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outline labratory syntheses of each of the following compounds starting with benzene and any other reagents...
Question 31 with all the transformations VSNa 938 CHAPTER 20 AMINES g with benzene or toluene, outline a sy nthesis of each of the following compounds using diazonium salts as intermediates. (You need not repeat syntheses carried out in earlier parts of this problem.) (o) CH3 (I) 1,3-Dibromo-2-iodobenzene a) p-Fluorotoluene он o-lodotoluene (c) p-Cresol (d) m-Dichlorobenzene (e) m-CeH4(CN)2 (f) m-Bromobenzonitrile (g) 1,3-Dibromo-5-nitrobenzene (h) 3,5-Dibromoaniline CH3 CN CH3 (n) CH3 4.5-Tribromophenol ) 3,4.5-Tribromobenzonitrile (k) 2,6-Dibromobenzoic acid 20.32 Write equations for simple...
Propose syntheses of the following molecules, starting from benzene, toluene or phenol, any inorganic reagents and any organic reagent of TWO carbons or less: 4. Propose syntheses of the following molecules, starting from benzene, toluene or phenol, any inorganic reagents and any organi c reagent of TWO carbons or le a) NO2 b) CO2H c) OH d) e) NO2 NO2 Br CI CI CO2H Br
Outline a feasible laboratory synthesis of m-bromoethylbenzene, starting with benzene, using any available reagents, compounds, etc.
13. (20 points) Outline syntheses for each of the following compounds starting from ethyl acetoacetate and any other reagents as needed:
3 e f g 3. Suggest efficient syntheses for the following compounds, starting from the compound indicated and any other needed reagents. (98 pts) e) benzonitrile (C HsCEN) starting from benzene. (f) octanoic acid, from 1-hexanol. (g) phenol, from aniline (CsHsNH:).
13. (20 points) Outline syntheses for each of the following compounds starting from ethyl acetoacetate and any other reagents as needed: 0 0 A DEL
Outline all steps in the laboratory synthesis of the following compounds from benzene and/or toluene, using any needed aliphatic or inorganic reagents. Assume the para isomer can be separated from an ortho,para mixture. Do not show mechanisms. p-bromobenzoic acid m-bromobenzoic acid 2-bromo-4-nitrotoluene 2-bromo-4-nitrobenzoic acid 4-bromo-3-nitrobenzoic acid o-iodobenzoic acid
14. Starting with an appropriate alkyl halide and using any other needed reagents, outline the syntheses of each of the following. When alternative possibilities exist for a synthesis, you should choose the one that gives the better product. Indicate whether each reaction follows an SN1 or SN2 reaction mechanism. 14. Starting with an appropriate alkyl halide and using any other needed reagents, outline the syntheses of each of the following. When alternative possibilities exist for a synthesis, you should choose...
Starting with benzene or toluene, outline a synthesis of each of the following compounds using diazonium salts as intermediates a) 3,4,5-Tribromobenzonitrile b) 2,6-Dibromobenzoic acid
Propose syntheses of each of the following compounds, from the given starting material and any other needed reagents. » O- CH2OH from O con b) CH3CCHz from CH3CH=CH2 ОН • OCHGHs from O-Br