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Design a realistic method for the synthesis of the product in the reaction from the specified...
Design a realistic method for the synthesis of the product in the reaction from the specified starting (reactant) molecule(s). Assume that simple inorganic and organic reagents are readily available, but they must be specified) If an ortho-, para-mixture is formed in any step of your synthesis, assume that the two isomers can be separated without explanation ОН CH3CH20- -NH-CATCH
2. Aklomide, 2-chloro-4-nitrobenzamide, is an ingredient in veterinary antibacterial preparations. Propose a synthesis of aklomide starting with toluene. Show all reagents and all intermediate structures. You do not need to show the mechanism. Assume ortho and para isomers can be separated. NH2 O2N Aklomide
Ethyl phenylacetate is a pleasant smelling compound used in perfumery. Propose a synthesis starting with benzene. Show all reagents and all intermediate structures. You do not need to show the mechanism. Assume ortho and para isomers can be separated. 3. Ethyl phenylacetate
Ethyl phenylacetate is a pleasant smelling compound used in perfumery. Propose a synthesis starting with benzene. Show all reagents and all intermediate structures. You do not need to show the mechanism. Assume ortho and para isomers can be...
Need help understanding what compounds to use when doing
multistep syntheses.
5. (Multistep synthesis) For each of the following multistep syntheses, provide an efficient multistep synthesis of the target compound from the starting compound. More than one reaction is required for this synthesis. You may use any inorganic compounds that you need. For cach functional group transformation, give all necessary reagents, solvents, and catalysts; give a structural formula of the organic reactant and the major organic product(s). Show stercochemistry appropriately...
Give a reasonable synthesis for
each of the following compounds from the indicated starting
materials. You may use any other organic or inorganic reagents you
wish unless otherwise indicated. The desired product for each
reaction you propose must be the one of the predominant products.
Give the reactants, conditions (where appropriate) and products of
each synthetic step. If equal mixtures are anticipated (i.e. ortho
/ para products) then indicate where separations are needed. NO
MECHANISMS! [6 points
2. Give a...
Homework extra credit!
#18. As promised in lecture... Propose a synthesis of this compound starting with the ind se a synthesis of this compound starting with the indicated material. For full credit you need to write out all the steps, showing the reagents used for each reaction. each step. For reactions that produce both ortho and para isomers, assume that the par e both ortho and para isomers, assume that the para isomer is the major product. This is not...
Outline a synthesis of the following compound from benzene (C_6H_5), methane (CH_4) and any needed inorganic reagents. Assume that ortho- and para-substitution products can be separated.
Outline all steps in the laboratory synthesis of the following compounds from benzene and/or toluene, using any needed aliphatic or inorganic reagents. Assume the para isomer can be separated from an ortho,para mixture. Do not show mechanisms. p-bromobenzoic acid m-bromobenzoic acid 2-bromo-4-nitrotoluene 2-bromo-4-nitrobenzoic acid 4-bromo-3-nitrobenzoic acid o-iodobenzoic acid
4. Propose an efficient synthesis of the molecule below starting with benzene. You can use any other reagents you want. NOTE: Some reactions produce ortho- and para-products. It is allowable to just take ONE of the products and use it in the next synthesis or claim it as the final product (we assume that ortho- and para-products can be separated). (3 points) CH2CH2CH Br
u.Propose a synthesis of the following molecule from benzene and any organic or (" inorganic reagents necessary. In your synthesis, you can only separate isomers in the middle of the synthesis, the final step should give only the desired product. (Hint! Don't forget about carbocation rearrangements.)