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Chem. 2425 Test 1 Summer II 2020 Name: 11. Consider the Grignard reaction below to answer...
can you double check these answers? 11. Consider the Grignard reaction below to answer the following...
can you double check these answers?
11. Consider the Grignard reaction below to answer the following question(s). HO muchopnice electronice 3.CH Mg ch нс CH, 2 Hot : A the alcohol product can be classified as a .3 alcanot The nucleophile in this reaction is: 1' alcohol 2' alcohol 3' alcohol 4 alcohol 12. To answer the following question(s), consider the reaction below: OH POCH Pyridine CH CH3 Draw arrows which account for the complete stepwise mechanism for this reaction....
1. What will be the products (A-D) in the following aldehyde and ketone reactions ? Hoon...
1. What will be the products (A-D) in the following aldehyde and ketone reactions ? Hoon 1) SOCI 2) (CH3)2NH A FO сндон, H30* OH B CH H₃C. OH H3C Pyridine H3C CH, с مل CH3NH2, A D 2. Provide IUPAC names for the following compounds (E-G). Name: нас. сн, сн. E Name: H3C CH3 CH3 F Name: HO OH CH3 G 3. Provide a mechanism for the following reactions a) OCH3 CH3NH2, 4 NHCH3 b) FO 1) SOCI 2)...
Draw an arrow pushing mechanism and find the theoretical yield for the Grignard reaction below using...
Draw an arrow pushing mechanism and find the theoretical yield
for the Grignard reaction below using the following amounts of
reagent with the given molecular weights:
565 microliters of 2-bromopropane (molecular weight =
123g/mol)
304 microliters of 4-methoxybenzaldehyde (molecular weight =
136.15g/mol)
molecular weight of product = 180.27g/mol
The
limiting reagent is _____________.
In this experiment, you will prepare the Grignard reagent isopropyl-magnesium bromide from 2-bromopropane. You will allow this Grignard reagent to react with 4-methoxy-benzaldehyde to form a secondary...
Chem 2010 Substitution Problem Set Name 1. Choose the appropriate answer for each of the following...
Chem 2010 Substitution Problem Set Name 1. Choose the appropriate answer for each of the following (circle your answer): the strongest base: i c F the strongest acid: CHOH H20 NH3 the worst nucleophile in protic, polar solvents: 1 F the slowest in an SN2 reaction: (CH3)2CHCH2Br CHI CH3CH2CH2Br the best solvent for an Snl reaction: acetone water pentane the worst nucleophile: OH "Сн, NH the strongest base NH H20 F the best nucleophile: OH CH3 NH the best solvent...
1. The synthesis of Grignard reagent is challenging. a) Draw the product that is expected to...
1. The synthesis of Grignard reagent is challenging. a) Draw the product that is expected to be formed if the Grignard reagent was in contact with water prior to the reaction with MgBr CO2? (2 pts) b) Circle the correct answer. In the reaction in 1 a), phenyl magnesium bromide acts as a (nucleophile/electrophile/base/acid). (1 pt) Consider the following reaction and circle the correct answer. In this reaction, phenyl magnesium bromide acts as a, Oo MgBr MgBr (nucleophile/electrophile/base/acid). (1 pt)...
please help!! thank you! Which of the following compounds is most reactive towards nucleophilic addition reaction?...
please help!! thank you!
Which of the following compounds is most reactive towards nucleophilic addition reaction? H1 H H A B С D E Predict the product for the following reaction sequence. iii PBrz Mg/ether Н H Cr04 ОН 2. Hz0+ A. 6,7-dimethyl-3-nonanol B. 6,7-dimethyl-3-nonanone C. 6,7-dimethyl-3-nonanal D. 3,4-dimethyl-7-nonanol E. 3,4-dimethyl-7-nonanone Predict the product for the following reaction 1. LiAlH4 (excess) 2. H30* OH OH OH -Н HO B с D Provide the structure of the ylide needed to prepare...
59. Provide the major organic product in the reaction shown below. 1. NH4 2. KOH, heat...
59. Provide the major organic product in the reaction shown below. 1. NH4 2. KOH, heat 0 3. H20 60. O= 1. NH2NH2 H₃C 0 CH2 CH3 2. "OH, heat ii. What is the reactant W in the synthesis given below? a) Cyclopentanone b) Cyclopentene c) Cyclopentanol d) Bromocyclopentane e) Triphenylphosphine oxide What is the final product of this synthetic sequence? | Br2 Mg 1. C,H,CHO H Cr,04 Benzene FeCl, ether 2. H,0 acetone d) e) CHECCHS p-BrC.H.CH.C.HSCH:CHCOOH CA HECH,...
Organic Chemistry II Draw the mechanisms for the following reactions. O CH CH2ONa 1. CHsCH CHCH3)MgBr...
Organic Chemistry II
Draw the mechanisms for the following reactions. O CH CH2ONa 1. CHsCH CHCH3)MgBr HCI Et2O 2. НО. CH3CH2OH a. b. C. Draw structural formulas for the alkoxide ion and the alkyl(aryl)bromide that may be used in a Williamson synthesis of the ether shown. o-CH3 Draw structural formulas for an aldehyde or ketone and alkyl (or aryl) bromide that could be used in a Grignard synthesis of the alcohol shown. он CH3CHCHCH2CH3 0% CH3
Did I do this correctly? 21. Name and draw the product of the following reaction: H...
Did I do this correctly?
21. Name and draw the product of the following reaction: H NO2 O Tupac Name: 1- (2.4 -Dinitroprenyl)- isopropyli denenud razia ch3 NO2 + HEN H3C "CH3 .C NO2 "N-N CH3 "NO2 Acetone 2,4-Dinitrophenyl- hydrazine Acetone 2,4- Ginitropnery) hydrazine 22. Draw the product of the following reaction: Connor name CH3 CHE CH3C=CHCCHE H2NNH2 CH3-ċ=CH-CH₂-CH3 KOH at CH3 23. Draw the product of the following reaction: 1. CH_MBt, ether 2.H30* 24. What is the order of...
4) " The reaction of a Grignard reagent with a solvent ench as water or an...
4) " The reaction of a Grignard reagent with a solvent ench as water or an alcohol produces which of the following? A) tertiary alcohol B) alkane C) primary alcohol D) secondary alcohol 5) 5) The reaction of phenylmagnesium bromide (C6H5MgBr) with propanal (CH3CH2CH=0), followed by hydrolysis yields. Draw the structure of the product. A) 1-phenyl-1-propanol. B) 3-phenyl-1-propanol. C) 2-phenyl-2-propanol. D) 2-phenyl-1-propanol. 6) What is the product of the following reaction? (2) H30+ OH CA CA D C BD S...
can you double check these answers?
11. Consider the Grignard reaction below to answer the following question(s). HO muchopnice electronice 3.CH Mg ch нс CH, 2 Hot : A the alcohol product can be classified as a .3 alcanot The nucleophile in this reaction is: 1' alcohol 2' alcohol 3' alcohol 4 alcohol 12. To answer the following question(s), consider the reaction below: OH POCH Pyridine CH CH3 Draw arrows which account for the complete stepwise mechanism for this reaction....
1. What will be the products (A-D) in the following aldehyde and ketone reactions ? Hoon 1) SOCI 2) (CH3)2NH A FO сндон, H30* OH B CH H₃C. OH H3C Pyridine H3C CH, с مل CH3NH2, A D 2. Provide IUPAC names for the following compounds (E-G). Name: нас. сн, сн. E Name: H3C CH3 CH3 F Name: HO OH CH3 G 3. Provide a mechanism for the following reactions a) OCH3 CH3NH2, 4 NHCH3 b) FO 1) SOCI 2)...
Draw an arrow pushing mechanism and find the theoretical yield
for the Grignard reaction below using the following amounts of
reagent with the given molecular weights:
565 microliters of 2-bromopropane (molecular weight =
123g/mol)
304 microliters of 4-methoxybenzaldehyde (molecular weight =
136.15g/mol)
molecular weight of product = 180.27g/mol
The
limiting reagent is _____________.
In this experiment, you will prepare the Grignard reagent isopropyl-magnesium bromide from 2-bromopropane. You will allow this Grignard reagent to react with 4-methoxy-benzaldehyde to form a secondary...
Chem 2010 Substitution Problem Set Name 1. Choose the appropriate answer for each of the following (circle your answer): the strongest base: i c F the strongest acid: CHOH H20 NH3 the worst nucleophile in protic, polar solvents: 1 F the slowest in an SN2 reaction: (CH3)2CHCH2Br CHI CH3CH2CH2Br the best solvent for an Snl reaction: acetone water pentane the worst nucleophile: OH "Сн, NH the strongest base NH H20 F the best nucleophile: OH CH3 NH the best solvent...
1. The synthesis of Grignard reagent is challenging. a) Draw the product that is expected to be formed if the Grignard reagent was in contact with water prior to the reaction with MgBr CO2? (2 pts) b) Circle the correct answer. In the reaction in 1 a), phenyl magnesium bromide acts as a (nucleophile/electrophile/base/acid). (1 pt) Consider the following reaction and circle the correct answer. In this reaction, phenyl magnesium bromide acts as a, Oo MgBr MgBr (nucleophile/electrophile/base/acid). (1 pt)...
please help!! thank you!
Which of the following compounds is most reactive towards nucleophilic addition reaction? H1 H H A B С D E Predict the product for the following reaction sequence. iii PBrz Mg/ether Н H Cr04 ОН 2. Hz0+ A. 6,7-dimethyl-3-nonanol B. 6,7-dimethyl-3-nonanone C. 6,7-dimethyl-3-nonanal D. 3,4-dimethyl-7-nonanol E. 3,4-dimethyl-7-nonanone Predict the product for the following reaction 1. LiAlH4 (excess) 2. H30* OH OH OH -Н HO B с D Provide the structure of the ylide needed to prepare...
59. Provide the major organic product in the reaction shown below. 1. NH4 2. KOH, heat 0 3. H20 60. O= 1. NH2NH2 H₃C 0 CH2 CH3 2. "OH, heat ii. What is the reactant W in the synthesis given below? a) Cyclopentanone b) Cyclopentene c) Cyclopentanol d) Bromocyclopentane e) Triphenylphosphine oxide What is the final product of this synthetic sequence? | Br2 Mg 1. C,H,CHO H Cr,04 Benzene FeCl, ether 2. H,0 acetone d) e) CHECCHS p-BrC.H.CH.C.HSCH:CHCOOH CA HECH,...
Organic Chemistry II
Draw the mechanisms for the following reactions. O CH CH2ONa 1. CHsCH CHCH3)MgBr HCI Et2O 2. НО. CH3CH2OH a. b. C. Draw structural formulas for the alkoxide ion and the alkyl(aryl)bromide that may be used in a Williamson synthesis of the ether shown. o-CH3 Draw structural formulas for an aldehyde or ketone and alkyl (or aryl) bromide that could be used in a Grignard synthesis of the alcohol shown. он CH3CHCHCH2CH3 0% CH3
Did I do this correctly?
21. Name and draw the product of the following reaction: H NO2 O Tupac Name: 1- (2.4 -Dinitroprenyl)- isopropyli denenud razia ch3 NO2 + HEN H3C "CH3 .C NO2 "N-N CH3 "NO2 Acetone 2,4-Dinitrophenyl- hydrazine Acetone 2,4- Ginitropnery) hydrazine 22. Draw the product of the following reaction: Connor name CH3 CHE CH3C=CHCCHE H2NNH2 CH3-ċ=CH-CH₂-CH3 KOH at CH3 23. Draw the product of the following reaction: 1. CH_MBt, ether 2.H30* 24. What is the order of...
4) " The reaction of a Grignard reagent with a solvent ench as water or an alcohol produces which of the following? A) tertiary alcohol B) alkane C) primary alcohol D) secondary alcohol 5) 5) The reaction of phenylmagnesium bromide (C6H5MgBr) with propanal (CH3CH2CH=0), followed by hydrolysis yields. Draw the structure of the product. A) 1-phenyl-1-propanol. B) 3-phenyl-1-propanol. C) 2-phenyl-2-propanol. D) 2-phenyl-1-propanol. 6) What is the product of the following reaction? (2) H30+ OH CA CA D C BD S...
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