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9. Given the reaction condition, what is the product outcome, A-D? CHO CHO CHO CHO HO...
What is the outcome of the following reaction? 24) What is the outcome of the following reaction? HO Ag(NH)20H HO .OH O...
What is the outcome of the following reaction?
24) What is the outcome of the following reaction? HO Ag(NH)20H HO .OH OH OH t f C) A) No Reaction OH H- 1 B) CHO OH H- H- OH -OH H- OH H- H- - OH CH2OH D) -OH H- biac CO H OH H OH CH2OH H OH -OH H- -OH H- cop onta is true?
24) What is the outcome of the following reaction? HO Ag(NH)20H HO .OH OH...
CHO 1. NH2OH 2. Ac2o 3. CH,O CHO OH H- HO H HO H HCN H...
CHO 1. NH2OH 2. Ac2o 3. CH,O CHO OH H- HO H HO H HCN H OH OH H- OH H- -OH H- CH2OH CH2OH The Wohl degradation is a series of reactions that shorten an aldose chain by one carbon, it is almost the exact opposite of the Kiliani In this reaction the aldose aldehyde carbonyl group is converted into a nitrile. The resulting cyanohydrin loses HCN under basic cone Conversion of the aldehyde to a nitrile is accomplished...
The principal product of this reaction is: I, II, III or IV? CHO НО- -Н I...
The principal product of this reaction is: I, II, III or
IV?
CHO НО- -Н I -ОН 1. NaBH4 H -ОН 2. H,0* НО- -Н CH2OH СОН ÇOCH СН,ОН ÇO2H -Н НО. НО- -Н НО- -Н НО- -Н Н- -ОН H -ОН Н. -ОН -ОН H— Н- -ОН -ОН H Н- -ОН -ОН H— НО -Н НО- -Н НО- -Н НО- -Н CH OH CH,OH СОН СОН III IV -
What is the product of the following sequence of reactions? CHO NaCN H3O*, heat HCI OH...
What is the product of the following sequence of reactions? CHO NaCN H3O*, heat HCI OH | OH portion pour O A) I OB) 11 OC) III OD IV What is the product of the reaction shown below? CH,CH-C-H HCN OCN A) CH3CH2CH2CN B) CH3CH2CHC=NH OH C) CH3CHCH D) CH3CH2CHOH CN ОА) в ОВ) с OCD O DA
9. Match each reaction to its single most likely major product or outcome in the box....
9. Match each reaction to its single most likely major product or outcome in the box. Place the Roman numeral of your choice on the line by the reaction. No answer may be used more than once. (10 points) он CH3OH H2SO4 cat toon a.) i. Lana ii. H -NH2 HỌ R b.) iii. HO iv. H NaOCH CH3OH to c.) V. OH vi. 1. LiAlH4, ether 2. H300 d.) -NH2 vii. HO NH2 viii.
draw the major product 14. HNO, CHO Но+н H-HOH H-HOH HO+H CH2OH 15. oo HNcO; 1)...
draw the major product
14. HNO, CHO Но+н H-HOH H-HOH HO+H CH2OH 15. oo HNcO; 1) (CH3),COCOCOC(CH3) 3 o N:C:NH/ Ph сно HOTH PHNHNH2 16. HOH (3 equiv.) H +OH HO+H CH2OH
Que. 9) What is the major organic product obtained from the following reaction? H2SO4 o OH...
Que. 9) What is the major organic product obtained from the following reaction? H2SO4 o OH OH OH c. 3 d. 4 Que. 10) What is the relationship between D-erythrose and D-threose? CHO CHO HOH HOH H OH OH CHOH CH,OH D-Erythrose D-Threose a. constitutional isomers b. enantiomers c. diastereomers d. tautomers Que. 11) What is the relationship between D-ribose and D-xylose? CHO CHO І н он н -он нон нон н -он н -он І І CH OH Сн,он...
T. How many stereoisomers of beta-D-glucopyranose exist (including itself)? a. 4 e. too many to consider...
T. How many stereoisomers of beta-D-glucopyranose exist (including itself)? a. 4 e. too many to consider b. 8 с. 16 d. 32 onsider the following Fischer projections and answer the questions: CHO H OH HO H H OH H O ČH2OH glucose CHO CHO H OH Но- СНО н H- OH HO OH HO -н -н H- OH H HO -H HO н- H OH ČH2OH H OH CH2OH OH CH OH allose galactose talose 2. Which pair are not...
11.10_1 What is a major product of the following reaction? NaOH, HO 2 ~ CHO ?...
11.10_1 What is a major product of the following reaction? NaOH, HO 2 ~ CHO ? heat CHO CHO A) B) CHO D) CHO C) СА B oc 11.105 Which of the following is the best way to synthesize the compound in the box in high yield? A) Phyp NaOH B) mily Н,0 PPhg C) NaOH ox + D) H2O 11.10_4 In the presence of a base which of the following compounds WILL NOT undergo self- condensation to give an...
19. What is the major product of the following reaction? 1 R2BH 2 HO H202 H2O...
19. What is the major product of the following reaction? 1 R2BH 2 HO H202 H2O -CH=CH DH I. CH3IV H ÇH2 H OH OH A) I B) II C) III D) IV E) V PART B. Please draw the structure of product of the following reaction. 20. Draw the major product of the following reaction: CH:CHs HCl H:C CH: 21. Draw the major product of the following reaction: 22. Draw the major product of the following reaction
What is the outcome of the following reaction?
24) What is the outcome of the following reaction? HO Ag(NH)20H HO .OH OH OH t f C) A) No Reaction OH H- 1 B) CHO OH H- H- OH -OH H- OH H- H- - OH CH2OH D) -OH H- biac CO H OH H OH CH2OH H OH -OH H- -OH H- cop onta is true?
24) What is the outcome of the following reaction? HO Ag(NH)20H HO .OH OH...
CHO 1. NH2OH 2. Ac2o 3. CH,O CHO OH H- HO H HO H HCN H OH OH H- OH H- -OH H- CH2OH CH2OH The Wohl degradation is a series of reactions that shorten an aldose chain by one carbon, it is almost the exact opposite of the Kiliani In this reaction the aldose aldehyde carbonyl group is converted into a nitrile. The resulting cyanohydrin loses HCN under basic cone Conversion of the aldehyde to a nitrile is accomplished...
The principal product of this reaction is: I, II, III or
IV?
CHO НО- -Н I -ОН 1. NaBH4 H -ОН 2. H,0* НО- -Н CH2OH СОН ÇOCH СН,ОН ÇO2H -Н НО. НО- -Н НО- -Н НО- -Н Н- -ОН H -ОН Н. -ОН -ОН H— Н- -ОН -ОН H Н- -ОН -ОН H— НО -Н НО- -Н НО- -Н НО- -Н CH OH CH,OH СОН СОН III IV -
What is the product of the following sequence of reactions? CHO NaCN H3O*, heat HCI OH | OH portion pour O A) I OB) 11 OC) III OD IV What is the product of the reaction shown below? CH,CH-C-H HCN OCN A) CH3CH2CH2CN B) CH3CH2CHC=NH OH C) CH3CHCH D) CH3CH2CHOH CN ОА) в ОВ) с OCD O DA
9. Match each reaction to its single most likely major product or outcome in the box. Place the Roman numeral of your choice on the line by the reaction. No answer may be used more than once. (10 points) он CH3OH H2SO4 cat toon a.) i. Lana ii. H -NH2 HỌ R b.) iii. HO iv. H NaOCH CH3OH to c.) V. OH vi. 1. LiAlH4, ether 2. H300 d.) -NH2 vii. HO NH2 viii.
draw the major product
14. HNO, CHO Но+н H-HOH H-HOH HO+H CH2OH 15. oo HNcO; 1) (CH3),COCOCOC(CH3) 3 o N:C:NH/ Ph сно HOTH PHNHNH2 16. HOH (3 equiv.) H +OH HO+H CH2OH
Que. 9) What is the major organic product obtained from the following reaction? H2SO4 o OH OH OH c. 3 d. 4 Que. 10) What is the relationship between D-erythrose and D-threose? CHO CHO HOH HOH H OH OH CHOH CH,OH D-Erythrose D-Threose a. constitutional isomers b. enantiomers c. diastereomers d. tautomers Que. 11) What is the relationship between D-ribose and D-xylose? CHO CHO І н он н -он нон нон н -он н -он І І CH OH Сн,он...
T. How many stereoisomers of beta-D-glucopyranose exist (including itself)? a. 4 e. too many to consider b. 8 с. 16 d. 32 onsider the following Fischer projections and answer the questions: CHO H OH HO H H OH H O ČH2OH glucose CHO CHO H OH Но- СНО н H- OH HO OH HO -н -н H- OH H HO -H HO н- H OH ČH2OH H OH CH2OH OH CH OH allose galactose talose 2. Which pair are not...
11.10_1 What is a major product of the following reaction? NaOH, HO 2 ~ CHO ? heat CHO CHO A) B) CHO D) CHO C) СА B oc 11.105 Which of the following is the best way to synthesize the compound in the box in high yield? A) Phyp NaOH B) mily Н,0 PPhg C) NaOH ox + D) H2O 11.10_4 In the presence of a base which of the following compounds WILL NOT undergo self- condensation to give an...
19. What is the major product of the following reaction? 1 R2BH 2 HO H202 H2O -CH=CH DH I. CH3IV H ÇH2 H OH OH A) I B) II C) III D) IV E) V PART B. Please draw the structure of product of the following reaction. 20. Draw the major product of the following reaction: CH:CHs HCl H:C CH: 21. Draw the major product of the following reaction: 22. Draw the major product of the following reaction
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