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draw the major product 14. HNO, CHO Но+н H-HOH H-HOH HO+H CH2OH 15. oo HNcO; 1)...
give major product O 11. Ç(CH3)3 1) CH3CCI, AICI: 2) (CH3)2NH H2, Raney-Ni, heat 12. ÇO Me 1) PhMgBr (2 equiv.) 2) H20, H30 13. CNH2 1) Brz, NaOH, H20 2) CH,CCI, pyridine 14. HNO3 CHO но +н н+он н+он нон CH OH оо 15. H2NCO, 1) (CH3),COCOCOC(CH3)3 Ph -N: C: NH- PhNHNH | 16. CHO HOTH HOH (3 equiv.) H-OH HO+H CH2OH ai
II. Draw the structure for the major organic product of each of the following reactions. (7.5 pts each, 45 pts) Ç(CH3) 30 1) PhČCI, AICI: 11. 2) Et2NH, H2, Raney-Ni, heat 12. ÇO,Me 1) EtMgBr (2 equiv.) 2) H20, H30* O 13. CNH2 1) Bry, NaOH, H,0 O 2) (CH3)2CHCCI, pyridine 14. Brą, H20 CHO HOEH H HOH НЕОН HO+H CH OH 15. H2N. ***** оо CO2 1) (CH3),COCOCOC(CH3)3 2) -N: C: NH- 16. CHO нон PhNHNH2 H+OH (3 equiv.)...
find the major product оо HN .CO2 1) (CH3)3COCOCOC(CH3)3 Ph 2) -N=C: NH- + CHO HO FH PhNHNH2 H+OH (3 equiv.) H-OH HO+H CH2OH
15. HN оо CO; 1) (CH3)3COCOCOC(CH3)3 2) -N:CENH CHO HOTH PhNHNH | 16. HOH (3 equiv.) HO+H н+он CH OH 17. Use ANY needed reagents to effect the following transformation. (30 points) starting material product
15. HN оо CO; 1) (CH3)3COCOCOC(CH3)3 2) -N:CENH CHO HOTH PhNHNH | 16. HOH (3 equiv.) HO+H н+он CH OH 17. Use ANY needed reagents to effect the following transformation. (30 points) starting material product
CHO HO+H PhNHNH2 H OH (3 equiv.) H-OH HO+H CH2OH
оо 15. H2NCO, 1) (CH3),coĈOCOC(CH3)3 2 a NEC:NHO 16. CHO HOTH PhΝΗΝΗΣ HOH (3 equiv.) HO EH HOH ♡ CH2OH 17. Use ANY needed reagents to effect the following transformation. (30 points) starting material product Izred oss motor bada et 0-0.00 WEDDI entwooed monterige grated som sports stebri bris plans volonterosso
оо 15. H2NCO, 1) (CH3),coĈOCOC(CH3)3 2 a NEC:NHO 16. CHO HOTH PhΝΗΝΗΣ HOH (3 equiv.) HO EH HOH ♡ CH2OH 17. Use ANY needed reagents to effect the following transformation. (30 points) starting material product Izred oss motor bada et 0-0.00 WEDDI entwooed monterige grated som sports stebri bris plans volonterosso
оо 15. H2NCO, 1) (CH3),coĈOCOC(CH3)3 2 a NEC:NHO 16. CHO HOTH PhΝΗΝΗΣ HOH (3 equiv.) HO EH HOH ♡ CH2OH 17. Use ANY needed reagents to effect the following transformation. (30 points) starting material product Izred oss motor bada et 0-0.00 WEDDI entwooed monterige grated som sports stebri bris plans volonterosso
5. Convert the following Fischer projection to a pyranose). CHO HOH но-н H- H НЕОН CH2OH acyclic pyranose scaffold a-pyranose Haworth