1. Provide the major organic product(s) for each of the following reactions: 1) HNOZ/H, SO 2)...
a.) H H_Cro acetone b.) 1. XS KMnO,/KOH/HOIA 2.H30* c.) ni XS NaBH,, H,0 H OH d.) o 1. XS LAIH/THF/-78 °C 2. H20 H OH e.) NaNH / lig NH3 f.) Br 1. Mg/THE 2. CO2 3. H30 9.) Ph Ph cyclopropene HF CH h.) OH 1. PCCICH.CH 2. Pri 3. N,Cag) 1. LITHF 2.CO 3. NH.Ca) HNO, NH 1. HNO () 2. NaSCH CH.CH AICI, 3-chloro-2-methylpentane m.) 1.Pr.CI. AICI 2. NBS, CCH n.) OH XS H.COM acetone OH...
II. Draw the structure for the major organic product of each of the following reactions. (7.5 pts each, 45 pts) Ç(CH3) 30 1) PhČCI, AICI: 11. 2) Et2NH, H2, Raney-Ni, heat 12. ÇO,Me 1) EtMgBr (2 equiv.) 2) H20, H30* O 13. CNH2 1) Bry, NaOH, H,0 O 2) (CH3)2CHCCI, pyridine 14. Brą, H20 CHO HOEH H HOH НЕОН HO+H CH OH 15. H2N. ***** оо CO2 1) (CH3),COCOCOC(CH3)3 2) -N: C: NH- 16. CHO нон PhNHNH2 H+OH (3 equiv.)...
Questions Provide the major organic product in the following reaction(s): (15 pts) A. 1) Mg/Ether 2) CO, 3) H B. 1) KCN 2) CH3-MgBr 3) H*/H30* C. 1) Bry, FeBry 2) Mg/ether 3) CO2 4)H Page Section 01
Ph cyclopropene HF CH h) OH 1. POCICH.Ch 2. Pri 3 NH4Cl ag) 1.) 1. Li/THE 2.CO 3.NH.CH HNO k.) NH 1. HNO (aq) 2. NaSCH CH.CH AICI, 3-chloro-2-methylpentane m.) 1.Pr.CI. AICI 2. NBS, CCU. n) -OH XS H.CO acetone он 0.) OH XS Bobbit's SiO, CH.CH -OH 1. Ch. AICI 2 NaOH, 30 C 4,000 psi 3. HCI 9.) SCH 2Na, ETOH, NH, r.) 1. LIETO 2. oxirane 3. H,00 1.2 PY-MOBI OMe 2. NHCl(aq) t.) 1. Cl/ Feer...
Question 3 (32 pts.) For each of the following reactions: a) Provide the missing major organic product or reagents/conditions b) Pay attention to stereochemistry and identify any racemic mixtures using the (t) symbol. NH CO/HCI a) AICI: 1. KMnO,/ OH/boil b) 2. H30+ NO2 1. H/Pd/C c) 2. Bry/FeBry :0: d) SOZ/HSO
5. Synthesis Reactions: Draw the major products for the following reactions (need not show any byproducts). (3 points each, 21 points) Note: For Diels-Alder reactions, be sure to show relative stereochemistry, if appropriate. CH (be sure to specify the CN product stereochemistry) So, H2SO. b. Br OCH AICI, (show monosub, only) 1. AICI, 2. Zn(Hg), HCI 3. HNO, H,SO d. нс Bry FeBry OCH (be sure to specify the product stereochemistry) f. 1. Brą, hv 2. NaOH
II. Draw the structure for the major organic product of each of the following reactions. (7.5 pts each, 45 pts) Ç(CH3)3 o 11. 1) PhČCI, AICI 2) EtANH, H2, Raney-Ni, heat 12. ÇO Me 1) EtMgBr (2 equiv.) 2) H20, H30* 13. o CNH2 1) Brą, NaOH, H20 o 2) (CH3)2CHCCI, pyridine 14. CHO HO+H H-OH Br2, H20 H-HOH HO+H CH2OH
Draw the major product(s) of the following reactions. 1) HNO3 H2S0 2) Zn, HCi Br 1) AICl3, CI 2) Zn(Hg), HCl, heat 1) CH3CI, AICI3 2) KMnO4, NaOH, heat 3) H3o 1)CH3C, AIC 2) Excess NBS
Draw the major product for the following reactions. -OH 2. Draw the major product for the following reactions. 1) TSCI 2) NaOEt, Heat 3) O; 4) DMS 1) NBS, heat (I cq.) 2) NaNH, DMSO 3) KMnO4 (aq) NaOH, cold 4) NaOCI, acetic acid 1) O 2) H,0 3)NI, H, 150, 100 atm 1) RBH 2) H.O, NaOH 3) NBS, heat (I eq) 1) KMnO heat 2) Na, NH, CH OH 3) Bry, light (I eq) 1) NBS, light 2)...
II. Draw the structure for the major organic product of each of the following reactions. 11. Ç(CH3) 30 1) PhČCI, AICI: 2) Et2NH, H2, Raney-Ni, heat 12. ÇO2Me 1) EtMgBr (2 equiv.) 2) H20, H30+ 13. o CNH2 1) Br2, NaOH, H20 O 2) (CH3)2CHČCI, pyridine 14. Br2, H20 CHO HOEH H -OH H-OH HOEH CH2OH