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CHO HO+H PhNHNH2 H OH (3 equiv.) H-OH HO+H CH2OH Show transcribed image text
CHO HO EH PhNHNH | 16. нон (3 equiv.) НО H H -ОН CH2OH
HNO3 Н- CHO HOTH -ОН H-OH HO+H CH2OH
draw the major product 14. HNO, CHO Но+н H-HOH H-HOH HO+H CH2OH 15. oo HNcO; 1) (CH3),COCOCOC(CH3) 3 o N:C:NH/ Ph сно HOTH PHNHNH2 16. HOH (3 equiv.) H +OH HO+H CH2OH
PhNHNH | 16. CHO HO FH H+OH (3 equiv.) НОН HO FH CH2OH 17. Use ANY needed reagents to effect the following transformation. (30 points) ÇO2Et O ON starting material product
find the major product оо HN .CO2 1) (CH3)3COCOCOC(CH3)3 Ph 2) -N=C: NH- + CHO HO FH PhNHNH2 H+OH (3 equiv.) H-OH HO+H CH2OH
оо 15. H2N CO2 1) (CH3)3COCOCOC(CH3)3 아 2) -N:CENA CHO HO+H PhNHNH | 16. H -OH (3 equiv.) HO -H H- CH2OH -OH
ot the following reactions. ea CHO H OH H- OH OH OH CH2OH CHO OH H- OH OH H OH CH2OH Banic product in each of the following reactions. Benedict's NADH
CHO 1. NH2OH 2. Ac2o 3. CH,O CHO OH H- HO H HO H HCN H OH OH H- OH H- -OH H- CH2OH CH2OH The Wohl degradation is a series of reactions that shorten an aldose chain by one carbon, it is almost the exact opposite of the Kiliani In this reaction the aldose aldehyde carbonyl group is converted into a nitrile. The resulting cyanohydrin loses HCN under basic cone Conversion of the aldehyde to a nitrile is accomplished...
complete the reactions Br2, H2O CHO HO EH H-OH H-OH НО- CH2OH T ЕН O CNH2 1) Brą, NaOH, H20 O 2) (CH3)2CHCCI, pyridine
9. Given the reaction condition, what is the product outcome, A-D? CHO CHO CHO CHO HO H H OH Н. -OH 1. HCN, NaCN H OH H OH H OH H OH 2. Hy/Lindlar cat. 3. HO CH2OH H OH H OH CH2OH CH2OH CH2OH (III) (II) A). (1) only B. (11) only C. (III) only D. both (11) and (III) 9. Given the reaction condition, write the structure of the final product. CHO H OH 1. Br2 H -OH...