Please help with both if possible!
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Please help with both if possible! 1. Provide the missing reactants or products for the reactions...
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1) (27 points) Provide the missing reactants, reagents or products 1) NaBH4 2) H30* H30+ H - Nat COH HỌN NH2NH2, KOH 2) H30+ CrO3 H2504 HO H2O 1) Mg, EtOEt \ОН 3) H30+ 2) (27 points) Draw "arrow pushing" mechanisms for THREE of the reactions in question 1
1. Provide the products for the following reactions (2 points, 1 point per question). 1) NaOH, Br2 2) H30+ pentanol, H2O+ 2. Draw the mechanism for the following (1.5 point). ethanol, H30+ ОН 3. If you were doing the reaction shown in #2 in lab, how would you use IR to determine if you formed the product or a mixture of product and starting material (0.5 points)? 4. Draw the 'H-NMR for the structure below. Label each peak on the...
1. Give the missing reagents, reactants or products for each of the following reactions. KOC(CH3)2 (E2) 1. BH3 2. H2O2, NaOH, H2O PCC HBr/ROOR how many stereoisomers? PCC ad Excess H, H CH2Cl2 OT_HBr SN2 give one stereoisomer SN2 NaCN ACN (solvent) KMnO4 H2SO4 NaOEt (E2) mCPBA H2SO4 (cat) don't worry about this reaction ОН PCC CH2Cl2 NaOEt (E2) mCPBA H2SO4 (cat) don't worry about this reaction OH PCC CH2Cl2 HI (SN1)
1. Give the missing reagents, reactants or products for each of the following reactions. KOC(CH . (E2) 1.BH 2. H2O NaOH, HÔ PCC HB/ROOR how many stereoisomers? how many stereoisomers? PCC Excess H2O H CH2C12 HB Nal SN2 give one stereoisomer SN2 NaCN ACN (solvent) KMnO4 HO H2SO mCPBA NaOEt (E2) H2SO4 (cat) don't worry about this reaction OH OH KMnO4 H2SO4 NaOEt (E2) mCPBA H2SO4 (cat) don't worry about this reaction OH Рcc CH2C12 HI (SN1)
Determine the missing products or reagents. Draw arrow pushing
mechanisms for 3 of the above reactions.
1) (27 points) Provide the missing reactants, reagents or products 1) NaBH4 2) H30+ H30* H-= - Nat CO2H HON H+ muly & West NH NH2, KOH 1) PP / H 2) H30+ Croz H2SO4 HO H20 1) Mg, EtOEt OH 3) H30+
Please Print! 2. Fill in the missing reactants, reagents & conditions, or products. Show stereochemistry where appropriate. 10 points. MgBr OH then H30+ „CH₃ HAN CH3 Ht cat MgBr N-CH₃ Мео (then H30t Meo он NaCN -CH3 CH₃ OTS CN or CH "CH₃ +
4. Fill-in-the-blanks: draw the missing reactants or products involved in the following single or multi-step reactions. Indicate stereochemistry and draw multiple stereoisomers where applicable. i EtOH EtOH [H2SO4] 1) EtMgBr 2) H20 5. For most ketones, hydrate formation is unfavorable, because the equilibrium favors the ketone rather than the hydrate. However, the equilibrium for hydration of hexafluoroacetone favors the hydrate. Propose a mechanism for this transformation below and provide an explanation for this observation. H2O Но он F3CX CF3 F3C...
Queston 6 (56 pts.). Provide the missing major organic products, or reagents/conditions, or organic reactants, as appropriate. Do not forget to include stereochemistry as appropriate unless specified otherwise. 2. Hgo :0: :o 1. Na* CN 2. H30* /heat gnore stereochemistry c) :Br: :OH d) 1 Equiv H3C CI: e) Ph h) heat (Aldol reaction)
3. (5pts each) For the following reactions, in each box please provide the missing reage or predict the reactants or major products. 1) LDA 2) a. Br Br b. ОН ix x PPh3 c. H d. NaOH, H2O, heat 2eq GE2 e. キミのIII f. -GEN 1) Me-MgBr 2) H,0
give reactants, reagents, and/or products for the following
reactions, as appropriate.
reactants, reagents, and/or products for the following reactions, as appropriate SOCI dom OH 1) NaBH, (excess) SOCIE OCH 2) H,O* OH, H2O (excess) 1. CH3CH2MgBr (excess) 2. H30 NaBH4 (excess) Br 1) Mg, ether 2) H30*