2.
a. Anti-cancer drug :
i. metal (Os) oxidation state : +2 ( overall charge is zero , Cl (-1) and -COO- (-1))
ii. d- electron count : 6 ( Os(II) = 5d6 )
iii. Coordination No. in complex : 9
b. [Fe4S4(SR)4]2- :
i. metal (Fe) oxidation state : +2 and +3 ( overall charge is -2 : S(-2) , -RS- (-1) )
ii. d- electron count : 5 (Fe(III) ) ; 6 (Fe(II) )
iii. Coordination No. in complex : 4
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3.
2. Indicate i. the metal oxidation state, ii. d-electron count, and iii. coordination number (CN) for...
2. Indicate i. the metal oxidation state, ii. d-electron count, and iii. coordination number (CN) for the following complex (12 Points). a. Anti-cancer drug b. [Fe4S4(SR)4]2- SR S > Fe Cmos i. i. ii. ii. iii. 5. Draw the metal coordination structure of carbonic anhydrase enzyme. Clearly show the ? geomet 21
Determine the oxidation state and valence d electron count for the metal ion in the coordination complex [Ru(NH3)6]Cl2. For the oxidation state enter your answer in form "charge value" (for example "+2").
Determine the oxidation state and coordination number of the metal ion in each complex ion. [Cu(CN)2]1- [Ag(NH3)2]1+ [Cu(OH2)4]2+ [Pt(NH3)2Cl2] [Fe(CN)6]4- [Fe(OH2)6]2+ [Zn(CN)4]2- [Cd(NH3)4]2+ [Cu(CO)5] [CuCl5]3- [Fe(EDTA)]2- [Pt(en)2]2+
For Cr(CO)3(C6H6) Write the: i) Structure ii) Formula iii) Metal Oxidation State iv) Valence electron count Thanks.
For Rh(Cl)(P(C6H5)3)3 Write the: i) Structure ii) Formula iii) Metal Oxidation State iv) Valence electron count Thanks.
(b) Determine the oxidation state of the metal, the d electron configuration, the number of unpaired electrons and the ligand field stabilisation energy for the following complexes: (i) [Co(NH3)5Br]2+ (ii) [MnO4]- (iii) [Fe(CN)6]3- (iv) [Cu(H2O)6]2+
6 Identify the coordination number (C.N.), metal oxidation state(O.S.) and the number of metal d electrons for each of the following complexes. (a) [Ni(CN):) C.N. = _ ; O.S. = __, d-electrons = d-electrons = (b) [Pd(Cl)]2 C.N. = _ ; O.S. = ___, d-electrons = (c) [Cr(CN)]C.N. =__; O.S. = —, (d) [Fe(CO).]? C.N. = __; O.S. = ___, d-electrons =- (e) [Cr(CI):]& C.N. = ___; O.S. = __, d-electrons = (1) [Ag(CN)2] C.N. = ___; O.S. = ___,...
5. For each of the following transition metal complexes, give (i) the d-electron count, (ii) the approximate shape of the complex, and (iii) an energy level diagram showing the splitting and filling of the d-orbitals. (a) [Os(CN)6]3- (b) cis-PtCl2(NH3)2 (c) [Cu(NH3)4]*
6 Identify the coordination number (C.N.), metal oxidation state(O.S.) and the number of metal d electrons for each of the following complexes. (a) [Ni(CN)s] C.N. = __;0.S. = ___, d-electrons = (b) (Pd(C1).]C.N. = ____; O.S. - ___, d-electrons = (c) (Cr(CN)] C.N. - ___.O.S. = ___, d-electrons = (d) [Fe(CO).)? C.N. = ___; O.S. = ___, d-electrons = (e) (Cr(Cl)s) C.N. = ____ ; O.S. = ____ d-electrons =_ (1) (Ag(CN)2] C.N. = _ ; O.S. = _ ,...
For tricarbonyl(η2-dihydrogen) bis(triisopropylphosphine)tungsten Write the: i) Structure ii) Formula iii) Metal Oxidation State iv) Valence electron count Thanks.