V. Reactions. Draw the major expected products or supply the necessary reagents for each of the...
1. Provide the major organic product(s) for each of the following reactions: 1) HNOZ/H, SO 2) Sn/HCl(aq) 3) HO 1) (CH3)2CHCI/AICI: 2) NBS/hv 1) Cly/FeCl3 2) HNO,/H2SO4 1) CH3CH,COCI/AICI 2) H20 оооооооо 3) Zn(Hg)/HCl(aq) 1) SOZ/H,SO 2) Bry/FeBrz 1) (CH3)3CCI/AICI: 2) KMnO/HOIA 2) H30* 1) CH,COCIAICI: 2) H, 3) Bry/FeBry COH 1) SOCI_/pyridine 2) PhCH/AICI 3) H20 1. Br JFeBry 2. Mg/Eto 3. oxirane 4, HO* 1) Bry/FeBry 2) s09/H230 1) NBS/hv 2) PhoNa (1 CH3COCI / AIC وا (2...
3. Give the major organic product(s) for each of the following reactions or sequences of reactions. Show all relevant stereochemistry. KMnO4 1. NaCN andere 2. H20, heat 1. LiAIH THE (c) Cou 2. H20 1. Mg, ether (d) -CHLB 2. CO2 3.H30 le) OH ether
Part A Complete the following reaction by filling in the necessary reagents. OH он о 1. CO2, NaOH 2. HCI 1. CH2OH 2. HCI 1. KMnO4, HO 2. HCI 1. CH3COCI, AICI, 2. Zn(Hg), HCI
Constants 1 Periodic Ta Part A Complete the following reaction by filling in the necessary reagents. OH OH 0 1. CO2, NaOH 2. HCI 1. CH3OH 2. HCI 1. KMnO4, HO 2. HCI 1. CH3COCI, AICI 2. Zn(Hg), HCI Submit Request Answer
5. Synthesis Reactions: Draw the major products for the following reactions (need not show any byproducts). (3 points each, 21 points) Note: For Diels-Alder reactions, be sure to show relative stereochemistry, if appropriate. CH (be sure to specify the CN product stereochemistry) So, H2SO. b. Br OCH AICI, (show monosub, only) 1. AICI, 2. Zn(Hg), HCI 3. HNO, H,SO d. нс Bry FeBry OCH (be sure to specify the product stereochemistry) f. 1. Brą, hv 2. NaOH
8. Predict the major product or products for the following reactions. Assume reagents are present in excess amounts unless otherwise indicated. Clearly depict any stereochemistry. "No Reaction is a possible answer. (4 points) each So, H2SO4 CH,CH,C1 AICI, NO Br2 FeBry OH 어 CI AICI, FeB NOH 100 °C 2.HO die HCI HO
Question 3 (32 pts.) For each of the following reactions: a) Provide the missing major organic product or reagents/conditions b) Pay attention to stereochemistry and identify any racemic mixtures using the (t) symbol. NH CO/HCI a) AICI: 1. KMnO,/ OH/boil b) 2. H30+ NO2 1. H/Pd/C c) 2. Bry/FeBry :0: d) SOZ/HSO
12 Identify the compound showing following infrared spectrum 15 Identify the reaction CH2OH sequence for the following transformation. CH (A) (B) CH3CI KMnO4, H" CH COCI LIAH AICI: AICI: Br2 CH3COCI HOCH2CH2OH Mg FeBry AICI, H30+ ether CH20 H307 wavumber om (B) (A) Хон (C) (D) Mg. Å CH,COCI H30 ОН (C) Br2 FeBry ether AICI CH3COCI BEZ Mg CH20 H30* AICI; FeBry ether (D) 13 A factor which explains the large difference in the boiling point of OCH OH...
3. (28 pts) Draw the starting material, reagents, or major products of the following reactions. Indicate stereochemistry where relevant. - 5 mino cat. NaOCH CH, OH bo He° °CH °CH, Z HOA L ambe also THF, CO, : HO. HO H. CH, OH en generall HD, HD
II. Draw the structure for the major organic product of each of the following reactions. (7.5 pts each, 45 pts) Ç(CH3) 30 1) PhČCI, AICI: 11. 2) Et2NH, H2, Raney-Ni, heat 12. ÇO,Me 1) EtMgBr (2 equiv.) 2) H20, H30* O 13. CNH2 1) Bry, NaOH, H,0 O 2) (CH3)2CHCCI, pyridine 14. Brą, H20 CHO HOEH H HOH НЕОН HO+H CH OH 15. H2N. ***** оо CO2 1) (CH3),COCOCOC(CH3)3 2) -N: C: NH- 16. CHO нон PhNHNH2 H+OH (3 equiv.)...