. NaNH, NHÀ...
The best way to synthesize the following amine is: H2N 1. NBS, hv 2. NaNH. NHÀ...
The best way to synthesize the following amine is: H2N 1. NBS, hv 2. NaNH. NHÀ 1. HNO3 H2SO4 2. Fe, HC1 3. NaOH 1. Br2, FeBrz 2. NaN3 3. H. Ni 1. NaCN Br 2. LiAlH4 3. H2O
What is the major product of the following reaction? NAOH heat X X ger K OH...
What is the major product of the following reaction? NAOH heat X X ger K OH o The best way to synthesize the following amine is: H2N- 1. HNO3 H2SO4 2. Fe, HCI 3. NaOH 1. NaCN Br 2. LiAH, 3. H0 1. Bry. FeBrz 2. NaN 3. H. Ni 1 NBS hr 2 NaNH NHI What is the major product of this reaction! CHU, Hy0°.H20 OH -OH och OH
The best way to synthesize the following amine is: HN 1. SOCI 2. ex NH; HO...
The best way to synthesize the following amine is: HN 1. SOCI 2. ex NH; HO 3. LiAIH 4. H20 1. NaN; Br 2. H. Ni 1. NaCN Br 2. LAIH, 3 H,0 1. ex. NH 2 LAIH 3 но HO
Question 32 (4 points) The best way to synthesize the following amine is: HN 1. ex....
Question 32 (4 points) The best way to synthesize the following amine is: HN 1. ex. NH; 2. LiAlH4 3. HO HO 1. NaCN Br 2. LiAlH4 3. H2O 1. SOCl2 2. ex. NH; HO 3. LiAlH4 4.HO 1. NaN3 Br 2. H. Ni
Write the products of these reactions -NH2 1. NaNO2, HCI 2. CuCN 1. N(CH3)3 2. Ag20,...
Write the products of these reactions
-NH2 1. NaNO2, HCI 2. CuCN 1. N(CH3)3 2. Ag20, H20 3.A 1. LAIHA 2. H20 NaN3 1. LATHA 2. H2O NaCN 1. LIAH 2. H20 Br NaCN H. Ni HNO3 H2SO4 NaOH H20 1. NaNO2 HCI 2. HBF 4 CH3 HNO3 Na Cr207 H2SO4 H2SO4 Sn HCI 1. NaNO2 HCI 2. CuCN
17. Use ANY needed reagents to effect the following transformation. (30 points) starting material product List...
17. Use ANY needed reagents to effect the following transformation. (30 points) starting material product List of Reagents -N:C:N- KMnO4, H2SO4 8 00 (CH3),COCOCOC(CH3)3 Ag(NH3)2+, 120 Fe, HCI KMnO4, NaOH, H2O, cold AlCl3 Bra (excess), NaOH (excess), H20 Brz, Fe Br2, H20 Br2, H2O, H3O+ Br2, hy Br2, NaOH (excess), H2O Br2, P Buli CF3CO,H CH;=0 Formaldehyde оо CH3COCCH o CH_CC1, pyridine H2, Lindlar's catalyst H2.Pd/C H2, Pa/C, high pressure H, Raney-Ni HANNH HENNH, KOH, (HOCH2CH2)20, heat H2O H20, H2SO4,...
DOME 4. What will be the best way to synthesize the following compound starting from benzene?...
DOME 4. What will be the best way to synthesize the following compound starting from benzene? the o ů na A. 1) CH3CH2CI, AICI3; 2) Cl2, FeCl3 B. 1) CH2=CH2, HF; 2) Cl2, FeCl3; ovods and to none C. 1) CH3CO-O-COCH3, AICI3; 2) Cl2, FeCl3; 3) Zn, HCI; D. 1) CH3CO-O-COCH3, AICI3; 2) Zn, HCI; 3) Cl2, FeCl3; E. none of the above EVE. none droedsw abruogo Oriollot to 8 Smund og tengsmont to 5. What set of reagents will...
In each reaction box, place the best reagent and conditions from the list below. 1) 2)...
In each reaction box, place the best reagent and conditions from the list below. 1) 2) Br 3) CH3CH2CH2CI, AlCl3 HNO3. H2S04 NBS, ROOR, hv H2 CH3CH2Cl, AICla , AICI AlCl3 NaBH4 Br2, FeBr3 Cl Zn(Hg), HCI Br2 In each reaction box, place the best reagent and conditions from the list below. 1) CHyCH2CH2CI, AlCl 2) 3) 4) mCPBA Pd, H2 BH3THF (CH3)3CO Br2, H20 CHCOO S ROR Br2, FeBr3 HBr Br2 In each reaction box, place the best reagent...
dd.) XS NBS CCM, A ee.) 1. fuming H2SO4 2. HNO3/H2SO4 3. Zn(Hg), HCI, A ff.)...
dd.) XS NBS CCM, A ee.) 1. fuming H2SO4 2. HNO3/H2SO4 3. Zn(Hg), HCI, A ff.) OH 1. H.Cros/acetone 2. PrMgl/Et20 3. H30* gg.) HORS. NH2 SO3 H2SO4 hh.) OE 1. LAIH/Et20/ -78 °C 2. H20 ii.) 1. Li/Et, 2. Ph Co 3. H30* jj.) Br 1. Mg/THE 2. formaldehyde 3. NHCl(aq) kk.) 2 Na, EtOH, NH3 II.) CH3BF4 mm.) SOUH 2 Na, EtOH, NH3 nn.) NO2 H2SO4(conc) HNO3(conc) NO2 00.) 1. SO3, H2SO4 2. NaOH/KOHA 3. H30*
1. Provide the major organic product(s) for each of the following reactions: 1) HNOZ/H, SO 2)...
1. Provide the major organic product(s) for each of the following reactions: 1) HNOZ/H, SO 2) Sn/HCl(aq) 3) HO 1) (CH3)2CHCI/AICI: 2) NBS/hv 1) Cly/FeCl3 2) HNO,/H2SO4 1) CH3CH,COCI/AICI 2) H20 оооооооо 3) Zn(Hg)/HCl(aq) 1) SOZ/H,SO 2) Bry/FeBrz 1) (CH3)3CCI/AICI: 2) KMnO/HOIA 2) H30* 1) CH,COCIAICI: 2) H, 3) Bry/FeBry COH 1) SOCI_/pyridine 2) PhCH/AICI 3) H20 1. Br JFeBry 2. Mg/Eto 3. oxirane 4, HO* 1) Bry/FeBry 2) s09/H230 1) NBS/hv 2) PhoNa (1 CH3COCI / AIC وا (2...
The best way to synthesize the following amine is: H2N 1. NBS, hv 2. NaNH. NHÀ 1. HNO3 H2SO4 2. Fe, HC1 3. NaOH 1. Br2, FeBrz 2. NaN3 3. H. Ni 1. NaCN Br 2. LiAlH4 3. H2O
What is the major product of the following reaction? NAOH heat X X ger K OH o The best way to synthesize the following amine is: H2N- 1. HNO3 H2SO4 2. Fe, HCI 3. NaOH 1. NaCN Br 2. LiAH, 3. H0 1. Bry. FeBrz 2. NaN 3. H. Ni 1 NBS hr 2 NaNH NHI What is the major product of this reaction! CHU, Hy0°.H20 OH -OH och OH
The best way to synthesize the following amine is: HN 1. SOCI 2. ex NH; HO 3. LiAIH 4. H20 1. NaN; Br 2. H. Ni 1. NaCN Br 2. LAIH, 3 H,0 1. ex. NH 2 LAIH 3 но HO
Question 32 (4 points) The best way to synthesize the following amine is: HN 1. ex. NH; 2. LiAlH4 3. HO HO 1. NaCN Br 2. LiAlH4 3. H2O 1. SOCl2 2. ex. NH; HO 3. LiAlH4 4.HO 1. NaN3 Br 2. H. Ni
Write the products of these reactions
-NH2 1. NaNO2, HCI 2. CuCN 1. N(CH3)3 2. Ag20, H20 3.A 1. LAIHA 2. H20 NaN3 1. LATHA 2. H2O NaCN 1. LIAH 2. H20 Br NaCN H. Ni HNO3 H2SO4 NaOH H20 1. NaNO2 HCI 2. HBF 4 CH3 HNO3 Na Cr207 H2SO4 H2SO4 Sn HCI 1. NaNO2 HCI 2. CuCN
17. Use ANY needed reagents to effect the following transformation. (30 points) starting material product List of Reagents -N:C:N- KMnO4, H2SO4 8 00 (CH3),COCOCOC(CH3)3 Ag(NH3)2+, 120 Fe, HCI KMnO4, NaOH, H2O, cold AlCl3 Bra (excess), NaOH (excess), H20 Brz, Fe Br2, H20 Br2, H2O, H3O+ Br2, hy Br2, NaOH (excess), H2O Br2, P Buli CF3CO,H CH;=0 Formaldehyde оо CH3COCCH o CH_CC1, pyridine H2, Lindlar's catalyst H2.Pd/C H2, Pa/C, high pressure H, Raney-Ni HANNH HENNH, KOH, (HOCH2CH2)20, heat H2O H20, H2SO4,...
DOME 4. What will be the best way to synthesize the following compound starting from benzene? the o ů na A. 1) CH3CH2CI, AICI3; 2) Cl2, FeCl3 B. 1) CH2=CH2, HF; 2) Cl2, FeCl3; ovods and to none C. 1) CH3CO-O-COCH3, AICI3; 2) Cl2, FeCl3; 3) Zn, HCI; D. 1) CH3CO-O-COCH3, AICI3; 2) Zn, HCI; 3) Cl2, FeCl3; E. none of the above EVE. none droedsw abruogo Oriollot to 8 Smund og tengsmont to 5. What set of reagents will...
In each reaction box, place the best reagent and conditions from the list below. 1) 2) Br 3) CH3CH2CH2CI, AlCl3 HNO3. H2S04 NBS, ROOR, hv H2 CH3CH2Cl, AICla , AICI AlCl3 NaBH4 Br2, FeBr3 Cl Zn(Hg), HCI Br2 In each reaction box, place the best reagent and conditions from the list below. 1) CHyCH2CH2CI, AlCl 2) 3) 4) mCPBA Pd, H2 BH3THF (CH3)3CO Br2, H20 CHCOO S ROR Br2, FeBr3 HBr Br2 In each reaction box, place the best reagent...
dd.) XS NBS CCM, A ee.) 1. fuming H2SO4 2. HNO3/H2SO4 3. Zn(Hg), HCI, A ff.) OH 1. H.Cros/acetone 2. PrMgl/Et20 3. H30* gg.) HORS. NH2 SO3 H2SO4 hh.) OE 1. LAIH/Et20/ -78 °C 2. H20 ii.) 1. Li/Et, 2. Ph Co 3. H30* jj.) Br 1. Mg/THE 2. formaldehyde 3. NHCl(aq) kk.) 2 Na, EtOH, NH3 II.) CH3BF4 mm.) SOUH 2 Na, EtOH, NH3 nn.) NO2 H2SO4(conc) HNO3(conc) NO2 00.) 1. SO3, H2SO4 2. NaOH/KOHA 3. H30*
1. Provide the major organic product(s) for each of the following reactions: 1) HNOZ/H, SO 2) Sn/HCl(aq) 3) HO 1) (CH3)2CHCI/AICI: 2) NBS/hv 1) Cly/FeCl3 2) HNO,/H2SO4 1) CH3CH,COCI/AICI 2) H20 оооооооо 3) Zn(Hg)/HCl(aq) 1) SOZ/H,SO 2) Bry/FeBrz 1) (CH3)3CCI/AICI: 2) KMnO/HOIA 2) H30* 1) CH,COCIAICI: 2) H, 3) Bry/FeBry COH 1) SOCI_/pyridine 2) PhCH/AICI 3) H20 1. Br JFeBry 2. Mg/Eto 3. oxirane 4, HO* 1) Bry/FeBry 2) s09/H230 1) NBS/hv 2) PhoNa (1 CH3COCI / AIC وا (2...
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