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Show in step-by-step detail the mechanism by which: either toluene is nitrated by nitric acid, HNO3,...
Please write the complete mechanism for the reaction to produce the di-nitrated product (dinitrobenzoate) in the...
Please write the complete mechanism for the reaction to produce the di-nitrated product (dinitrobenzoate) in the nitration of methyl benzoate with nitric acids and sulfuric acid. Draw each step of the mechanism on a separate line beginning on the left margin, and then explaining on the right how the reaction step occurs. Please be sure to use expanded structural formulas for all chemical species. Include all bonds, non-bonding electrons, formal charges, and electron-flow arrows. DO NOT use bond-line formulas, but...
The industrial production of nitric acid (HNO3) is a multistep process. The first step is the...
The industrial production of nitric acid (HNO3) is a multistep process. The first step is the oxidation of ammonia (NH3) over a catalyst with excess oxygen (O2) to produce nitrogen monoxide (NO) gas as shown by the unbalanced equation given here: ?NH3(g)+?O2(g)→?NO(g)+?H2O(g) Part A What volume of O2 at 684 mmHg and 41 ∘C is required to synthesize 19.0 mol of NO? Express your answer to three significant figures and include the appropriate units. volume of O^2=
7. The mononitration reaction of toluene is brought about by reaction with concentrated nitric acid in the presence...
7. The mononitration reaction of toluene is brought about by reaction with concentrated nitric acid in the presence of concentrated sulfuric acid yielding a mixture of ortho, meta and para isomers of nitrotoluene. Show the expected structures of this mononitration reaction performed on the following isomers of dimethylbenzene (or xylene). Be careful to show distinct products and not simply the same compound drawn in two different orientations. d d a. 1,2-dimethylbenzene SHD clumiol on 1 Winuonmo adiio aman lsge an...
1) The net ionic equation for the reaction between aqueous nitric acid and aqueous sodium hydroxide...
1) The net ionic equation for the reaction between aqueous nitric acid and aqueous sodium hydroxide is A) H+ (aq) + HNO3 (aq) + 2OH- (aq) → 2H20 (1) + NO3- (aq) B) HNO3 (aq) + NaOH(aq) → NaNO3(aq) + H20 (1) C) H+ (aq) + OH- (aq) + H2O (1) D) HNO3 (aq) + OH- (aq) + NO3- (aq) + H2O (1) E) H+ (aq) + Na+ (aq) + OH- (aq) → H20 (1) + Na+ (aq) 2) Which...
The first step in industrial nitric acid (HNO3) production is the catalyzed oxidation of ammonia (NH3)....
The first step in industrial nitric acid (HNO3) production is
the catalyzed oxidation of ammonia (NH3). Without the catalyst the
following reaction predominates:
4NH3(g) + 3O2(g) ⇔ 2N2(g) + 6H2O(g).
When 0.0150 mol each of NH3(g) and O2(g) are placed in a 1.00 L
container at a certain temperature the N2(g) concentration at
equilibrium is 1.96x10-3 M. Fill in the following ICE table and
calculate the resulting KC.
NH3(9) 02(9) N2(9) H20(9) Initial (1) 015 mol mol .015 Number Number...
Write a net ionic equation to show that nitric acid, HNO3, behaves as an acid in...
Write a net ionic equation to show that nitric acid, HNO3, behaves as an acid in water. + H2o(l) Submit Answer Retry Entire Group 5 more group attempts remaining Use the References to access important values if needed for this question. Acid Conjugate base H,S HS Acid Strength Increases Base Strength Increases HCiO CIO (1) Write a net ionic equation for the reaction between H2S and CIO that shows H2S behavin g as a Bronsted-Lowry acid BL acid BL base...
The industrial production of nitric acid (HNO3) is a multistep process. The first step is the oxidation of ammonia (NH...
The industrial production of nitric acid (HNO3) is a multistep process. The first step is the oxidation of ammonia (NH3 ) over a catalyst with excess oxygen (02) to produce nitrogen monoxide (NO) gas as shown by the unbalanced equation given here: ?NH, (g)+?O2(g) +?NO(g)+?H2O(g) Part A What volume of O2 at 684 mmHg and 39 °C is required to synthesize 19.0 mol of NO? Express your answer to three significant figures and include the appropriate units. View Available Hint(s)...
what is the purpose of the acid catalyst: sulfuric acid? why cant acetic acid, which is...
what is the purpose of the acid catalyst: sulfuric acid? why
cant acetic acid, which is already being used, serve in the same
capacity? show mechanism of the reaction
H+ R-C-OH + carboxylic acid (excess) R2-OH alcohol + HO Ric-o-R₂ an ester The general reaction scheme for a Fischer esterification is shown above. Using the combination of acetic acid and either isopentanol AND n-propanol you will synthesize two fruity-smelling esters. The hydronium source that will catalyze this reaction is sulfuric...
Reaction 1: Nitration HNO3 NO2 H2SO4, H20 NO2 toluene NO2 ortho meta para Procedure for Reaction...
Reaction 1: Nitration HNO3 NO2 H2SO4, H20 NO2 toluene NO2 ortho meta para Procedure for Reaction 1: 1) To a stirred solution of 3 mL (44.7 mmoles) 67 % HNO3 in 3.75 mL of water, H2SO4 (9 mL) was slowly added at 10-15 °C. 2) This nitrating solution was added dropwise with vigorous stirring to 4 mL (37.5 mmoles) of toluene while cooling in ice-water in order to maintain the reaction temperature between 15 and 25 °C. 3) Stirring was...
C. Indicate which is the late-detemning step. d. Is it the same mechanism as in question...
C. Indicate which is the late-detemning step. d. Is it the same mechanism as in question 1? Why or why not? 3. Explain why El and Sx1 mechanisms follow first order reaction kinetics, whereas E2 and SN2 mechanisms follow second order reaction kinetics. 4. Which is the better nucleophile in a protic solvent: chloride ion or bromide ion? Try to explain this in terms of the nature of the chloride ion and the bromide ion. 5. For the synthesis of...
7. The mononitration reaction of toluene is brought about by reaction with concentrated nitric acid in the presence of concentrated sulfuric acid yielding a mixture of ortho, meta and para isomers of nitrotoluene. Show the expected structures of this mononitration reaction performed on the following isomers of dimethylbenzene (or xylene). Be careful to show distinct products and not simply the same compound drawn in two different orientations. d d a. 1,2-dimethylbenzene SHD clumiol on 1 Winuonmo adiio aman lsge an...
1) The net ionic equation for the reaction between aqueous nitric acid and aqueous sodium hydroxide is A) H+ (aq) + HNO3 (aq) + 2OH- (aq) → 2H20 (1) + NO3- (aq) B) HNO3 (aq) + NaOH(aq) → NaNO3(aq) + H20 (1) C) H+ (aq) + OH- (aq) + H2O (1) D) HNO3 (aq) + OH- (aq) + NO3- (aq) + H2O (1) E) H+ (aq) + Na+ (aq) + OH- (aq) → H20 (1) + Na+ (aq) 2) Which...
The first step in industrial nitric acid (HNO3) production is
the catalyzed oxidation of ammonia (NH3). Without the catalyst the
following reaction predominates:
4NH3(g) + 3O2(g) ⇔ 2N2(g) + 6H2O(g).
When 0.0150 mol each of NH3(g) and O2(g) are placed in a 1.00 L
container at a certain temperature the N2(g) concentration at
equilibrium is 1.96x10-3 M. Fill in the following ICE table and
calculate the resulting KC.
NH3(9) 02(9) N2(9) H20(9) Initial (1) 015 mol mol .015 Number Number...
Write a net ionic equation to show that nitric acid, HNO3, behaves as an acid in water. + H2o(l) Submit Answer Retry Entire Group 5 more group attempts remaining Use the References to access important values if needed for this question. Acid Conjugate base H,S HS Acid Strength Increases Base Strength Increases HCiO CIO (1) Write a net ionic equation for the reaction between H2S and CIO that shows H2S behavin g as a Bronsted-Lowry acid BL acid BL base...
The industrial production of nitric acid (HNO3) is a multistep process. The first step is the oxidation of ammonia (NH3 ) over a catalyst with excess oxygen (02) to produce nitrogen monoxide (NO) gas as shown by the unbalanced equation given here: ?NH, (g)+?O2(g) +?NO(g)+?H2O(g) Part A What volume of O2 at 684 mmHg and 39 °C is required to synthesize 19.0 mol of NO? Express your answer to three significant figures and include the appropriate units. View Available Hint(s)...
what is the purpose of the acid catalyst: sulfuric acid? why
cant acetic acid, which is already being used, serve in the same
capacity? show mechanism of the reaction
H+ R-C-OH + carboxylic acid (excess) R2-OH alcohol + HO Ric-o-R₂ an ester The general reaction scheme for a Fischer esterification is shown above. Using the combination of acetic acid and either isopentanol AND n-propanol you will synthesize two fruity-smelling esters. The hydronium source that will catalyze this reaction is sulfuric...
Reaction 1: Nitration HNO3 NO2 H2SO4, H20 NO2 toluene NO2 ortho meta para Procedure for Reaction 1: 1) To a stirred solution of 3 mL (44.7 mmoles) 67 % HNO3 in 3.75 mL of water, H2SO4 (9 mL) was slowly added at 10-15 °C. 2) This nitrating solution was added dropwise with vigorous stirring to 4 mL (37.5 mmoles) of toluene while cooling in ice-water in order to maintain the reaction temperature between 15 and 25 °C. 3) Stirring was...
C. Indicate which is the late-detemning step. d. Is it the same mechanism as in question 1? Why or why not? 3. Explain why El and Sx1 mechanisms follow first order reaction kinetics, whereas E2 and SN2 mechanisms follow second order reaction kinetics. 4. Which is the better nucleophile in a protic solvent: chloride ion or bromide ion? Try to explain this in terms of the nature of the chloride ion and the bromide ion. 5. For the synthesis of...
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