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Question 3 (32 pts.) For each of the following reactions: a) Provide the missing major organic...
Question 3 (32 pts.) For each of the following reactions: a) Provide the missing major organic product or reagents/conditions b) Pay attention to stereochemistry and identify any racemic mixtures using the (+) symbol. NH2 CO/HCI a) AICI: 1. KMnO/OH/boil b) 2. H307 NO2 1. H/Pd/C c) 2. Bry/FeBrz :0: d) SOZ/H2SO4
page that includes everything in green text Question 3 (32 pts.) For each of the following reactions: a) Provide the missing major organic product or reagents/conditions b) Pay attention to stereochemistry and identify any racemic mixtures using the (+) symbol. NH2 CO/HCI a) AICI: 1. KMnO/OH/boil b) 2. H30* NO2 1. H_/Pd/C c) 2. Bry/FeBrg :0: SOG/H2SO4 Question 4 (21 pts.) Assuming the A-systems in the following structures are flat, indicate whether they are aromatic, anti-aromatic or non-aromatic. H
Question 6, Contd... Provide the missing major organic products or reagents/conditions for the following reactions. Unless indicated otherwise, do not forget to include stereochemistry as appropriate and INDICATE ANY RACEMIC MIXTURES. OCH3 1 Equiv. CH3NH2 ignore stereochemistry NMez HCI (cat.) heat excess 1. Nat OEt OEt Eto OEt excess 2. H3O+ Ph
1. Provide the major organic product(s) for each of the following reactions: 1) HNOZ/H, SO 2) Sn/HCl(aq) 3) HO 1) (CH3)2CHCI/AICI: 2) NBS/hv 1) Cly/FeCl3 2) HNO,/H2SO4 1) CH3CH,COCI/AICI 2) H20 оооооооо 3) Zn(Hg)/HCl(aq) 1) SOZ/H,SO 2) Bry/FeBrz 1) (CH3)3CCI/AICI: 2) KMnO/HOIA 2) H30* 1) CH,COCIAICI: 2) H, 3) Bry/FeBry COH 1) SOCI_/pyridine 2) PhCH/AICI 3) H20 1. Br JFeBry 2. Mg/Eto 3. oxirane 4, HO* 1) Bry/FeBry 2) s09/H230 1) NBS/hv 2) PhoNa (1 CH3COCI / AIC وا (2...
please help asap Question 3 (36 pts.) For each of the following reactions: a) Provide the missing major organic product. Pay attention to stereochemistry unless directed otherwise and identify any racemic mixtures using the (1) symbol. c) Assign each reaction as OXIDATION or REDUCTION as appropriate NaBH, ETOH 1. Excess LIAIH 2. H2O nyomas La Na, Cr20;/H,SO/H, Excess PCC/CH_C12 OH Question 4 (22 pts.). Synthesize the target) molecule on the right from the starting molecule the left Give reagents and...
PLEASE ANSWER ALL QUESTIONS 41) Provide the major organic product of the following reaction. Bry, FeBry 42) Provide the major organic product that results when benzene is treated with the following sequence of reagents: 1. HNO3, H2SO4 2. Br2, FeBr3. Answer: NO2 43) Explain why Friedel-Crafts alkylation reactions are prone to poly alkylation, whereas Friedel- Crafts acylation reactions are not prone to polyacylation? 44) Which series of reagents would be required to perform the following synthesis? A) 1. CICH2CH2CH3, AICI;...
Which set of reagents will accomplish the following transformation? COOH NH Br A) B) C) 1) CH;CI / AICI 2) Br2/FeBrz 3) Conc. KMnO4 OH, A. then H30 4) Cl2/AICI; 5) HNO3 H2SO4 6) Sn/HCI 1) CH3C1 / AICI 2) Conc KMnO4 OH, A, then H30* 3) HNO; / H2SO4 4) Sn HCI 5) Bry/FeBrz 6) C12/AICI: 1) CH,CI/AICI: 2) Bry/FeBrz 3) Cly/AICI: 4) Conc. KMnO OH, Athen H30 5) HNO3 /H SO. 6) Sn/HCI B) D) 1) HNO; H2SO4...
Queston 6 (56 pts.). Provide the missing major organic products, or reagents/conditions, or organic reactants, as appropriate. Do not forget to include stereochemistry as appropriate unless specified otherwise. 2. Hgo :0: :o 1. Na* CN 2. H30* /heat gnore stereochemistry c) :Br: :OH d) 1 Equiv H3C CI: e) Ph h) heat (Aldol reaction)
V. Reactions. Draw the major expected products or supply the necessary reagents for each of the following reactions. Be sure to indicate stereochemistry when relevant. (21) AICI 1.) KMnO4. OH 2.) H,09 FeBry 1. HNO2, H,SO + Mg, anh. ether 2. CO2 4. LIAIH, then H 1. CH3COCI 2. Bry/FeBry 3. NaOH, HO
For each of the following questions, provide the missing reagents (that can be purchased) and conditions or predict the MAJOR product. Indicate stereochemistry and identify a racemic mixture if applicable. If no reaction occurs, write out "no reaction." . a. d. Ag,O/NH,OH "ОН e. 1) CH (CH,),Br/ 2 Li 2) HCI f но но но. (:) g. н NH NH