1. A voltaic cell is constructed based on the following redox reaction: Sn2+ (aq) + Mn (s)àSn (s) + Mn2+ (aq)
Calculate Ecell at 25 oC under the following conditions:
(a) Standard conditions
(b) [Sn2+] = 0.0200 M; [Mn2+] = 4.00 M
(c) [Sn2+] = 0.500 M; [Mn2+] = 0.00250 M
2. Consider the following redox reaction at 25oC: MnO2 (s)àMn2+ (aq) + MnO4- (aq)
(a) Balance the equation in acid
(b) Calculate Eocell
(c) CalculateDGorxn
(d) Calculate K
Hint!!! After balancing your half-reactions, determine which reaction is oxidation and which reaction is the reduction and use Eocell = Ecath (red) – Eanode (ox)
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