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Part II - Reactions (16 marks] Draw the expected major product(s) for each of the following...
page 3 of 5 Chem 231, Assignment 5 Part II - Reactions (16 marks] Draw the expected major product(s) for each of the following reactions. Question Answer 8. 1. Nah OH ? 2. OTS 9. NBS major product 10. Nal Br 7 Acetone Br 11. 1. NaNH2 HEC-CECH ? 2. OTS 12. OH Br NaOH ? cyclic compound 13. OH HBr ? 14. ? ON cat. H2SO4 H2O Room temp. 15. Br MeOH ?
Part I – Reactions Draw the expected major product(s) or required reagent(s) for each of the following reactions. Part 1 - Reactions (20 marks) Draw the expected major product(s) or required reagent(s) for each of the following reactions. Question Answer 1. MgBr 1. CH3CN 2. H30* 2. OH HT ОН 3. Br PPh3 1. BULI 2. CH20 CI (1 mole) ОН 5. 1. LDA ? (directed aldol condensation) 2. CH3CHO 6. HO H (cat) OH ? (cyclic anhydride) . (-H20)...
Problem 10. Draw the structure of the major product formed in each of the following reactions. Consider the resulting stereochemistry of the products formed (6p) KBr ng MeOH NaF DMSO H2(g), Pd (cat.) c) Solvent OH 1) NaH (strong base) THF (solvent) d) 2) CI Nal e) CI Acetone
Evening SN2 vs. E2 Homework Predict the major product(s) expected for each of the following reactions. Remember to indica stereochemistry, when appropriate. If no reaction is expected, write NR. a. CH3CN opothe Na t-BuO t-BuOH Rrot b. C. H3C d. H3C Br e. OH EtOH Pro NaN3 OH acetone poic NaOH Stos nlphe h. OTS EtOH pokc
6) Predict the major product in each of the following reactions and indicate if it came from an Sn1, S2, E1, or E2 reaction. H3C Br NaOme CH3 H2O H Br MeOH 'BUOK H Br DMSO H3C Br NaOme CH3 H20 MeOH H OTS ЕКОН
. Draw the expected major product(s) or required reagent(s) for each of the following reactions. 5. to 1. LDA ? (directed aldol condensation) 2. CH3CHO 6. HO OH H (cat) (-H20) ? (cyclic anhydride) 7. ? ? -NHCH3 5. to 1. LDA ? (directed aldol condensation) 2. CH3CHO 6. HO OH H (cat) (-H20) ? (cyclic anhydride) 7. ? ? -NHCH3
1. PREDICT THE PRODUCT: Provide the structure of the major product expected from the following reactions or reaction sequences. Make sure you account for any regio- and/or stereochemistry! (24 pts.) H2O 1. Hg(OAC), CH, OH 2. NaBH H2SO4 H20 1) BH-THF 2) H202, KOH HBr Bry, H2O HBr ROOR 1. BH3-THF 2. H2O2, NaOH H20, H2SO4 1. NaNH2 H2 H-CEC-CH2 CH2 CH3 2. CH CH Br Lindlar cat 1. Sia BH-THF 2. H2O2, H2O
please explain the work 1. Predict the major organic product for each of the following elimination reactions, and indicate whether each one occurs via the E1 or the E2 mechanism. Be sure to clearly indicate the proper stereochemical relationships between groups (if appropriate), and write the word "racemic" under any compound that is formed as a racemic mixture. Br H3CY CH3 NaOCH3. CH3OH OH يلي H2SO4 ما H3c OTS KOt-Bu t-BuOH AgNO3 H20 Ph HC, NaOH H2O OH H2SO4
Unit 3 Hinw '3 SNİSNDELE2 1. Give the major product(s) for the following reactions. Indicate the mec reaction occurs, write "no reaction. s) in operation. If no KOC(CH) (CH COH b. H3C NaNH2 NHy Nal H3C H2CH-CH3 CH,COCH CH OH CH3 2. Give the mechanism of each of the following reactions. NaCN CH CH CHCN NaBr a. CH,CH,CH Br acetone HSCH,CH (CH) CSCH,CH3 HBr Cl + NaCI + CH OH NaOCH CH3OH Br CH OH CH3
Complete the following reaction with the major product Reactions: complete the following reaction with the major product HBr он 1- OH POCl3 pyridine 2- H2SO4 OH 3- Hl 4- H20 H3PO4 5- Cl2 H20 7- 1) BH2-THF 2) H202, KOH 8- 2) 9- 1) BH3-THF 10- DLL 10- Date: G# : 12, and 13- Br H20 но 2) NaH 14, and 15- ) NaOH i NaOH 2 dil H.0 3) PBr 3)HBr F6 FZ F8