2. (5 pts) Calculate the Ecell of the following galvanic battery configuration. Als e flow e...
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4. Consider an electrochemical cell (a.k.a. galvanic cell or voltaic cell) with Ag(s) and 1.0 M AgNO3(aq) in one compartment and Cu(s) and 1.0 M Cu(NO3)2(aq) in the other compartment. Write the reactions and calculate the standard state cell potential at 298 K. E cathode = a. Reduction (cathode): Eanode = b. Oxidation (anode): Eºcell = C. Net (overall cell reaction): 5. Consider a galvanic cell with Sn(s) and 1.0 M Sn(NO3)2(aq) in one...
Part A through H
1. [60 pts) A galvanic cell is a type of battery where the electrodes are immersed in different electrolyte solutions, which are connected by an ion-conducting bridge. Consider a galvanic cell with Al and Cu electrodes. The Al electrode is immersed in a solution containing a standard concentration of Al3+ ions and the Cu electrode is immersed in a solution containing a standard concentration of Cu* ions. External Circuit The standard reduction potentials for the half...
4. Consider a Galvanic cell constructed from the following half cells, linked by an external circuit and by a KCl salt bridge. - an Al(s) electrode in 1.0 M AI(NO3)3 solution - a Pb(s) electrode in 1.0 M Pb(NO3)2 solution The balanced overall (net) cell reaction is 5. Calculate the value of Eºcell for the following reaction: 2Au(s) + 3 Ca2+(aq) → AU3+ (aq) + 3 Ca(s) 6. Determine the equilibrium constant, Keq, at 25°C for the reaction 2Br (aq)...
Table view List view Ecell (calculated) Ecell (calculated) 1.115 1.124 Table 1. Voltaic cells data table Ecell (measured) Reaction Quotient Q 1. Zn | Zn2(1.0M) || Cu2+(1.0 M) | Cu 2. Zn | Zn2+(1.0 M) || Cu2+(0.1 M) Cu 1.067 3. ZnZn2+(0.1 M) || Cu2+(1.0 M) | Cu 4. Zn | Zn2+(1.0 M) || Pb2+(1.0 M) | Pb 5. ZnZn2(1.0M) || Pb2+(0.1 M) | Pb 0.600 6. Zn | Zn2+(0.1 M) || Pb2+(1.0 M) I Pb 0.644 7. ZnZn2+(1.0 M)...
2) On the standard galvanic cell schematic shown below, add labels for: (2 pts) A) Anode B) Cathode C) Salt Bridge D) Show the direction of electron flow through the wire Equations and Constants: AG --FE E-Eº - (RT/nF)InQ R-8.3145 J/mol K F-96485 J/V mole (7 pts) 3) For the galvanic cell represented by Zn(s)Zn²+ (aq)|| Ag (aq)| Ag(s) Voltmeter A) Write the anode half reaction Zn(s) JAg(s) B) Write the cathode half reaction C) Write the net reduction-oxidation reaction...
The following electrochemical cell was set up in the lab Ag(s)│Ag(NO3)(aq)││KMnO4(aq), HCl(aq), Mn(Cl)2(aq)│Pt(s) What is Ecell° for this galvanic cell? If a more complete description of the cell is Ag(s)│Ag(NO3)(aq, 0.50 M)││KMnO4(aq, 0.50 M), HCl(aq, 2.5 M), Mn(Cl)2(aq, 0.01 M)│Pt(s), Ag(s) what is Ecell? What is the balanced, spontaneous cell reaction for the cell conditions given in b.?
What is the standard emf of a galvanic cell made of a Co electrode in a 1.0 M Co(NO32 solution and a Al electrode in a 1.0 M AI(NO3)3 solution at 25°C? 0 cell Standard Reduction Potentials at 25°C Half-Reaction E(V +2.87 +2.07 +1.82 O,(g) 2H (aq)2e0(g)+HO Co3+(aq) + e-_? Co2+(aq) H,02(aq) + 2H"(aq) + 2e-_ 2H20 Cu2+(aq) + 2e-? Cu(s) AgCIs) + Ag(s) + CI(a) S02-(aq) + 4H'(aq) + 2e S02(g) + 2H20 Cu2+(aq) + e-_ Cu+(aq) Sn (aq)...
Calculate the Ecell value at 298 K for the cell based on the reaction: Cu(s) + 2Ag+ (aq) → Cu2+ (aq) + 2Ag(s) where [Ag+] = 0.00350 M and [Cu2+] = 7.00x10-4 M. The standard reduction potentials are shown below: Ag+(aq) +e → Ag(s) E° = 0.7996 V Cu2+ (aq) + 2e -→ Cu(s) E° = 0.3419 V 2nd attempt Ecell = V
Sketch the galvanic cell based on a half-cell containing 0.1 M Cu(NO3)2 with a Cu(s) electrode and a half-cell containing 0.001 M Fe(NO3)2 with an Fe(s) electrode. Show the direction of electron flow and identify the cathode and the anode. Calculate Ecell and ∆G at 25 ◦C.
data collected
Cu(NO3)2 | Zn(NO3)2 = 0.999 V
Pb | 1.0 M Pb(NO3)2 || 1.0 M Zn(NO3)2 | Zn = 0.396 V
PART B: REDUCTION POTENTIALS 1. Report the measured cell potential for each galvanic cell and state which electrode corresponds to the cathode and which to the anode. 2. Given E = -0.76 V for the Zn/Zn half-cell, and your measured Ecell, calculate the reduction potential at the Cu and Pb electrodes and write the redox half- 6 reactions...