Provide the structure of the major product for the fillowing
reactions. Assume enough reagent to react with all functional
groups capable of reaction
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Provide the structure of the major product for the fillowing reactions. Assume enough reagent to react...
Provide the structure of the major product for the fillowing reactions. Assume enough reagent to react with all functional groups capable of reaction 0 0 OH h) NH H2SO4 i) CN H20, 4 Q.culi j) ci & Br Br ~0,-780 SOCI, k) Br NH CN N jpg
Provide the structure of the major product for the fillowing reactions. Assume enough reagent to react with all functional groups capable of reaction NH a) hori H NaBH3CN 1) th MgBr b) CN 2) H2O HO t C1 NH2
Two pages 30 1) Provide the structure of the major product for ten of the following fifteen reactions. Assume enough reagent to react with all functional groups capable of reaction. NH NaBH,CN 1) MEB 2)H,0 HO NH NaN, 1) NaNO,, H.SO. NH, 2) HBF. KOH 1) odo H30 opas 1) LiAIH, 2) H.O OH h) NH H,SO H.0, A CN 1 cui Oculi O .-780 Br SOCI, NH 1) CHI (xs) 2) Ag,0,H,O, tion N'HSO, H20 Cu_0 Br corond me...
36. Select the final product for the multi-step sequence indicated below: ECI NaNO, pyr. AICI KOH HCI HBF NH, ACCI ? BF no 0 HO OH 37. What reagents are needed for the transformation required?: OME A. NH3, KOH / NaN 0, HCI / aniline. NaoMe B. HNO,, H2SO4 / HCI. Sn/NaNO2, HCI / anisole C. HNO3, H,80 / KOH, H,SO / NaNO2, HCl/phenol, Mel D, 4-methoxyanline, NH A CI
Draw the structure of the major organic product/s for each of the following reactions. Indicate the stereochemistry for each reaction, when appropriate. If multiple functional groups in the molecule react under the conditions, you may assume that enough reagents (excess) are added to react with all the possible functional groups. If enantiomers are generated, you may draw one and indicate “+enantiomer”. LOH 1.Na º 2.CH31 3.CO, HCI, AICIZ/ Cuci
VI. Reactions (21 pts) Provide the major product in the following reaction. It as the product Show your work for each stepll Pay attentio Stereochemistry! Product in the following reaction. If no reaction occurs, write" NR stepll pay attention to Regiochemistry and TSCI ElyN 1. CHy-Br (xs) 2 A0,0,H,O, A H-CI E-G NaBH,CN a. NaNs, EtOH b. H20, он 1. SOCI, pyridine 2. NaN, DMF 3. LIAIH, EL 0
D 1) SOCI2. py OH 2) NaCN What is the major product of the above reaction sequence? IN CN CI CI CN NH2 1) CHI (xs) 2) Ag20 3) A What is the major product of the reaction? NH2 ON + NaOH NOZ What is the major product of the above reaction? ON OH NOZ ON OH NO2 OH ON NO2 No reaction Et CH OH H20* What is the major product of the above reaction sequence? OME -Et OH...
VI. Reactions (21 pts) Provide the major product in the following reaction. If no reaction occurs, write "NR as the product. Show your work for each step!! Pay attention to Regiochemistry and Stereochemistry! TSCI EtyN 1. CHg-Br (xs) 2. Ag20, H20, A H-CI Et20 Sold lo no? NaBH CN a. NaNg, EtOH b. H20,4 OH 1. SOCI, pyridine 2. NaN, DMF 3. LIAIH, Et20
1. PREDICT THE PRODUCT: Provide the structure of the major product expected from the following reactions or reaction sequences. Make sure you account for any regio- and/or stereochemistry! (24 pts.) H2O 1. Hg(OAC), CH, OH 2. NaBH H2SO4 H20 1) BH-THF 2) H202, KOH HBr Bry, H2O HBr ROOR 1. BH3-THF 2. H2O2, NaOH H20, H2SO4 1. NaNH2 H2 H-CEC-CH2 CH2 CH3 2. CH CH Br Lindlar cat 1. Sia BH-THF 2. H2O2, H2O
30 1) Provide the structure of the major product for ten of the following fifteen reactions. Only one regioisomer is necessary if two are equally probable. NO2 Sn a) HCI Br AIBr; b) Br c) ΗΝΟ, d) H2SO4 Br2 e) Fc 1) KMnO, A f) 2) H30+ Br2 g) O N-Br h) hy NH2 H2 (1 atm) CF3 Rh/C, 25°C NO2 12 j) CuCl2 Cl2 NH k) FeCl3