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D) (4 pts) Draw the ring flip of the given molecule. Label which is the lower...
C) (3 pts) Write the condensed formula of the given bond-line structure. Im OH D) (4 pts) Draw the ring flip of the given molecule. Label which is the lower energy. CI Br
4 points Draw the following molecule after it undergoes a chair flip. H Chair flip "CHз -H Br
1. Now construct cis-1,2-dimethylcyclohexane in the chair conformation and draw it. Perform the ring flip and draw that conformation. Which of the two conformations is preferred? This compound is meso, find the conformation that accounts for this? 2. Construct and draw trans-1-ethyl-2-methylcyclohexane in the chair conformation. Perform the ring flip and draw that conformation. Which conformation is preferred/most stable? Why? Construct and draw the cis isomer in the most stable chair conformation. Perform the ring flip and draw that conformation....
002OU NAME (PRINT): 10.30.19 RING FLIP (5P75): Provide the ring-flipped conformation for CIS 1,3-dimethylcyclohexane A. Circle the conformation that is lower in energy. B Label bonds off chair as A for axial and E for equatorial. C. Number carbons in chair. EXAMPLE Lower in Energy g
5. Draw the ring-flip and determine their relative energies. --CH O (CHDC- OH 6 pts 6. Draw the conformations of the following compound and rank their relative stability.
9. Draw the chair conformations of the substitute cyclohexanes showing the ring flip.. Show axial and equitorial bonds clearly. Label which conformation is most stable or if @ l-ethyl cyclohexane they are equal. O CIS-1,2-dimetyl cyclohexane © trans-1,2-dimethyl cyclohexane
4. (6pts) Label each molecule as a nucleophile or electrophile AND draw an arrow pointing to the atom on the molecule that would be the nucleophile or electrophile CI CEN HTΉ I verbo on si smith H-C-OH I-O-I H₃C – NH₂ Hool H3CH
1. (a) Draw the two chair conformations for this molecule. (3 pts) (b) Label the more stable conformation (1 pt) 2. Provide (RS)-designations for the two starred (1) stereogenic centers (3 pts) 3. Use a Newman projection to draw the most stable conformation for the C(3)-C(4) bond in this molecule. (3 pts) OH 3-fluoro-3-methylpentan-1-ol
Draw the newman projections for 1,4 dimethylcyclohexane for cis and trans with ring flip. there should be 4 newman projections.
1. Draw a chair conformation of cis-1-tert-butyl-2-ethyleyclohexane. Then, ring flip the chair to generate the other chair conformation, Circle the most stable conformation of the molecule (8 pts). 2. Designate the RIS configuration of all the stereocenters in the following molecules (8 pts): OH HO+CH3 H oH CHCI 3. Identify the relationship between the following molecules as: identical, constitutional isomers. enantiomers, or diastereomers (8 pts). enantiomers. e home enantiomers diastereomers. ó Tenantiomers. I Ć dias tereomers. MAC mome of the...