among these four molecules only the option "D" Compound give secondary carbocation where the methyl group migration occur to give tartiary carbocation and more stable to give both SN1and E1 reaction.
D) Br 6. Which of the following alkyl bromides is likely to undergo rearrangement by a...
Which of the following alkyl halides is likely to undergo rearrangement by a 1, 2- methyl shift? A) 3-bromo-3-methylpentane B) 2-chloro-3, 3-dimethylpentane C) 3-bromo-2, 3-dimethylpentane D) 2-iodo-2-methylpentane Which of the following alkyl halides is the worst substrate for the Sn2 reaction? A) Br B) Br C) Br D) Br In the mechanism for the reaction shown below, the first curved arrow moves from_ to Н. CH3CH2NH2 H3C + CH3 A) carbon (in CH3CH2NH2) to oxygen B) oxygen to nitrogen C)...
Page 9 of 60 Question 9 (1 point) Which of the following alkyl halides is likely to undergo rearrangement by a 1, 2- methyl shift? A) 2-iodo-2-methylpentane B) 3-bromo-3-methylpentane C) 3-bromo-2, 3-dimethylpentane D) 2-chloro-3, 3-dimethylpentane
Which of the following alkyl bromides would undergo a relatively fast E2-type elimination reaction? Br Br A) B) C) D) Br odov Br A B D
Which of the following alkyl bromides would undergo a relatively fast E2-type elimination reaction? Br Br A) B) C) D) oc "A dd Br Br А с
Given the following alkyl bromides, select the alkyl bromide that will undergo SN1 solvolysis with water to form the corresponding alcohol product the fastest. Br Br Br
Which of the following carbocations is most likely to undergoe a rearrangement? ( Hint: Remember that a 1,2-shift can involve a shift of -H or -R Il IV QUESTION 27 Which of the following alkyl halides will undergo E2 elimination of HBr more rapidly (assume that elimination is induced by "OCH3)? Br Br AI B QUESTION 29 Is the configuration of the following molecule R or S? H OAR B. S chirality center present C Neither, there is no
10. Which of the following cations is most likely to undergo rearrangement? Is the rearrangement a methyl shift or hydride shift? A. O L c. Yo Do
Ex. Credit 1 show product of E2: "saw-horse" subst. alkyl bromide MUST be put in the "anti Coplanar conformation." 2. Problem with bromo-methyl cycloalkane produces 5 products via SN1/ El: show mechanism for all five products. 3.Pinnicol/ pinnicolone rearrangement Ex. Credit 1 show product of E2: "saw-horse" subst. alkyl bromide MUST be put in the "anti Coplanar conformation." 2. Problem with bromo-methyl cycloalkane produces 5 products via SN1/ El: show mechanism for all five products. 3.Pinnicol/ pinnicolone rearrangement
Please help me understand why this is the correct answer 5. which of the following alkyl halides is most likely to undergo rearrangement in an SNI reaction? A) 2-chloro-3,3-dimethylpentane B) 1-bromo-4-methylcyclohexane C) 3-bromopentane D) 3-chloropentane CH3 c-C-C-L-C
(2) Diels-Alder reactions of a diene with a dienophile are known to undergo a concerted reaction. However, 2,3-Di- tert-1,3-butadene does not undergo Diels-Aider reactions. Explain 2,3-di-tert-1,3-butadiene (4) Propose mechanisms for the following steps 1 and 2. Slep 1 Step 2 Bry Br NaBH CH acetic acid (I) Using> as a symbol, rank the following alkyl bromides in order of decreasing reactivity. (6 pts) Br Cн,Br -Br (a) For hydrolysis by an Sy1 mechanism (b) For hydrolysis by an S,2 mechanism...