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d LiAIH4 он + ОН ether H30 SOCI ether Na2Cr2O7 acetic acid...
Draw the major product for each reaction. он. CH3 heat N(CH3)3 a. LiAIH4, Et20 b. H30*/H20...
Draw the major product for each reaction. он. CH3 heat N(CH3)3 a. LiAIH4, Et20 b. H30*/H20 1. NaCN, DMSO Br 2. a. LiAIH4. THF b. H3O+/H2O 1. NaN3, DMSO Br 2. a. LiAIH4, THF b. H3O /H20 1. HNO3, H2SO4 2. SnCl2 3. Br2 4. a. HNO2, H2SO4 H3C b. H2PO2 NH2 1. NaNO2, HCI, H20 но 2. HBF4
Help! 1. 1. LIAIH4 / dry ether он 2. aqueous H2S04 2. AICl3 Ci но dSN2...
Help!
1. 1. LIAIH4 / dry ether он 2. aqueous H2S04 2. AICl3 Ci но dSN2 Nucleophilic substitutiong a = Electrophilic addition b E2 Elimination c SN1 Nucleophilic substitution f Carbonyl nucleophilic addn g = Nucleophilic subs at carbonyl(acyl Xfer) h = Conjugate (nucleophilic) addn Electrophilic aromatic substitution Identify the mechanism by which each of the reactions above proceeds from among the mechanisms listed. Use the letters a -i for your answers. 2. Review Topics] 1. HCI reflux он +...
draw out structures or reagents Draw out either the structures or the reagents A-Q needed to...
draw out structures or reagents
Draw out either the structures or the reagents A-Q needed to complete the reaction roadmap below 1) CuLi(CH-CH(), 0 2) H.O 1) Mg 2) formaldehyde Br 3) H30 G H2C1 CH3 HyC N B 1)Bry(excess), NaOH 2)HCI PCC F PBr3 E NaOH A Р I 1) Dibal 2) H,O, CH Nz, ether HCI 1) TOSCI, pyridine 2) NaH SOCI J 1) NaBr 2) H30 H M 1) 2CH,MgBr 2) H,O, HCI HECHC=CH2 Acetic Acid NaOCH...
Fill in the boxes over each arrow with the letter that corresponds to the reagents needed to perform each step of the multistep synthesis show below. Reagents may be used more than once, or not at all...
Fill in the boxes over each arrow with the letter that
corresponds to the reagents needed to perform each step of the
multistep synthesis show below. Reagents may be used more than
once, or not at all. Pay close attention to the numbered carbons in
the starting material, and be sure that your answer accounts for
the position of these carbons in the final product.
pts) Fill in the boxes over each arrow with the letter that corresponds to the...
please need help with all the questions and ASAP, thank you 11. Please predict the principle...
please need help with all the questions and ASAP, thank you
11. Please predict the principle organic product of the following reactions, show stereochemistry where appropriate. Note that some reactions involve isotope-labeled compounds, in those cases the correct isotope must be used. (66') 1. LIAID 2. H,O (1) 18 1) THF (2). CH3Li + 2) HaO NaBH4 (3) CH3OD H2(excess)/Pt (4) d herd (5). - Mg Br D2O diethyl ether Br +Li (6) diethyl ether LICu(CH2CHs)2 Br (7). 1. diethyl...
Hc VCH Draw the organic product formed when CH3CH2CH2OH is treated with each reagent. a H2S04 (180°C) d SOC12, pyri...
Hc VCH Draw the organic product formed when CH3CH2CH2OH is treated with each reagent. a H2S04 (180°C) d SOC12, pyridine Ig 1) NaH; 2) CH3CH2Br b NaH e PBr3 h 1) TSCI, pyridine; 2) NaSH c HBr f TsCl, pyridine 3. Draw the organic product formed when l-methylcyclohexanol is treaded with each reagent. In some cases, no reaction occurs. a KH c HBr Te NaHCO3 b Nacid HCI f 1) KH; 2) CH3CH2Br Draw two different routes to each of...
What is the correct name for the following compound? d) 5-oxo-3-octenoic acid What is the defining...
What is the correct name for the following compound? d) 5-oxo-3-octenoic acid What is the defining functional group of a carboxylic acid? a) an-H attached to a carbonyl group b) an-H attached to a carbon-carbon triple bond c) an-OH attached to a carbonyl group d) an -OH group attached to a O-C double bond e) an-OH group attached to an aromatic ring To convert a carboxylic acid to an aldehyde a) convert the acid to an acid chloride, then use...
Please I need help on this. I'm so lost 1. Acetic acid (H)CO2H) has k, =...
Please I need help on this. I'm so lost
1. Acetic acid (H)CO2H) has k, = 1.8 x 10- and acetate (H:C:01") has ks = 5.6 x 10-10. (a) Write balanced chemical equilibrium equations (with physical states) for acid dissociation of acetic acid and base hydrolysis of acetate ion. (b) Write K, and equilibrium constant expressions for the above reactions. (c) Use your expressions from part b to show that Kx. = 1.0 x 10-* = [H,O'][OH). 2. For each...
18. Draw the structures of Compound 18a. and 18b. (18 pts), clearly indicate your assignments of...
18. Draw the structures of Compound 18a. and 18b. (18 pts), clearly indicate your assignments of all proton resonances (8 pts). Calculate the Unsaturation Index of each compound (4 pts) (30 points total) 30 Unsat. Index = (2C+2-H-X+NY2 = 200 25 e = 2.00 ppm, 4.90 f = 1.27 ppm, 20 720 Compound 18a: C,H,O, singlet, 2H triplet, 3H 127 15 d = 2.66 ppm, a = 7.21 ppm, b = 7.18 ppm, doublet, 2H doublet, 2H C = 4.90...
Draw the major product for each reaction. он. CH3 heat N(CH3)3 a. LiAIH4, Et20 b. H30*/H20 1. NaCN, DMSO Br 2. a. LiAIH4. THF b. H3O+/H2O 1. NaN3, DMSO Br 2. a. LiAIH4, THF b. H3O /H20 1. HNO3, H2SO4 2. SnCl2 3. Br2 4. a. HNO2, H2SO4 H3C b. H2PO2 NH2 1. NaNO2, HCI, H20 но 2. HBF4
Help!
1. 1. LIAIH4 / dry ether он 2. aqueous H2S04 2. AICl3 Ci но dSN2 Nucleophilic substitutiong a = Electrophilic addition b E2 Elimination c SN1 Nucleophilic substitution f Carbonyl nucleophilic addn g = Nucleophilic subs at carbonyl(acyl Xfer) h = Conjugate (nucleophilic) addn Electrophilic aromatic substitution Identify the mechanism by which each of the reactions above proceeds from among the mechanisms listed. Use the letters a -i for your answers. 2. Review Topics] 1. HCI reflux он +...
draw out structures or reagents
Draw out either the structures or the reagents A-Q needed to complete the reaction roadmap below 1) CuLi(CH-CH(), 0 2) H.O 1) Mg 2) formaldehyde Br 3) H30 G H2C1 CH3 HyC N B 1)Bry(excess), NaOH 2)HCI PCC F PBr3 E NaOH A Р I 1) Dibal 2) H,O, CH Nz, ether HCI 1) TOSCI, pyridine 2) NaH SOCI J 1) NaBr 2) H30 H M 1) 2CH,MgBr 2) H,O, HCI HECHC=CH2 Acetic Acid NaOCH...
Fill in the boxes over each arrow with the letter that
corresponds to the reagents needed to perform each step of the
multistep synthesis show below. Reagents may be used more than
once, or not at all. Pay close attention to the numbered carbons in
the starting material, and be sure that your answer accounts for
the position of these carbons in the final product.
pts) Fill in the boxes over each arrow with the letter that corresponds to the...
please need help with all the questions and ASAP, thank you
11. Please predict the principle organic product of the following reactions, show stereochemistry where appropriate. Note that some reactions involve isotope-labeled compounds, in those cases the correct isotope must be used. (66') 1. LIAID 2. H,O (1) 18 1) THF (2). CH3Li + 2) HaO NaBH4 (3) CH3OD H2(excess)/Pt (4) d herd (5). - Mg Br D2O diethyl ether Br +Li (6) diethyl ether LICu(CH2CHs)2 Br (7). 1. diethyl...
Hc VCH Draw the organic product formed when CH3CH2CH2OH is treated with each reagent. a H2S04 (180°C) d SOC12, pyridine Ig 1) NaH; 2) CH3CH2Br b NaH e PBr3 h 1) TSCI, pyridine; 2) NaSH c HBr f TsCl, pyridine 3. Draw the organic product formed when l-methylcyclohexanol is treaded with each reagent. In some cases, no reaction occurs. a KH c HBr Te NaHCO3 b Nacid HCI f 1) KH; 2) CH3CH2Br Draw two different routes to each of...
What is the correct name for the following compound? d) 5-oxo-3-octenoic acid What is the defining functional group of a carboxylic acid? a) an-H attached to a carbonyl group b) an-H attached to a carbon-carbon triple bond c) an-OH attached to a carbonyl group d) an -OH group attached to a O-C double bond e) an-OH group attached to an aromatic ring To convert a carboxylic acid to an aldehyde a) convert the acid to an acid chloride, then use...
Please I need help on this. I'm so lost
1. Acetic acid (H)CO2H) has k, = 1.8 x 10- and acetate (H:C:01") has ks = 5.6 x 10-10. (a) Write balanced chemical equilibrium equations (with physical states) for acid dissociation of acetic acid and base hydrolysis of acetate ion. (b) Write K, and equilibrium constant expressions for the above reactions. (c) Use your expressions from part b to show that Kx. = 1.0 x 10-* = [H,O'][OH). 2. For each...
18. Draw the structures of Compound 18a. and 18b. (18 pts), clearly indicate your assignments of all proton resonances (8 pts). Calculate the Unsaturation Index of each compound (4 pts) (30 points total) 30 Unsat. Index = (2C+2-H-X+NY2 = 200 25 e = 2.00 ppm, 4.90 f = 1.27 ppm, 20 720 Compound 18a: C,H,O, singlet, 2H triplet, 3H 127 15 d = 2.66 ppm, a = 7.21 ppm, b = 7.18 ppm, doublet, 2H doublet, 2H C = 4.90...
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