Please fill in the boxes for the empty portions of these reactions. сн. 2) Н,0* н*...
Please fill in the boxes for the empty portions of these reactions. CH3 OH Q OH OH -MgBr HC сн. сі AICI KMnO,,H,O H2C heat сн. H 636868 CI (CH,CH),Culi |
Complete the following questions/reactions by providing the missing portions shown by empty boxes. In some cases, not all boxes may be used or necessary. Show all major organic products unless otherwise specified. Make sure to clearly indicate stereochemistry where necessary. 1) CH, 2) H0* H O OH OH HCI NaOH но HO HC OH MgBr 1) THE 2) acid CH, HO Brg
14. (1 pt each) Name the following molecules. CH3 CH3 нно н н-с-с-с-NA ті Hн н,с Сн, Н CH,CH нс H 15. (3 pts each) Give the product(s) for the following reactions, and name all reactants and products. CH, он ОН н,с + нэс- сн - сн 3 нус. NH2 ОН Hн ІІ ОН + н-с-с-о-н НО P н Н ОН
Complete the following questions/reactions by providing the missing portions shown by empty boxes. In some cases, not all boxes may be used or necessary. Show all major organic products unless otherwise specified. Make sure to clearly indicate stereochemistry where necessary CH, OH OH OH Br MgBr OH но CH, C AICI, KMnO4, H2O HC heat CHE 6363638 (CH,CH, Culi
2) Order the following alkenes from most stable to least stable Нас Нас с-сн, н,с Hас +C- Нас н CHs -CH3 H Hе most stable least stable (a) I (b) I (c) I ll (d) 7) Order the following C-H bonds from strongest to weakest. strongest weakest (a) (b) (c) II (d) 8) Which of the following is represents the lowest energy transition state for the addition of BH, to 2-methyl-1-propene? quCH «сHs нСи Нас (b) (a) Нив--н H H...
need help with these Q1-Fill in the boxes with the product of the following reactions. Draw only the predominate regioisomer and indicate the stereochemistry where appropriate. If a racemic mixture is formed, you may indicate this using a wavy line or mark the chiral center with an asterisk (*), and write racemic in the box. 1) н, crо, 2) SOCI 3) Меон RT но -он NH он н,Cro, OMe дн,сго, он 1) NaOH 2) - Br Мео Гоме Н,о A/NBS
Fill in the Boxes d LiAIH4 он + ОН ether H30 SOCI ether Na2Cr2O7 acetic acid + so, CH(CH2). MgBr ether H2O HCI е. он KMnO4 H30* он ОН SO5H ОН (KSO3)2NO f. - НО SnCl2 НО он + НО ON
4. Alcohols undergo two major types of elimination reactions. Classify the following reactions as DEHYDRATION (removal of W U RCACIAD 20s Sax oa or DEHYDROGENATION (removal of hydrogen). ater) а. НС, CH2 concentrated., acid CH2 Cн Hас CH2 A-CH2 CH CH2 Н,с сн CH3 CH3 OH (Oil-D b. Н,С CH CH2 O CH2 CH2 CH H3C CHh CHh CH CH CH2 Н.С CH3 CH3 ОН CH CH2 CH2 CH2 CH2 C. CH, CH, "oн Но 4. Alcohols undergo two major...
3 pts 4. Identify and write down the (1) Major class of enzymes, (2) Subclass of enzyme? соон соон нo a, -c + —н NAD* - о + =c + H+ NADH CH3 CH, Pyruvate Lactate COO соо" + но-сн + + нс H2O NADH H+ CH CH2 -ООС -оос Fumarate L-Malate но н Он + ADP он он НО он он
2) Fill in each of the following boxes with the structure of the major reaction product(s) from each of the following reactions. (28 points total). a) Pd(PPhale NaOH b) + Pd(OA) (CH CHN CN 1. NaBH 2. H2O HH OH но -н H- OH HH OH CH,OH HNO, но NH,OH trace of acid 1. CHI (excess 2. Ag,0 H2O, heat CI 1 CRUS POY Grubbs catalyst) Page 2 of 5