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5. Leucine is one of the 20 natural amino acids. At neutral pH, leucine mostly exists...
5. Leucine is one of the 20 natural amino acids. At neutral pH, leucine mostly exists...
5. Leucine is one of the 20 natural amino acids. At neutral pH, leucine mostly exists in the form of a zwitterion, HL. Given that leucine has a pK1=2.36 and pK2=9.60, answer the following questions. (5 points each) a. What is the pH of a 0.0252 M solution of sodium leucinate, Na L? b. What is the equilibrium concentration of H:L in this solution?
TABLE 5.1 PK values for amino acids 2.36 Amino acid Alanine Arginine Asparagine Aspartic acid Cysteine...
TABLE 5.1 PK values for amino acids 2.36 Amino acid Alanine Arginine Asparagine Aspartic acid Cysteine Glutamic acid Glutamine Glycine Histidine Isoleucine Leucine Lysine Methionine Phenylalanine Proline Serine Threonine Tryptophan Tyrosine Valine PK, PK₂ 2.34 9.69 2.17 9.04 2.02 8.80 1.88 9.60 1.96 10.28 2.19 9.67 2.17 9.13 2.34 9.60 1.82 9.17 9.60 9.60 2.18 8.95 2.28 1.83 9.13 1.99 10.60 2.219.15 2.09 9.10 2.83 9.39 2.20 9.11 2.32 9.62 2.36 9.21 5.56. Of the amino acids listed in Table...
Which of the following describes the pI of an amino acid? Select one: Oa. the pH...
Which of the following describes the pI of an amino acid? Select one: Oa. the pH at which the amino acid is primarily in the zwitterion form b. the pH at which there are equal concentrations of protonated and neutral forms c, the negative log of the concentration of the ionized amino acid d. the pH of the buffer solution used in electrophoresis that causes the amino acid to migrate to the positive electrode 0 O
A:What is the pH of a 0.0252 M solution of sodium leucinate, Na*L* B: What is...
A:What is the pH of a 0.0252 M solution of sodium leucinate, Na*L* B: What is the equilibrium concentration of H2L* in this solution?
Amino Acids SW C2 9. Which of the following is an L-amino acid? çoo coo coo...
Amino Acids SW C2 9. Which of the following is an L-amino acid? çoo coo coo HẠN |-R HANH, HẠN –H HÀNH R coo B. 10. The following questions refer to the structures A-E below: (a) Which represents the structure of an amino acid at very high pH? (b) Which is a zwitterion? (c) Which represents the structure of an amino acid at very low pH? (d) Which structure/(s) is/are) not possible? R-CH-COOR-CH-COOH R-CH-COOH R-CH-COOR -CH-COO NH2 NH2 *NH NH2...
Answer the following questions based upon a tripeptide sequence with the following amino acids: S L...
Answer the following questions based upon a tripeptide sequence with the following amino acids: S L D Serine Leucine Aspartate a) What is the overall charge of the most abundant tripeptide species at neutral pH (pH 7.0)? b) At physiological pH, what is the best desciption of the chemical properties of the side chain of each amino acid? options are: hydrophobic, polar uncharged, negativelly charged, and positively charged c) What is the overall charge of the most abundant tripeptide...
please help >< Polyprotic acids have more than one proton to donate to water, therefore have...
please help ><
Polyprotic acids have more than one proton to donate to water, therefore have more than one equilibrium constant for proton donation. For phosphoric acid, there is a three-step equilibrium: H, PO +H,0 5 H2PO4 + H30* H,PO," +H,0 5 HPO - +H30* HPO 2- +,0 5 PO.- +,0* Kai = 7.11 x 10-3 Ka2 = 6.32 x 10-8 Ka; = 4.5 x 10-13 For all conjugate acid base pairs: K, XKK where K is for the reaction...
20. Properties of a Buffer The amino acid glycine is often used as the main ingredient...
20. Properties of a Buffer The amino acid glycine is often used as the main ingredient of a buffer in biochemical experi- ments. The amino group of glycine, which has a pKa of 9.6, can exist either in the protonated form (-NH3 or as the free base (-NH2), because of the reversible equilibrium (a) In what pH range can glycine be used as an effective buffer due to its amino group? (b) In a 0.1 M solution of glycine at...
5. Suppose we discovered a form of life like our own which utilized 20 amino acids,...
5. Suppose we discovered a form of life like our own which utilized 20 amino acids, but had 6 nitrogeneous bases instead of the 4 our life uses. What would be the minimum length (i.e., number of base-pairs) of a codon which could represent all 20 currently used amino acids? 6. What evidence exists to support the idea that an ancestor of all present-day living organisms had a simpler genetic code in which the length of a codon was 2...
A buffer solution is able to maintain a constant pH when small amounts of acid or...
A buffer solution is able to maintain a constant pH when small amounts of acid or base are added to the buffer. Consider what happens when 1 mL of a 5 M solution is added or 0.005 mol of HCl are added to a 100.0 mL solution acetic acid buffer that contains 0.0100 mol of Acetic acid, HC,H,O,, and 0.0100 mol of sodium acetate, NaC,H,O,. The initial concentration of both the acid and the base are 0.0100 mol/ 0.1000 L...
5. Leucine is one of the 20 natural amino acids. At neutral pH, leucine mostly exists in the form of a zwitterion, HL. Given that leucine has a pK1=2.36 and pK2=9.60, answer the following questions. (5 points each) a. What is the pH of a 0.0252 M solution of sodium leucinate, Na L? b. What is the equilibrium concentration of H:L in this solution?
TABLE 5.1 PK values for amino acids 2.36 Amino acid Alanine Arginine Asparagine Aspartic acid Cysteine Glutamic acid Glutamine Glycine Histidine Isoleucine Leucine Lysine Methionine Phenylalanine Proline Serine Threonine Tryptophan Tyrosine Valine PK, PK₂ 2.34 9.69 2.17 9.04 2.02 8.80 1.88 9.60 1.96 10.28 2.19 9.67 2.17 9.13 2.34 9.60 1.82 9.17 9.60 9.60 2.18 8.95 2.28 1.83 9.13 1.99 10.60 2.219.15 2.09 9.10 2.83 9.39 2.20 9.11 2.32 9.62 2.36 9.21 5.56. Of the amino acids listed in Table...
Which of the following describes the pI of an amino acid? Select one: Oa. the pH at which the amino acid is primarily in the zwitterion form b. the pH at which there are equal concentrations of protonated and neutral forms c, the negative log of the concentration of the ionized amino acid d. the pH of the buffer solution used in electrophoresis that causes the amino acid to migrate to the positive electrode 0 O
Amino Acids SW C2 9. Which of the following is an L-amino acid? çoo coo coo HẠN |-R HANH, HẠN –H HÀNH R coo B. 10. The following questions refer to the structures A-E below: (a) Which represents the structure of an amino acid at very high pH? (b) Which is a zwitterion? (c) Which represents the structure of an amino acid at very low pH? (d) Which structure/(s) is/are) not possible? R-CH-COOR-CH-COOH R-CH-COOH R-CH-COOR -CH-COO NH2 NH2 *NH NH2...
please help ><
Polyprotic acids have more than one proton to donate to water, therefore have more than one equilibrium constant for proton donation. For phosphoric acid, there is a three-step equilibrium: H, PO +H,0 5 H2PO4 + H30* H,PO," +H,0 5 HPO - +H30* HPO 2- +,0 5 PO.- +,0* Kai = 7.11 x 10-3 Ka2 = 6.32 x 10-8 Ka; = 4.5 x 10-13 For all conjugate acid base pairs: K, XKK where K is for the reaction...
20. Properties of a Buffer The amino acid glycine is often used as the main ingredient of a buffer in biochemical experi- ments. The amino group of glycine, which has a pKa of 9.6, can exist either in the protonated form (-NH3 or as the free base (-NH2), because of the reversible equilibrium (a) In what pH range can glycine be used as an effective buffer due to its amino group? (b) In a 0.1 M solution of glycine at...
5. Suppose we discovered a form of life like our own which utilized 20 amino acids, but had 6 nitrogeneous bases instead of the 4 our life uses. What would be the minimum length (i.e., number of base-pairs) of a codon which could represent all 20 currently used amino acids? 6. What evidence exists to support the idea that an ancestor of all present-day living organisms had a simpler genetic code in which the length of a codon was 2...
A buffer solution is able to maintain a constant pH when small amounts of acid or base are added to the buffer. Consider what happens when 1 mL of a 5 M solution is added or 0.005 mol of HCl are added to a 100.0 mL solution acetic acid buffer that contains 0.0100 mol of Acetic acid, HC,H,O,, and 0.0100 mol of sodium acetate, NaC,H,O,. The initial concentration of both the acid and the base are 0.0100 mol/ 0.1000 L...
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