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The rate constant at 298K for the decomposition reaction CH3 + 2C,H, is 6.6 % 103151...
The activation energy for the gas phase decomposition of t-butyl chloride is 173 kJ/mol. (CH3)3CCl---->(CH3)2C=CH2 + HCl The rate constant for this reaction is 7.30×10-5 s-1 at 546 K. What is the rate constant at 589 K? ___s-1
The activation energy for the gas phase decomposition of t-butyl chloride is 173 kJ/mol. (CH3)3CCl--->(CH3)2C=CH2 + HCl The rate constant for this reaction is 5.58×10-4 s-1 at 577 K. What is the rate constant at 623 K? ___s-1
The activation energy for the gas phase decomposition of t-butyl acetate is 170 kJ. CH3COOC(CH3)3—(CH3)2C=CH2 + CH3COOH The rate constant at 540 K is 7.54x10-4 /s. The rate constant will be Is at 583 K.
#14 Rate Constant and Temperature 1. The rate constant (k) for a reaction was measured as a function of temperature. A plot of lnk versus 1/T (in K) is linear and has a slope of -1.01 x 104 K. Calculate the activation energy for this reaction. 2. The rate constant of a reaction at 32.0oC is 0.0550 s-1. If the frequency factor is 1.20 x 1013 s-1, what is the activation energy? 3. A reaction has a rate constant of...
5. The reaction CH+2C,H, is first order with rate constant k = 1.89 x 10251. a. Suppose that (C.Hs]o = 0.265 M. How long (in seconds) will it take for the concentration of C.Hg to decrease to 45.0% of its initial value? (8 points) b. What is the concentration of the product CzH4 after 1.75 seconds of reaction? (8 points)
For the gas phase decomposition of t-butyl acetate, CH3COOC(CH3)3—>(CH3)2C=CH2 + CH3COOH the rate constant in s has been determined at several temperatures. When In k is plotted against the reciprocal of the Kelvin temperature, the resulting linear plot has a slope of -2.04x104 K and a y-intercept of 30.7. The value of the rate constant for the gas phase decomposition of t-butyl acetate at 533 K is (Enter your answer to one significant figure.)
The reaction A- + H+ → P has a rate constant given by the empirical expression kr = (6 x 1012) exp((- 5925 K)/T). Evaluate the energy and entropy of activation at 25°C°. [8 marks]
Another study of the decomposition of ClO determined the rate constant vs. temperature resulting in the following data: T (K) K (M-1s-1) 238 1.9 x 109 258 3.1 x 109 278 4.9 x 109 298 7.2 x 109 Use an Arrhenius plot to determine the activation energy (Ea) and the frequency factor (A). Show all work
Part A: The rate constant for a certain reaction is k = 1.90×10−3 s−1 . If the initial reactant concentration was 0.150 M, what will the concentration be after 7.00 minutes? Part B: A zero-order reaction has a constant rate of 4.60×10−4 M/s. If after 30.0 seconds the concentration has dropped to 8.00×10−2 M, what was the initial concentration? Part C: A certain reaction has an activation energy of 60.0 kJ/mol and a frequency factor of A1 = 7.80×1012 M−1s−1...
There are several factors that affect the rate of a reaction. These factors include temperature, activation energy, steric factors (orientation), and also collision frequency, which changes with concentration and phase. All the factors that affect reaction rate can be summarized in an equation called the Arrhenius equation: k=Ae−Ea/RT, where k is the rate constant, A is the frequency factor, Ea is the activation energy, R=8.314 J mol−1 K−1 is the gas constant, and T is the absolute temperature. A certain...