1.
Answer:
2.
Answer:
Mechanism:
predict products o 0 NaBH4,420H فلم OCHZ 0 - H excess NH2NH2/H+ KOH/H2O/Heat ہ H
1. predict the products KOH, H2O + Ph H heat a. (21.4) 1. LDA (strong bulky base) vi H b. 2. then heat H (21.4) c. NaOH/ H2O i i H cold (21.3) 1. LDA ܘܐ 2. e. 3. mild acid for neutralization (21.5) 2. Predict the products NaOCH2CH3 1. NaOH/H2O 2. H HOCH2CH3 Br Br 3. Heat a. Nao in ethanol of b. (C9H1403) 21.8 ol H*, Brz. C. (21.1) NaOH, Bra d. (21.3) PC13, Br2 ОН e. (21.1)
Choose
the correct reagent. What is the name of this reaction?
1.Clemmenson: NH2NH2, KOH, HEAT
2.Wolf Kishner: NH2NH2, KOH, HEAT
3.Wolf Kishner Zn(Hg)HC
HẠC -NH. trace H,O* + H₂O HAN -NH2 H30* -H₂O KOH/H2O Heat 1) Na CEN 2) H30*
Fill in the reaction's reagents/ products
1) KOH H, H2O سینه Heat 2) Ph-CH2-Br 1) 2x MgBr اللہ H 2) H20 PhCuli H Heat
5. Predict the product of the Robinson Annulation. sigue KOH, H20, heat 6. Predict the major organic products. 1. LIAIHA 2. H+ CH3CH2CH.SK 1. CH3CH_MgBr 2. H+ CH3CH2OH (CH2CH)Culi KCN H20 7. Predict the two possible products of the intramolecular Aldol condensation. chlo KOH, H20, heat
CONCEPTUAL CHECKPOINT 13.10 Predict the products for each of the following reactions O Excess oExcess Excess HBr Heat HI Heat HBr Heat O Excess Excess HI Heat Excess HI Heat HBr Heat
1. Predict the four possible Aldol condensation products and their dehydration products. in KOH, H20,4 2. Provide a mechanism for the following transformation. CH,CH, OK CH.CH,OH, heat 3. Predict all possible Claisen condensation products plus their decarboxylation products. ao 1. KOE 2.H.O. 3. heat wybos 4. Predict the product of the Dieckmann cyclization. 1. KOEI 2.H.0. 3. heat
18. Give the curved arrow mechanism for each reaction. KOH, H2O KOH,H,O O NaOH,H,O 0028
2. Predict the products of the following Grignard reactions. 1. excess EtMgBr 2. H2O Och3 B. o 1. excess CH3MgCI 2. H30*
Fill the missing reagents/products in each box: (2pts each, 12 pts total) 1) KOH H*, H2O Heat 2) Ph-CH2-Br