In ques 9
Option a is correct as because both 1st and 2nd will go 1,2 methyl shift to form tertiary carbocation which is stable due to hyperconjugation.
Where as compound 3 undergoes a 1, 3 methyl shift which is much slower as compared to 1,2 methyl shift. Hence remaing all options are incorrect.
Question 9 (2 points) Which of the following carbocations is (are) likely to undergo rearrangement through...
Question 47 (2 points) Which of the following carbocations is (are) likely to undergo rearrangement through a methyl shift? нус CH HC CH нус CH oa) both II and III ob) oc) 11 od) both I and II Question 48 (2 points) For the reaction shown, select the expected major organic product. 1. 1 e HCI 2 1 e HBO Ho Br + enantiomer + enantiomer + enantiomer + enantiomer IV 11 HI! Oa) 1 ob) 11 Oc) III od)...
Question 41 (2 points) Which of the following carbocations is (are) likely to undergo rearrangement through a methyl shift? H2C CH3 H3C CH3 H3C CH3 III a) both II and III Ob) both I and II Oc) Od) Question 42 (2 points) For the reaction shown, select the expected major organic product. 1. 1 eq HCI 2. 1 eq HBr Br. CI -Br -CI Ha CI Br + enantiomer + enantiomer + enantiomer CI Br + enantiomer IV 11 III...
4. Which of the following carbocations would be likely to undergo rearrangement? A) CH3-CH-CH-CH3 CH3 CH3 B) CH3-CH-?_CH3 CH3 CH3 C) CH3-C-CH2-CH3 D) More than one of the above E) All of the above t he dehydrated to an al
10. Which of the following cations is most likely to undergo rearrangement? Is the rearrangement a methyl shift or hydride shift? A. O L c. Yo Do
6. Which of the following carbocations would NOT be likely to undergo rearrangement? A) CH3CHCHCH3 CH3 CH3 B) CH3CHOCH3 CH3 CH C) CH3CCH2 CH3 D) CH3 CH3CHCH2 E) CH3 CH3CCHCH2CH3 CH3 7. Which alcohol would initially produce the most stable carbocation when treated with concentrated H2SO4? A) CH3 CH3CCH2 CH3 он CH3 B) CH3CHCHCH3 он CH3 C) CH3CHCH2CH2OH CH3 D) HOCH2 CHCH2CH3 E) CH2 OH CH3CHCH2CH3 Page 4
1. Which of the following structures is/are a secondary alkyl
halide? (a) I and II (b) II and V (c) I, II and V (d) IV only (e)
I, II and III 2. Which of the following is/are aprotic solvent(s)?
Choose all correct answers. (a) (b) (c) (d) (e) (f) 3. Which of the
following carbocations, if formed, is (are) likely to undergo
rearrangement through a hydride shift? (a) I (b) II (c) III (d) I
and II (e) II...
Which of the following carbocations is most likely to undergoe a rearrangement? ( Hint: Remember that a 1,2-shift can involve a shift of -H or -R Il IV QUESTION 27 Which of the following alkyl halides will undergo E2 elimination of HBr more rapidly (assume that elimination is induced by "OCH3)? Br Br AI B QUESTION 29 Is the configuration of the following molecule R or S? H OAR B. S chirality center present C Neither, there is no
D) Br 6. Which of the following alkyl bromides is likely to undergo rearrangement by a 1, 2-methyl shift during an Sy1 or El reaction (both reaction mechanisms form a carbocation)? A) benzylł bromide B) 2 -bromo 3-ethytpentane C) 3-bromo-3-methylpentane D) 2-bromo-3, 3-dimethylpentane r is untrue about the rate of an E2 elimination of an alky
Question 9 1 pts Which ane of the following carbocations, as drawn, is the mast stable? Me CH (methyl cation) Cна Me Me Question 10 1 pts With respect to the previous question, which carbocation (A, B, C, D, or E) is most likely to undergo a 1,2-hydride shift to generate a more stable carbocation? A
Which of the following alkyl halides is likely to undergo rearrangement by a 1, 2- methyl shift? A) 3-bromo-3-methylpentane B) 2-chloro-3, 3-dimethylpentane C) 3-bromo-2, 3-dimethylpentane D) 2-iodo-2-methylpentane Which of the following alkyl halides is the worst substrate for the Sn2 reaction? A) Br B) Br C) Br D) Br In the mechanism for the reaction shown below, the first curved arrow moves from_ to Н. CH3CH2NH2 H3C + CH3 A) carbon (in CH3CH2NH2) to oxygen B) oxygen to nitrogen C)...